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1. 发明专利

AU6497599A Impregnated glass fiber strands and products including the same 未知
公开(公告)号：AU6497599A
公开(公告)日：2000-05-01
申请号：AU6497599
申请日：1999-10-08
申请人： PPG IND OHIO INC , ERNEST L LAWTON , XIANG WU , WILLIAM B RICE , BRUCE E NOVICH
发明人： LAWTON ERNEST L , WU XIANG , RICE WILLIAM B , NOVICH BRUCE E
IPC分类号： C03C25/10 , C03C25/42 , C03C25/47 , C08J5/08 , D03D15/00 , D03D15/12 , D04H1/42 , D06M13/00 , D06M13/513 , D06M15/227 , D06M15/263 , D06M15/333 , D06M15/41 , D06M15/507 , D06M15/564 , D06M15/59 , D06M101/00 , H05K1/03 , H05K3/00

2. 发明授权

US06949289B1 Impregnated glass fiber strands and products including the same 失效
标题翻译：浸渍玻璃纤维束和产品包括相同
公开(公告)号：US06949289B1
公开(公告)日：2005-09-27
申请号：US09705575
申请日：2000-11-03
申请人： Ernest L. Lawton , Vedagiri Velpari , William B. Rice , Walter J. Robertson , Bruce E. Novich , Xiang Wu , Kami Lammon-Hilinski
发明人： Ernest L. Lawton , Vedagiri Velpari , William B. Rice , Walter J. Robertson , Bruce E. Novich , Xiang Wu , Kami Lammon-Hilinski
IPC分类号： C03C25/00 , C03C25/10 , C03C25/48 , C08J5/08 , H05K1/03 , D02G15/00
CPC分类号： C03C25/101 , B29B15/08 , C03C25/00 , C03C25/10 , C03C25/26 , C03C25/47 , C03C25/48 , C08J5/08 , H05K1/0366 , H05K2201/0209 , H05K2201/0212 , Y10T428/2927 , Y10T428/2933 , Y10T428/2938 , Y10T428/2964
摘要： The present invention provides an at least partially coated fiber strand comprising a plurality of glass fibers having a coating composition on at least a portion of at least one of the glass fibers, the coating composition comprising at least one coating comprising greater than 20 weight percent on a total solids basis of a plurality of particles selected from inorganic particles, organic hollow particles, composite particles, and mixtures of any of the foregoing, wherein the plurality of particles have a Mohs' hardness value which does not exceed the Mohs' hardness value of the glass fibers.
摘要翻译：本发明提供一种至少部分涂布的纤维束，其包含多个玻璃纤维，所述多个玻璃纤维在玻璃纤维的至少一个玻璃纤维的至少一部分上具有涂层组合物，所述涂料组合物包含至少一个包含大于20重量％选自无机颗粒，有机中空颗粒，复合颗粒和任何前述物质的混合物的多个颗粒的总固体，其中多个颗粒的莫氏硬度值不超过莫氏硬度值玻璃纤维。

