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51. 发明授权

US06780810B2 MULTIFUNCTIONAL CATALYST USEFUL IN THE SYNTHESIS OF CHIRAL VICINAL DIOLS AND PROCESS FOR THE PREPARATION THEREOF, AND PROCESS FOR THE PREPARATION OF CHIRAL VICINAL DIOLS USING SAID MULTIFUNCTIONAL CATALYSTS 失效
标题翻译：用于合成维生素D的多功能催化剂及其制备方法，以及使用具有多功能催化剂制备正性维生素D的方法
公开(公告)号：US06780810B2
公开(公告)日：2004-08-24
申请号：US10096072
申请日：2002-03-13
申请人： Boyapati Manoranjan Choudary , Naidu Sreenivasa Chowdari , Sateesh Madhi , Mannepalli Lakshmi Kantam
发明人： Boyapati Manoranjan Choudary , Naidu Sreenivasa Chowdari , Sateesh Madhi , Mannepalli Lakshmi Kantam
IPC分类号： B01J3100
CPC分类号： B01J31/1633 , B01J21/08 , B01J31/0239 , B01J31/0254 , B01J31/0271 , B01J31/1658 , B01J31/1825 , B01J2231/4261 , B01J2231/70 , B01J2531/66 , B01J2531/824 , B01J2531/825 , C07B2200/07 , C07C29/04 , C07C33/26 , C07C33/46
摘要： The present invention relates to a multifunctional reusable catalyst and to a process for the preparation thereof on a single matrix of the support to perform multicomponent reaction in a single pot. The multifunctional catalysts of the invention are useful for the synthesis of chiral vicinal diols by tandem and/or simultaneous reactions involving Heck coupling, N-oxidation and AD reaction of olefins in presence of cinchona alkaloid compounds both as an native one and immobilized one in the said matrix support. This invention also relates to a process for preparing vicinal diols by asymmetric dihydroxylation of olefins in presence of cinchona alkaloid compounds employing reusable multifunctional catalysts as heterogeneous catalysts in place of soluble osmium catalysts.
摘要翻译：本发明涉及一种多功能可重复使用的催化剂及其在单一载体基质上的制备方法，以便在一个锅中进行多组分反应。本发明的多官能催化剂可用于通过串联和/或同时反应来合成手性连位二醇，所述反应涉及Heck偶联，烯烃在存在cinchona生物碱化合物的情况下的N-氧化和AD反应，该化合物作为天然的化合物，并且在表示矩阵支持。本发明还涉及通过使用可再生多功能催化剂代替可溶性锇催化剂的可重复使用的多官能催化剂的香草素生物碱化合物存在下烯烃的不对称二羟基化制备连环二醇的方法。

52. 发明授权

US5919987A Preparation of alcohols and/or aldehydes 失效
标题翻译：醇和/或醛的制备
公开(公告)号：US5919987A
公开(公告)日：1999-07-06
申请号：US716216
申请日：1996-09-13
申请人： Heinz-Josef Kneuper , Maik Aron , Frank-Michael Korgitzsch , Michael Nilles , Wolfgang Harder , Michael Roper , Rocco Paciello
发明人： Heinz-Josef Kneuper , Maik Aron , Frank-Michael Korgitzsch , Michael Nilles , Wolfgang Harder , Michael Roper , Rocco Paciello
IPC分类号： B01J23/46 , B01J31/40 , C07B61/00 , C07C27/22 , C07C29/141 , C07C29/16 , C07C31/02 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/235 , C07C209/00 , C07C45/00
CPC分类号： B01J31/20 , B01J31/4046 , C07C209/00 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/80 , C07C51/235 , B01J2231/321 , B01J23/464 , B01J2531/822 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/183 , Y02P20/584
摘要： An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180.degree. C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180.degree. C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.
摘要翻译： PCT No.PCT / EP95 / 00825 Sec。 371日期1996年9月13日 102（e）日期1996年9月13日PCT 1995年3月6日PCT公布。 WO95 / 25080 PCT公开日期1995年9月21日通过在50至1000巴的压力和50至180℃的温度下通过烯烃反应物的催化加氢甲酰化来工业制备大于3个碳原子的烯烃的醛和/或醇。在均匀溶解在反应介质中的未络合的铑催化剂存在下进行。保持铑的催化活性，首先通过含氮络合剂如磺化或羧化吡啶，喹啉等的水溶液从最初排出的反应混合物中提取铑的催化活性。在加氢甲酰化反应中重复使用的复合铑的再循环中，含水铑萃取物进料到预羰化阶段，其中在基本上不溶于水的有机液体存在下进行所需的预羰基化，一氧化碳，合成气或含有一氧化碳的另一种气体混合物，从50至1000巴和50至180℃。然后将从该预羰化阶段排出的混合物分离成含有主要部分铑的有机相，相含有络合剂。然后将所得到的含再生催化剂的含铑有机相进料到加氢甲酰化阶段以完成其再循环。

