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    • 2. 发明申请
    • DEFINING AN ELECTRODE AREA
    • 定义电极区域
    • WO1996032635A1
    • 1996-10-17
    • PCT/AU1996000210
    • 1996-04-11
    • MEMTEC AMERICA CORPORATIONHODGES, Alastair, McIndoeJOHANSEN, OddvarBECK, Thomas, William
    • MEMTEC AMERICA CORPORATION
    • G01N27/40
    • B01D67/0086G01N27/30
    • The present invention relates to a method for defining an area (4) of a layer on a porous substrate comprising compressing a volume of the substrate to produce a compressed region (8) which defines, or which in combination with an edge (7) of the substrate or of the layer defines, a boundary of the area and which substantially prevents the transport of material through or across its surface. The present invention also relates to an electrochemical sensing device comprising: a porous substrate; and an electrode (1) on one side of the substrate; wherein a region of the substrate is compressed to an extent which forms a barrier to migration of electrolyte within the substrate, the compressed region defining, or in combination with an edge of the substrate or the electrode defining, a zone on the electrode of predetermined area.
    • 本发明涉及一种用于限定多孔基底上的层的区域(4)的方法,包括压缩一定体积的基底以产生压缩区域(8),该压缩区域(8)与边界(7) 衬底或层限定了该区域的边界,并且基本上防止材料通过其表面或穿过其表面。 本发明还涉及一种电化学感测装置,包括:多孔基材; 以及在所述基板的一侧上的电极(1) 其中所述衬底的区域被压缩到对所述衬底内的电解质迁移的阻挡的程度,所述压缩区限定或者与所述衬底或所述电极的边缘组合,限定所述电极上的预定区域 。
    • 7. 发明申请
    • ELECTROCHEMICAL CELL
    • 电化学细胞
    • WO1997000441A1
    • 1997-01-03
    • PCT/AU1996000365
    • 1996-06-19
    • MEMTEC AMERICA CORPORATIONHODGES, Alastair, McIndoeBECK, Thomas, WilliamJOHANSEN, Oddvar
    • MEMTEC AMERICA CORPORATION
    • G01N27/42
    • C12Q1/004G01N27/3273
    • A method for determining the concentration of a reduced (or oxidised) form of a redox species in an electrochemical cell of the kind comprising a working electrode and a counter electrode spaced from the working electrode by a predetermined distance, said method comprising the steps of: (1) applying an electric potential difference between the electrodes; (2) selecting the potential of the working electrode such that the rate of electro-oxidation of the reduced form (or electro-reduction of the oxidised form) of the species is diffusion controlled, (3) selecting the spacing between the working electrode and the counter electrode so that reaction products from the counter electrode arrive at the working electrode; (4) determining current as a function of time after application of the potential and prior to achievement of a steady state; (5) estimating the magnitude of the steady state current, and (6) obtaining from the change in current with time and the magnitude of the steady state current, a value indicative of the diffusion coefficient and/or of the concentration of the reduced form (or the oxidised form) of the species. Also disclosed is an apparatus for determining the concentration of a redox species in an electrochemical cell comprising: an electrochemical cell having a working electrode and a counter (or counter/reference) electrode, means for applying and electric potential difference between said electrodes, means for measuring the change in current with time, and characterised in that the working electrode is spaced from the counter electrode by less than 500 mu m.
    • 一种用于确定电化学电池中还原(或氧化)形式的氧化还原物质的浓度的方法,所述电化学电池包括工作电极和与工作电极隔开预定距离的对电极,所述方法包括以下步骤: (1)在电极之间施加电位差; (2)选择工作电极的电位使得物种的还原形式(或氧化形式的电还原)的电氧化速率被扩散控制,(3)选择工作电极和 相对电极使得来自反电极的反应产物到达工作电极; (4)在实施稳定状态之后,确定作为时间的函数的电流; (5)估计稳态电流的大小,以及(6)根据电流随时间的变化和稳态电流的大小获得表示扩散系数和/或浓缩形式的浓度的值 (或氧化形式)的物种。 还公开了一种用于确定电化学电池中的氧化还原物质的浓度的装置,包括:具有工作电极和计数器(或反/参考)电极的电化学电池,用于施加的电极和所述电极之间的电位差, 测量电流随时间的变化,其特征在于工作电极与对电极间隔小于500μm。