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    • 1. 发明申请
    • ELECTROLYTES AND METAL HYDRIDE BATTERIES
    • 电解液和金属氢化物电池
    • WO2016077288A1
    • 2016-05-19
    • PCT/US2015/059857
    • 2015-11-10
    • BASF CORPORATIONNEI, JeanYOUNG, KwoROTAROV, Damian
    • NEI, JeanYOUNG, KwoROTAROV, Damian
    • H01M10/34H01M10/26H01M4/38
    • H01M10/26H01M4/242H01M4/381H01M10/345H01M2300/0014H01M2300/0091
    • Metal hydride batteries comprising an electrolyte composition which comprises an aqueous solution comprising one or more compounds selected from the group consisting of metal hydroxides, metal oxide/hydroxides and ammonium hydroxides where when the electrolyte composition comprises KOH, the composition also comprises a further compound selected from the group consisting of metal hydroxides, metal oxide/hydroxides and ammonium hydroxides, exhibit reduced degradation of the anode material during operation. Anode materials advantageously exhibit ≤ 95% of the degradation of the same anode material in the same battery when replacing the electrolyte composition with 6M aqueous KOH and exhibit conductivity of ≥ 50% of that of 6M aqueous KOH. Anode materials are for example ABx high capacity hydrogen storage alloys comprising Mg where x is from about 0.5 to about 5 and which has a discharge capacity of ≥ 400 mAh/g.
    • 包含电解质组合物的金属氢化物电池,其包含含有一种或多种选自金属氢氧化物,金属氧化物/氢氧化物和氢氧化铵的化合物的水溶液,其中当所述电解质组合物包含KOH时,所述组合物还包含选自 由金属氢氧化物,金属氧化物/氢氧化物和氢氧化铵组成的组在操作期间表现出降低的阳极材料的劣化。 当用6M KOH水溶液替代电解质组合物时,阳极材料有利地表现出相同电池中相同阳极材料降解的≤95%,并且显示电导率≥6MKOH水溶液的电导率≥50%。 阳极材料例如是包含Mg的ABx高容量储氢合金,其中x为约0.5至约5,并且具有≥400mAh/ g的放电容量。