3. 发明授权

US06849328B1 Light-transmitting and/or coated article with removable protective coating and methods of making the same 有权
标题翻译：具有可移除保护涂层的透光和/或涂层制品及其制造方法
公开(公告)号：US06849328B1
公开(公告)日：2005-02-01
申请号：US09567934
申请日：2000-05-10
申请人： Paul A. Medwick , Erin Goodreau , Ernest L. Lawton , James J. Finley , George M. Martin , James P. Thiel , Gary J. Marietti , Roger L. Scriven
发明人： Paul A. Medwick , Erin Goodreau , Ernest L. Lawton , James J. Finley , George M. Martin , James P. Thiel , Gary J. Marietti , Roger L. Scriven
IPC分类号： B05D5/00 , B05D7/00 , B32B7/06 , B32B9/00 , B65G49/06 , C03C17/32 , C03C17/38 , C03C17/42 , C09D5/00 , B32B17/10
CPC分类号： C09D5/008 , B65B33/04 , B65G49/069 , C03C17/32 , C03C17/38 , C03C17/42 , C03C2217/475 , C03C2217/485 , C03C2218/328 , C03C2218/355 , Y10T428/273 , Y10T428/30 , Y10T428/31507 , Y10T428/31649 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31703 , Y10T428/31786 , Y10T428/31931 , Y10T428/31935
摘要： A method and coating are provided for temporarily protecting a substrate or article during shipping, handling or storage by applying a removable protective coating over at least a portion of the substrate. The substrate may be flat or curved and may have zero, one or more functional coatings. A plurality of substrates with the protective coating of the invention may be arranged in a shipping container so that the protective coating reduces the possibility of damage to the substrate or optional functional coating. In one embodiment, the protective coating is the evaporation or reaction product of an aqueous coating composition containing a polyvinyl alcohol polymer which may be subsequently removed by aqueous washing, thermal decomposition or combustion. In another embodiment, the protective coating is formed by sputtering a substantially carbon coating onto the substrate. The carbon coating is subsequently removed by combustion. The protective coating may have identification materials, such as colorants or fragrance materials, such that different types of substrates and/or functional coatings can be distinguished from each other. Additionally, the temporary protective coating can improve the heating of a functionally coated glass substrate.
摘要翻译：提供了一种方法和涂层，用于在运输，处理或存储期间通过在基底的至少一部分上施加可移除的保护涂层来临时保护基底或制品。基底可以是平的或弯曲的，并且可以具有零个一个或多个功能性涂层。具有本发明的保护涂层的多个基底可以布置在运输容器中，使得保护涂层减少了损坏基底或可选功能性涂层的可能性。在一个实施方案中，保护性涂层是含有聚乙烯醇聚合物的水性涂料组合物的蒸发或反应产物，其可随后通过水洗，热分解或燃烧除去。在另一个实施方案中，通过将基本上碳涂层溅射到基底上而形成保护涂层。随后通过燃烧除去碳涂层。保护涂层可以具有识别材料，例如着色剂或香料，使得可以区分不同类型的基材和/或功能性涂层。此外，临时保护涂层可以改善功能性涂覆的玻璃基板的加热。

4. 发明授权

US06593255B1 Impregnated glass fiber strands and products including the same 失效
标题翻译：浸渍玻璃纤维束和产品包括相同
公开(公告)号：US06593255B1
公开(公告)日：2003-07-15
申请号：US09705353
申请日：2000-11-03
申请人： Ernest L. Lawton , Vedagiri Velpari , William B. Rice , Walter J. Robertson , Bruce E. Novich , Xiang Wu , Kami Lammon-Hilinski
发明人： Ernest L. Lawton , Vedagiri Velpari , William B. Rice , Walter J. Robertson , Bruce E. Novich , Xiang Wu , Kami Lammon-Hilinski
IPC分类号： B32B900
CPC分类号： B32B9/00 , C03C25/00 , C03C25/10 , C03C25/26 , C03C25/28 , C03C25/32 , C03C25/42 , C03C25/47 , C03C25/48 , C08J5/08 , H05K1/0366 , H05K3/0047 , H05K2201/0166 , H05K2201/0175 , H05K2201/0209 , H05K2201/0212 , H05K2201/0215 , H05K2201/0239 , H05K2201/0245 , H05K2201/0248 , H05K2201/0254 , H05K2201/029 , H05K2203/127 , Y10T428/2927 , Y10T428/2933 , Y10T428/2938 , Y10T428/2964 , Y10T442/20 , Y10T442/3049
摘要： A fabric comprising at least one fiber strand comprising a plurality of fibers and having a resin compatible coating composition on at least a surface of the at least one fiber strand, wherein the at least one fiber strand has an Air Jet Transport Drag Force value of greater than 100,000 gram force per gram mass of strand as determined by a needle air jet nozzle unit having an internal air jet chamber having a diameter of 2 millimeters and a nozzle exit tube having a length of 20 centimeters at a strand feed rate of 274 meters per minute and an air pressure of 310 kiloPascals. A reinforced laminate comprising: (a) at least one matrix material; and (b) at least one fabric comprising at least one fiber strand comprising a plurality of fibers and having a resin compatible coating composition on at least a surface of the at least one fiber strand, wherein the at least one fiber strand has an Air Jet Transport Drag Force value of greater than 100,000 gram force per gram mass of strand as determined by a needle air jet nozzle unit having an internal air jet chamber having a diameter of 0.2 millimeters and a nozzle exit tube having a length of 20 centimeters at a strand feed rate of 274 meters per minute and an air pressure of 310 kiloPascals.
摘要翻译：一种织物，其包含至少一根纤维束，其包含多根纤维，并且在所述至少一条纤维束的至少一个表面上具有树脂相容的涂料组合物，其中所述至少一条纤维束具有更大的空气喷射输送阻力值通过具有直径为2毫米的内部空气喷射室的针气喷嘴单元确定的每克质量的绞线的100,000克力和具有274米长度的绞线进给速度的20厘米长度的喷嘴出口管分钟，气压310千帕。一种增强层压板，包括：（a）至少一种基体材料; 和（b）至少一种织物，其包含至少一根包含多根纤维并且在所述至少一根纤维束的至少一个表面上具有树脂相容性涂料组合物的纤维束，其中所述至少一根纤维束具有空气喷射运输阻力通过具有直径为0.2毫米的内部空气喷射室的针空气喷嘴单元和在一根股线上具有20厘米长度的喷嘴出口管确定的每克质量的股线的大于100,000克力的运输阻力值进料速度为274米/分钟，空气压力为310千帕。

