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    • 3. 发明申请
    • ANISOTROPIC FILM MANUFACTURING
    • ANISOTROPIC膜制造
    • WO2004065524A1
    • 2004-08-05
    • PCT/US2004/001179
    • 2004-01-16
    • OPTIVA INC.LAZAREV, Pavel, I.NAZAROV, Victor, V.
    • LAZAREV, Pavel, I.NAZAROV, Victor, V.
    • C09K19/32
    • C09K19/52C09K2019/0496C09K2219/03G02B5/3033G02B5/3083Y10T428/31504
    • The present invention relates to an anisotropic films and method for obtaining the same. The film comprises substrate and at least one modified conjugated aromatic crystalline layer deposited onto said substrate. The said layer is characterized by globally ordered crystalline structure with intermolecular spacing of 3.4 ± 0.3 Å along one of optical axes. The modified conjugated aromatic crystalline layer is formed by rodlike supramolecules, which comprise at least one polycyclic organic compound with conjugated p-system. At least part of the modified conjugated aromatic crystalline layer has electric conductivity and is slightly soluble or insoluble in polar solvents. The films are useful in optical applications, such as polarizers and retarders, and in electronic and light emitting devices, such as fiber optics modulators and switches, solar cells, charge-coupled device (CCD), thin film transistor integrated circuits, light emitting diodes, and light emitting displays.
    • 各向异性膜及其制造方法技术领域本发明涉及各向异性膜及其制造方法。 该膜包括底物和沉积在所述基底上的至少一个改性的共轭芳族结晶层。 所述层的特征在于全局有序的晶体结构,沿着光轴之间的分子间间隔为3.4 +/- 0.3Ag。 改性共轭芳族结晶层由棒状超分子形成,其包括至少一种具有共轭p系统的多环有机化合物。 至少部分改性共轭芳族结晶层具有导电性,并且在极性溶剂中微溶或不溶。 这些膜在光学应用中是有用的,例如偏振器和延迟器,以及电子和发光器件,例如光纤调制器和开关,太阳能电池,电荷耦合器件(CCD),薄膜晶体管集成电路,发光二极管 和发光显示器。
    • 5. 发明申请
    • ORGANIC PHOTOSENSITIVE OPTOELECTRONIC DEVICE
    • 有机光敏光电子器件
    • WO2004025705A2
    • 2004-03-25
    • PCT/US2003/028778
    • 2003-09-11
    • OPTIVA, INC.LAZAREV, Pavel, I.NAZAROV, Victor, V.
    • LAZAREV, Pavel, I.NAZAROV, Victor, V.
    • H01L
    • H01L51/4246H01L27/302H01L51/0012H01L51/0037H01L51/0076H01L51/4206H01L51/424Y02E10/549Y10T428/1041
    • An organic optoelectronic device is provided which comprises a multi-layer structure and a substrate. The multi-layer structure is comprised of a first electrode layer, a second electrode layer, and at least one organic photoelectric layer. The organic photoelectric layer is an anisotropically absorbing and electrically conducting layer and comprised of rodlike supramolecules which comprise at least one polycyclic organic compound with a conjugated p-system, has a globally ordered crystal structure with an intermolecular spacing of 3.4 ± 0.3 Å along a polarization axis of the organic photoelectric layer, and absorbs electromagnetic radiation in a predetermined spectral subrange of approximately 200 to 3000 nm. The multi-layer structure is formed on one side of the substrate. At least one of the first and second electrodes is transparent for the electromagnetic radiation to which the optoelectronic device is sensitive.
    • 提供了一种有机光电子器件,其包括多层结构和衬底。 多层结构由第一电极层,第二电极层和至少一个有机光电层组成。 有机光电层是一个各向异性的吸收和导电层,由棒状超分子组成,它包含至少一种具有共轭p-系统的多环有机化合物,具有全局有序的晶体结构,分子间距为3.4μm; 0.3Å 沿着有机光电层的偏振轴,并且吸收约200至3000nm的预定光谱子范围内的电磁辐射。 多层结构形成在衬底的一侧上。 第一和第二电极中的至少一个对于光电子器件敏感的电磁辐射是透明的。
    • 9. 发明申请
    • SULFODERIVATIVES OF INDANTHRONE, LYOTROPIC LIQUID CRYSTAL SYSTEM AND ANISOTROPIC FILM ON THEIR BASE
    • IND ONE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE ASE
    • WO2003104242A2
    • 2003-12-18
    • PCT/US2003/018175
    • 2003-06-09
    • OPTIVA, INC.NAZAROV, Victor, V.SIDORENKO, Elena, N.
    • NAZAROV, Victor, V.SIDORENKO, Elena, N.
    • C07F
    • C09B5/58C09B5/56C09B67/0038C09K19/3483C09K19/603Y10T428/10Y10T428/1036Y10T428/1041
    • The present invention relates to organic chemistry, in particular, to synthesis of sulfoderivatives of the polycyclic compounds and fabrication of optically anisotropic coatings on their base.The indanthrone sulfoderivatives of the general structural formulas I or II capable of forming LLC phase are disclosed. The disclosed compounds could be used, in particular, for producing optically isotropic or anisotropic and at least partially crystalline films. The application also includes the liquid crystal systems based on the disclosed compounds, and anisotropic films. (I) (II) wherein n is 3 or 4,R = CH3, C2H5, OCH3, OC2H5, Cl, Br, OH, NH2,z is the value selected from the list including 0, 1, 2, 3, and 4, M -counterion, andj - number of counterions in a dye molecule, and which can be fractional in case of one counterion belonging to several molecules, and in case n>1, counterions may be different.
    • 本发明涉及有机化学,特别涉及多环化合物的磺基衍生物的合成和其底物上的光学各向异性涂料的制造。公开了能够形成LLC相的通式结构式I或II的阴丹酮磺化衍生物。 所公开的化合物可以特别用于制备光学各向同性或各向异性和至少部分结晶的膜。 该应用还包括基于所公开的化合物的液晶体系和各向异性薄膜。 (I)(II)其中n为3或4,R = CH 3,C 2 H 5,OCH 3,OC 2 H 5,Cl,Br,OH,NH 2,z为从包括0,1,2,3和4的列表中选择的值 ,M-对中,和 - 染料分子中的抗衡离子数,并且在一个抗衡离子属于几个分子的情况下可以是分数,并且在n≥1的情况下,抗衡离子可能不同。