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    • 4. 发明授权
    • Barrier layer removal method and apparatus
    • 阻隔层去除方法和装置
    • US08598039B2
    • 2013-12-03
    • US13059814
    • 2008-08-20
    • Jian WangZhaowei JiaJunping WuLiangzhi XieHui Wang
    • Jian WangZhaowei JiaJunping WuLiangzhi XieHui Wang
    • H01L21/302
    • H01L21/67069H01L21/02074H01L21/32115H01L21/32135H01L21/67075
    • This invention relates to a method and apparatus by integrating semiconductor manufacturing processes of stress free electrochemical copper polishing (SFP), removal of the Tantalum oxide or Titanium oxide formed during SFP process and XeF2 gas phase etching barrier layer Ta/TaN or Ti/TiN process. Firstly, at least portion of plated copper film is polished by SFP. Secondly the barrier metal oxide film formed during SFP process is etched away by etchant. Finally, the barrier layer Ta/TaN or Ta/TiN is removed with XeF2 gas phase etching. The apparatus accordingly consists of three sub systems: stress free copper electropolishing system, barrier layer oxide film removal system and barrier layer Ta/TaN or Ti/TiN gas phase etching system.
    • 本发明涉及通过集成无应力电化学铜抛光(SFP)的半导体制造工艺,去除在SFP工艺期间形成的氧化钽或氧化钛和XeF 2气相蚀刻阻挡层Ta / TaN或Ti / TiN工艺的方法和装置 。 首先,通过SFP抛光电镀铜膜的至少一部分。 其次,在SFP工艺期间形成的阻挡金属氧化物膜被蚀刻剂蚀刻掉。 最后,用XeF2气相蚀刻除去阻挡层Ta / TaN或Ta / TiN。 因此该装置由三个子系统组成:无应力铜电解抛光系统,阻挡层氧化膜去除系统和阻挡层Ta / TaN或Ti / TiN气相蚀刻系统。