5. 发明授权

US06228496B1 Sizing composition for glass fibers 失效
标题翻译：玻璃纤维的上胶组合物
公开(公告)号：US06228496B1
公开(公告)日：2001-05-08
申请号：US09320520
申请日：1999-05-26
申请人： Ernest L. Lawton , Michael L. Gunther , Eric R. Pohl
发明人： Ernest L. Lawton , Michael L. Gunther , Eric R. Pohl
IPC分类号： B32B2520
CPC分类号： C03C25/321 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964 , Y10T442/20
摘要： The present invention provides a glass fiber strand comprising at least one glass fiber at least partially coated with a sizing composition prepared from ingredients comprising; at least one starch; at least one lubricant; and at least one silane coupling agent comprising: [((R1)bY)aR23-aSiR3]2NX, wherein R1 and R2 are each monovalent radials; R3 is a divalent linking group; a is 1 to 3; X is (R4)bZC(═O)CH(Q)CH(Q)—, wherein Z is CH2, O, S or N, Q is H, alkyl, aryl, alkaryl, or C(═O)ZR4 and R4 is a hydrocarbon moiety of one to twenty carbon atoms, hydrogen, a silyl group or an organic polymer; Y is oxygen, nitrogen or sulfur; and b is 1 or 2 depending upon the valency of Y. In one particular embodiment of the invention, the silane in the aqueous sizing composition is (CH3)3COC(═O)CH2CH2N[CH2CH2CH2Si(OCH3)3]2.
摘要翻译：本发明提供一种玻璃纤维束，其包含至少一种至少部分涂覆有由以下成分制备的施胶组合物的玻璃纤维：至少一种淀粉; 至少一种润滑剂; 和至少一种硅烷偶联剂，其包含：[（（R1）bY）aR23-aSiR3] 2NX，其中R1和R2各自是单价径向; R3是二价连接基团; a是1到3; X是（R4）bZC（= O）CH（Q）CH（Q） - ，其中Z是CH2，O，S或N，Q是H，烷基，芳基，烷芳基或C（= O）ZR4和R4 是1至20个碳原子的烃部分，氢，甲硅烷基或有机聚合物; Y为氧，氮或硫; 并且b是1或2，这取决于Y的化合价。在本发明的一个具体实施方案中，水性施胶组合物中的硅烷是（CH 3）3 COC（= O）CH 2 CH 2 N [CH 2 CH 2 CH 2 Si（OCH 3）3] 2。

6. 发明授权

US3972933A Preparation of carbodiimides from ureas by dehydration 失效
标题翻译：通过脱水从尿素制备碳二亚胺
公开(公告)号：US3972933A
公开(公告)日：1976-08-03
申请号：US473616
申请日：1974-05-28
申请人： Ernest L. Lawton
发明人： Ernest L. Lawton
IPC分类号： C07C273/18 , C07C275/28 , D06M13/395 , C07C119/00
CPC分类号： C07C267/00 , C07C273/1827 , D06M13/395
摘要： Biscarbodiimides which are known to be effective as a surface application for polyethylene terephthalate fibers in lowering carboxyl end group concentration of the fibers and increasing hydrolytic stability, are prepared by the dehydration of ureas with triphenylphosphine and carbon tetrachloride.
摘要翻译：通过用三苯基膦和四氯化碳脱水来制备已知作为聚对苯二甲酸乙二醇酯纤维降低纤维的羧基端基浓度和增加水解稳定性的表面应用的双碳二亚胺。

