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    • 3. 发明申请
    • PRODUCTION OF HYDROGEN FROM NON-CYCLIC ORGANIC SUBSTANCES HAVING MULTIPLE ALCOHOL FUNCTIONALITY
    • 从具有多种醇类功能的非循环有机物质生产氢
    • WO2007037813A2
    • 2007-04-05
    • PCT/US2006/031636
    • 2006-08-14
    • OVONIC BATTERY COMPANY, INC.REICHMAN, BenjaminMAYS, WilliamSTREBE, James
    • REICHMAN, BenjaminMAYS, WilliamSTREBE, James
    • C01B3/32
    • C01D7/07C01B3/02C01B3/323C01B2203/02C01B2203/1058C01B2203/1217C25B1/02
    • A method of producing hydrogen gas from a reaction of an organic substance having multiple alcohol functionality with a base. Hydrogen can be produced in a reaction of a base with an organic substance having multiple alcohol functionality that may proceed through the formation of a bicarbonate or carbonate compound as a byproduct. In some embodiments, the reaction may occur in the presence of water. The preferred organic substances include diols, triols, and higher order alcohols. Non-cyclic (linear or branched) organic substances having multiple alcohol functionality are among the preferred reactants. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the corresponding conventional reformation reactions of the organic substances and can produce hydrogen at less extreme reaction conditions. The preferred reactants further include low volatility organic substances having multiple alcohol functionality. Such reactants permit the efficient formation of hydrogen in a liquid phase system and enable a continuous reaction capability in the liquid phase without the need to condense volatilized reactant.
    • 从具有多个醇官能团的有机物质与碱的反应产生氢气的方法。 氢可以在碱与具有多个醇官能团的有机物质的反应中生成,所述有机物质可以通过形成作为副产物的碳酸氢盐或碳酸盐化合物而进行。 在一些实施方案中,反应可以在水的存在下进行。 优选的有机物质包括二醇,三醇和高级醇。 具有多个醇官能团的非环状(直链或支链)有机物质是优选的反应物。 本发明的碱促进的产氢反应在热力学上比有机物质的相应的常规重整反应更自发,并且可在较不极端的反应条件下产生氢。 优选的反应物还包括具有多个醇官能团的低挥发性有机物质。 这样的反应物允许在液相体系中有效地形成氢气,并且能够在液相中具有连续的反应能力,而不需要冷凝挥发的反应物。
    • 8. 发明申请
    • PRODUCTION OF HYDROGEN FROM NON-CYCLIC ORGANIC SUBSTANCES HAVING MULTIPLE ALCOHOL FUNCTIONALITY
    • 从具有多元醇官能度的非循环有机物质生产氢
    • WO2007037813A3
    • 2007-08-16
    • PCT/US2006031636
    • 2006-08-14
    • OVONIC BATTERY COREICHMAN BENJAMINMAYS WILLIAMSTREBE JAMES
    • REICHMAN BENJAMINMAYS WILLIAMSTREBE JAMES
    • C01B3/32
    • C01D7/07C01B3/02C01B3/323C01B2203/02C01B2203/1058C01B2203/1217C25B1/02
    • A method of producing hydrogen gas from a reaction of an organic substance having multiple alcohol functionality with a base. Hydrogen can be produced in a reaction of a base with an organic substance having multiple alcohol functionality that may proceed through the formation of a bicarbonate or carbonate compound as a byproduct. In some embodiments, the reaction may occur in the presence of water. The preferred organic substances include diols, triols, and higher order alcohols. Non-cyclic (linear or branched) organic substances having multiple alcohol functionality are among the preferred reactants. The instant base-facilitated hydrogen-producing reactions are thermodynamically more spontaneous than the corresponding conventional reformation reactions of the organic substances and can produce hydrogen at less extreme reaction conditions. The preferred reactants further include low volatility organic substances having multiple alcohol functionality. Such reactants permit the efficient formation of hydrogen in a liquid phase system and enable a continuous reaction capability in the liquid phase without the need to condense volatilized reactant.
    • 由具有多个醇官能团的有机物质与碱反应制备氢气的方法。 氢可以在碱与具有多个醇官能团的有机物质的反应中产生,其可以通过形成作为副产物的碳酸氢盐或碳酸盐化合物而进行。 在一些实施方案中,该反应可以在水存在下发生。 优选的有机物质包括二醇,三醇和更高级醇。 具有多个醇官能团的非环状(直链或支链)有机物质是优选的反应物之一。 与相应的常规有机物质重整反应相比,本发明碱促成的产氢反应在热力学上更自发,并且可以在不太极端的反应条件下产生氢气。 优选的反应物还包括具有多个醇官能团的低挥发性有机物质。 这种反应物允许在液相体系中有效地形成氢气,并且能够在液相中连续反应,而不需要冷凝挥发的反应物。