53. 发明授权

US5021595A Transition metal catalyst composition for olefin polymerization 失效
标题翻译：用于烯烃聚合的过渡金属催化剂组合物
公开(公告)号：US5021595A
公开(公告)日：1991-06-04
申请号：US487695
申请日：1990-03-02
申请人： Sudhin Datta
发明人： Sudhin Datta
IPC分类号： C07F7/28 , B01J31/16 , B01J31/18 , B01J31/22 , C07F7/00 , C07F9/00 , C07F11/00 , C08F4/06 , C08F4/60 , C08F4/639 , C08F4/68 , C08F10/00
CPC分类号： B01J31/223 , B01J31/181 , B01J31/1825 , C07F11/005 , C07F7/006 , C07F9/005 , C08F10/00 , B01J2531/46 , B01J2531/56 , B01J2531/62
摘要： This invention relates to bidentate transition metal catalyst compositions useful for coordination polymerization of alpha olefin monomers. The novel catalyst compounds are prepared by:(1) reacting a transition trihalide, a transition metal trialkoxide or mixed tri(halide/alkoxide), or the adducts of these materials with Lewis bases, with two equivalents of a bidentate chelating ligand; or(2) reacting two equivalents of the same or different transition metal (+3) tris chelates with one equivalent of a transition metal trihalide or its adduct with Lewis bases.The invention chelating ligands are those which contain at least two, and preferably not more than two, hetero atoms such as O, N, P, or S, separated by a hydrocarbon radical providing sufficient chain length so as to allow both hetero atoms to chelate the same metal atom. The chelating ligand must have at least one easily removable positive ion which is lost on chelation to afford a uninegative, bidentate ligand.
摘要翻译：本发明涉及可用于α-烯烃单体的配位聚合的二齿过渡金属催化剂组合物。通过以下方法制备新型催化剂化合物：（1）使过渡三卤化物，过渡金属三醇盐或混合的三（卤化物/醇盐）或这些物质的加合物与路易斯碱反应，与两当量的二齿螯合配体反应; 或（2）使两当量的相同或不同的过渡金属（+3）三螯合物与一当量的过渡金属三卤化物或其与路易斯碱的加合物反应。本发明螯合配体是含有至少两个，优选不多于两个杂原子如O，N，P或S的那些，由烃基分离，提供足够的链长以便允许两个杂原子螯合相同的金属原子。螯合配体必须具有至少一种容易除去的正离子，其在螯合时损失，以提供无定形的双齿配体。

54. 发明授权

US4469882A Process for the production of aromatic carbamates 失效
标题翻译：生产芳香族氨基甲酸酯的方法
公开(公告)号：US4469882A
公开(公告)日：1984-09-04
申请号：US395068
申请日：1982-06-23
申请人： Tsutomu Takeuchi , Mineo Nishi , Toshio Irie , Hirotaka Ryuto
发明人： Tsutomu Takeuchi , Mineo Nishi , Toshio Irie , Hirotaka Ryuto
IPC分类号： C07B61/00 , B01J31/02 , B01J31/36 , C07C271/06 , C07C125/065 , C07C125/073
CPC分类号： B01J31/0244 , B01J31/28 , B01J31/36 , C07C271/06 , B01J2231/34 , B01J2531/56 , B01J2531/824 , B01J2531/842 , B01J31/181 , B01J31/1825 , B01J31/2234
摘要： A process for producing aromatic carbamates in high yield is described, which comprises reacting aromatic nitro compounds, organic compounds containing a hydroxy group, and carbon monoxide in the presence of a catalyst comprising: (1) a platinum group metal or its compound, (2) metallic vanadium or its compound, (3) metallic iron or its compound, (4) a halogen atom, and (5) a tertiary amine, wherein the amount of each component used and the composition are adjusted within specific ranges.
摘要翻译： PCT No.PCT / JP81 / 00293 Sec。 371日期1982年6月23日 102（e）日期1982年6月23日PCT提交1981年10月22日PCT公布。出版物WO82 / 01550 PCT 日本1982年5月13日。描述了一种高产率生产芳族氨基甲酸酯的方法，其包括在催化剂存在下使芳族硝基化合物，含有羟基的一些有机化合物与一氧化碳反应，包括：（1）铂族金属或其化合物，（2）金属钒或其化合物，（3）金属铁或其化合物，（4）卤素原子和（5）叔胺，其中使用的每种组分的量和组成在具体范围。