7. 发明授权

US07354641B2 Resin compatible yarn binder and uses thereof 失效
标题翻译：树脂相容的纱线粘合剂及其用途
公开(公告)号：US07354641B2
公开(公告)日：2008-04-08
申请号：US10960967
申请日：2004-10-12
申请人： Robert B. Rau , Ernest L. Lawton
发明人： Robert B. Rau , Ernest L. Lawton
IPC分类号： B32B27/04 , B32B5/16 , D02G3/00
CPC分类号： B32B17/02 , B32B2605/18 , C03C25/26 , C03C25/47 , Y10T428/249944 , Y10T428/249946 , Y10T428/249948 , Y10T428/249952 , Y10T428/2933 , Y10T428/2982
摘要： Certain embodiments of the invention are directed to a fiber strand comprising at least one fiber at least partially coated with a starch-free composition formed from the components comprising at least one film forming material, at least one polymeric lubricant, at least one rosin, at least one organo silane coupling agent, at least one dispersion of polymeric particles, wherein the individual particles have a diameter of at least 0.1 microns, at least one emulsifying agent, and at least one additional lubricant that is different from the at least one polymeric lubricant.
摘要翻译：本发明的某些实施方案涉及包含至少一种纤维的纤维束，所述至少一种纤维至少部分地被无淀粉组合物涂覆，所述组合物由包含至少一种成膜材料，至少一种聚合物润滑剂，至少一种松香，至少一种有机硅烷偶联剂，至少一种聚合物颗粒分散体，其中各个颗粒具有至少0.1微米的直径，至少一种乳化剂和至少一种不同于至少一种聚合物润滑剂的另外的润滑剂。

8. 发明授权

US5393335A Starch-oil sizing for glass fibers 失效
标题翻译：用于玻璃纤维的淀粉 - 油上浆
公开(公告)号：US5393335A
公开(公告)日：1995-02-28
申请号：US52323
申请日：1993-04-23
申请人： Garry D. Puckett , Ernest L. Lawton , Xiang Wu
发明人： Garry D. Puckett , Ernest L. Lawton , Xiang Wu
IPC分类号： C03C25/32 , C08L3/00 , D06M15/11 , C09D103/02
CPC分类号： D06M15/11 , C03C25/321 , C08L3/00 , Y10T428/2962 , Y10T428/31612
摘要： An aqueous starch-oil sizing composition is provided which produces improved processibility in woven and non-woven applications. The sizing has low viscosity starch, a lubricant which is a mixture of oil and wax where the wax is present in an amount of at least twice the oil, cationic lubricants, and a humectant. The size also includes an organo-functional silane coupling agent such as gamma-glycidoxypropyltrimethoxy silane which may be hydrolyzed. Emulsifiers, defoamers, and biocides may be present. Strands of glass fiber which have been treated with this size have generally shown a reduced tendency to shed the size from the strands, a reduction in the buildup of broken filaments or "fuzz" on processing equipment and reduced strand breakage.
摘要翻译：提供了一种水性淀粉 - 油上胶组合物，其在织造和非织造应用中产生改进的加工性能。上浆具有低粘度淀粉，润滑剂是油和蜡的混合物，其中蜡的存在量至少为油的两倍，阳离子润滑剂和湿润剂。该尺寸还包括可水解的有机官能的硅烷偶联剂，例如γ-环氧丙氧基丙基三甲氧基硅烷。可能存在乳化剂，消泡剂和杀生物剂。已经用这种尺寸处理的玻璃纤维束通常显示出从股线上减小尺寸的趋势，减少在加工设备上破裂的丝或“绒毛”的积聚和减少的线断裂。