55. 发明授权

US3914268A Process for preparing aromatic organic isocyanates 失效
标题翻译：制备芳族有机异氰酸酯的方法
公开(公告)号：US3914268A
公开(公告)日：1975-10-21
申请号：US33886673
申请日：1973-03-07
申请人： SUMITOMO CHEMICAL CO
发明人： YAMAHARA TAKESHI , TAKAMATSU SCHICHIRD , DEGUCHI TAKASHI , USUI MASAHIRO , HIROSE KENICHI , YOSHIHARA HIROSHI
IPC分类号： C07C20060101 , C07C263/14 , C07C265/12 , C07C118/06
CPC分类号： C07C263/14 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J2231/4277 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , C07C265/14 , C07C265/12
摘要： In the production of an aromatic organic isocyanate by contacting an aromatic nitro compound and carbon monoxide in the presence of a catalyst system comprising a platinum group metal compound with or without an aromatic nitrogenous heterocyclic compound, an improved process wherein the said catalyst system includes further at least one of water, hydrogen, hydrogen halides, boric acids, formic acid, oxalic acid and formaldehyde. By such improved process a much higher reaction rate and a markedly excellent yield are attained.
摘要翻译：在芳香族有机异氰酸酯的制备中，通过使芳香族硝基化合物与一氧化碳在含有或不含有芳族含氮杂环化合物的铂族金属化合物的催化剂体系的存在下接触，其中所述催化剂体系进一步包括水，氢，卤化氢，硼酸，甲酸，草酸和甲醛中的至少一种。通过这种改进的方法获得了更高的反应速率和显着优异的产率。

56. 发明授权

US3867343A Catalysts and use thereof 失效
标题翻译：催化剂及其用途
公开(公告)号：US3867343A
公开(公告)日：1975-02-18
申请号：US41116673
申请日：1973-10-30
申请人： ICI LTD
发明人： GARDEN WILLIAM DAVID
IPC分类号： B01J31/22 , B01J31/24 , C07F7/08 , C08L83/04 , C08F11/04
CPC分类号： B01J31/124 , B01J31/0237 , B01J31/0247 , B01J31/1805 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/22 , B01J31/226 , B01J31/2291 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J2531/828 , C08G77/08 , C08G77/12 , C08G77/16 , C08L83/04 , C08L83/00 , C08L2666/52
摘要： New catalysts consisting of a platinum complex and ammonia or derivative thereof, use of such catalysts to confer longer bath lives on compositions containing siloxanes containing SiOH groups and siloxanes containing SiH groups and solventless catalysed compositions.
摘要翻译：由铂络合物和氨或其衍生物组成的新型催化剂使用这种催化剂使含有SiOH基团的硅氧烷和含有SiH基的硅氧烷和无溶剂催化组合物的组合物具有更长的浴寿命。

57. 发明授权

US08222469B2 Catalysts and processes for the formation of terminal olefins by ethenolysis 有权
标题翻译：通过乙烯分解形成末端烯烃的催化剂和方法
公开(公告)号：US08222469B2
公开(公告)日：2012-07-17
申请号：US12503608
申请日：2009-07-15
申请人： Richard R. Schrock , Smaranda C. Marinescu , Amir H. Hoveyda
发明人： Richard R. Schrock , Smaranda C. Marinescu , Amir H. Hoveyda
IPC分类号： C07C2/02
CPC分类号： C07C6/06 , B01J31/1805 , B01J31/181 , B01J31/1825 , B01J31/2226 , B01J31/2265 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/225 , C07C6/04 , C07C67/333 , C07C2531/22 , C07C11/02 , C07C11/12 , C07C69/533
摘要： The present invention relates generally to catalysts and processes for the formation of terminal olefin(s) from internal olefin(s) via ethenolysis reactions. The ethenolysis reactions may proceed with high conversion, high turnover, and/or high selectivity.
摘要翻译：本发明一般涉及通过乙烯分解反应从内部烯烃形成末端烯烃的催化剂和方法。乙烯分解反应可以进行高转化率，高转化率和/或高选择性。

58. 发明申请

US20110251393A1 HELICENE DERIVATIVE, AXIALLY ASYMMETRIC AMINO ACID, AMINE OR AMINOALCOHOL DERIVATIVE, PERYLENE DERIVATIVE OR SALT THEREOF, AND METHODS FOR PRODUCING SAME 审中-公开
标题翻译：乙烯衍生物，不对称氨基酸，胺或氨基醇衍生物，其衍生物或其盐，及其生产方法
公开(公告)号：US20110251393A1
公开(公告)日：2011-10-13
申请号：US13125495
申请日：2009-10-20
申请人： Takumi Furuta , Takeo Kawabata
发明人： Takumi Furuta , Takeo Kawabata
IPC分类号： C07D221/18 , C07C63/42 , C07C237/48 , C07C211/57 , C07D213/72 , C07D257/04 , C07C69/76 , C07C69/96
CPC分类号： C07D221/18 , B01J31/0247 , B01J31/1825 , B01J2531/0263 , C07C215/86 , C07C229/52 , C07C255/60 , C07C271/30 , C07D401/04
摘要： The invention provides a helicene derivative, axially chiral amino acid, amine or amino alcohol derivative, and azaperylene, such as compounds represented by Formulae (I), (I′), (II), (II′), and (III): and a method for producing the same.
摘要翻译：本发明提供了由式（I），（I'），（II），（II'）和（III）表示的化合物：丙烯衍生物，轴向手性氨基酸，胺或氨基醇衍生物，及其制造方法。

59. 发明申请

US20110089407A1 ELECTROLUMINISCENT METAL COMPLEXES WITH DIBENZO[F,H] QUINOXALINES 有权
标题翻译：电致发光金属复合物与二苯并[F，H]喹啉
公开(公告)号：US20110089407A1
公开(公告)日：2011-04-21
申请号：US12864877
申请日：2009-02-02
申请人： Beat Schmidhalter , Thomas Schafer , Peter Murer , Kristina Bardon , Stephan Allenbach , Andrea Ricci
发明人： Beat Schmidhalter , Thomas Schafer , Peter Murer , Kristina Bardon , Stephan Allenbach , Andrea Ricci
IPC分类号： H01L51/54 , C07F15/00
CPC分类号： G01N31/225 , B01J31/1825 , C07F15/0033 , C09K2211/1011 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H01L51/5048
摘要： This invention relates to electroluminescent metal complexes of the formula (I), or (II), a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：本发明涉及式（I）或（II）的电致发光金属络合物，其制备方法，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED），作为氧敏感指标，作为生物测定中的磷光指标，并作为催化剂。

60. 发明申请

US20110077421A1 HIGHLY Z-SELECTIVE OLEFINS METATHESIS 有权
标题翻译：高选择性脂蛋白METATHESIS
公开(公告)号：US20110077421A1
公开(公告)日：2011-03-31
申请号：US12571036
申请日：2009-09-30
申请人： Richard R. Schrock , Annie J. King , Yu Zhao , Margaret M. Flook
发明人： Richard R. Schrock , Annie J. King , Yu Zhao , Margaret M. Flook
IPC分类号： C07F7/08 , C07C6/04 , C07C69/34 , C07F5/02 , C07C43/20 , C07C303/00 , C07C211/00
CPC分类号： B01J31/2295 , B01J31/1805 , B01J31/181 , B01J31/1825 , B01J31/2226 , B01J31/2265 , B01J31/2278 , B01J2231/54 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/225 , B01J2540/40 , C07B2200/09 , C07C6/04 , C07C41/30 , C07C67/475 , C07C209/64 , C07C209/68 , C07C303/40 , C07C2531/18 , C07C2531/22 , C07C2601/14 , C07C2601/16 , C07C2602/10 , C07F5/025 , C07F7/083 , C07F11/00 , C07F11/005 , C07C13/28 , C07C11/02 , C07C15/50 , C07C43/166 , C07C69/593 , C07C311/18 , C07C211/53
摘要： The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.
摘要翻译：本发明一般涉及通过同位素反应从末端烯烃Z选择性形成内部烯烃的催化剂和方法。

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