9. 发明授权

US5089188A Spinning of sol gel siliceous-containing fibers with wet coagulation 失效
标题翻译：溶胶凝胶含硅质纤维与湿凝固纺丝
公开(公告)号：US5089188A
公开(公告)日：1992-02-18
申请号：US370205
申请日：1989-06-22
申请人： Desaraju V. Varaprasad , Agaram S. Abhiraman , Ernest L. Lawton
发明人： Desaraju V. Varaprasad , Agaram S. Abhiraman , Ernest L. Lawton
IPC分类号： C04B35/622 , D01F9/08
CPC分类号： C04B35/6269 , C04B35/6224 , C04B35/624 , C04B35/6264 , D01F9/08 , C04B2235/441
摘要： A wet and dry jet wet spinning process produce one or a plurality of siliceous-containing fibers. At least a partial hydrolyzate is formed from silicon alkoxides and/or colloidal dispersions of hydrolyzable metal oxides through acid catalyzed hydrolysis in the presence of a solvent. The ratio of amounts of the water to silicon alkoxide or hydrous oxide is around 1.5 to 1 up to less than around 4 to 1. Both the hydrolysis and polymerization reactions produce an ungelled hydrolyzate with a viscosity in the range of 70 to greater than 1000 poise. This hydrolyzate is extruded through a spinnerette into a gaseous environment for dry jet wet spinning followed by contacting with a nonsolvent liquid or directly into a nonsolvent liquid for wet spinning. The contacting with the nonsolvent liquid is for effective coagulation to produce cohesive fiber that may have some stickiness. The fiber is removed from the nonsolvent liquid where the fiber's length is continuous from the spinnerette to removal. The continuous fiber is collected when it has at least a coagulated surface to produce a predominantly nonsticky fiber. The fiber may be utilized as precursor fiber or further processed by washing and/or stretching and/or drying and/or heating for removal of water, and organic solvent and/or consolidating of the fiber.
摘要翻译：湿和干喷射湿法纺丝法生产一种或多种含硅质纤维。在溶剂存在下，通过酸催化水解，由可水解金属氧化物的硅烷氧化物和/或胶体分散体形成至少部分水解产物。水与硅氧烷或水合氧化物的量的比例约为1.5:1至小于约4:1。水解和聚合反应都产生粘度在70至大于1000泊的范围内的未凝胶化的水解产物。将该水解产物通过喷丝板挤出到气态环境中用于干燥喷射湿纺，然后与非溶剂液体接触或直接与非溶剂液体接触以进行湿纺。与非溶剂液体的接触是为了有效凝结以产生可能具有一些粘性的粘性纤维。将纤维从非溶剂液体中除去，其中纤维的长度从喷丝板连续到去除。当连续纤维至少具有凝固表面以产生主要不粘的纤维时被收集。纤维可以用作前体纤维，或通过洗涤和/或拉伸和/或干燥和/或加热进一步加工以去除水，有机溶剂和/或纤维的固结。

10. 发明授权

US08105690B2 Fiber product coated with particles to adjust the friction of the coating and the interfilament bonding 失效
标题翻译：纤维制品涂有颗粒以调节涂层的摩擦和丝间粘合
公开(公告)号：US08105690B2
公开(公告)日：2012-01-31
申请号：US10775174
申请日：2004-02-11
申请人： Ernest L. Lawton , Robert B. Rau , Garry D. Puckett
发明人： Ernest L. Lawton , Robert B. Rau , Garry D. Puckett
IPC分类号： D02G3/00 , B32B9/00
CPC分类号： D02G3/00 , C03C25/00 , C03C25/10 , C03C25/26 , C03C25/323 , C03C25/36 , C03C25/47 , C03C25/48 , C08J5/08 , H05K1/0366 , H05K2201/0166 , H05K2201/0175 , H05K2201/0209 , H05K2201/0212 , H05K2201/0245 , H05K2203/127 , Y10T428/2927 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： The present invention provides a glass fiber product having particles adhered to at least one fiber of the product, where the size and amount of particles is effective to reduce the tackiness of the glass fiber product and optionally effective to reduce interfilament bonding, and composition, and method for forming the same.
摘要翻译：本发明提供了一种玻璃纤维产品，其具有附着到产品的至少一种纤维上的颗粒，其中颗粒的尺寸和数量有效地降低玻璃纤维产品的粘性，并且可选地有效地减少纤维间粘合，以及组合物，和其形成方法。

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