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    • 1. 发明授权
    • Lead-free, bismuth-free free-cutting silicon brass alloy
    • 无铅,无铋自由切割硅黄铜合金
    • US08273193B2
    • 2012-09-25
    • US12651723
    • 2010-01-04
    • Chankai XuZhenqing HuSiqi Zhang
    • Chankai XuZhenqing HuSiqi Zhang
    • C22C9/02
    • C22C9/04
    • The present invention supplies a lead-free, bismuth-free free-cutting silicon brass alloy with high zinc which preferably comprises 35.0 to 42.0 wt % Zn, 0.1 to 1.5 wt % Si, 0.03 to 0.3 wt % Al, 0.01 to 0.36 wt % P, 0.01 to 0.1 wt % Ti, 0.001 to 0.05 wt % rare earth metals selected from the group consisting of La and Ce, 0.05 to 0.5 wt % Sn, and/or 0.05 to 0.2 wt % Ni, and the balance being Cu and unavoidable impurities. In yet another embodiment, the alloy may be boron-free. The invented alloy is excellent in castability, weldability, cuttability, electroplating properties, corrosion resistance, mechanical properties. The alloy is especially applicable in castings which need cutting and welding under low pressure die casting, such as castings for faucet bodies in the water supply system. The alloy is also suitable for use in components which are produced from casting ingots by die forging.
    • 本发明提供一种含有高锌的无铅,无铋自由切割硅黄铜合金,其优选包含35.0至42.0重量%的Zn,0.1至1.5重量%的Si,0.03至0.3重量%的Al,0.01至0.36重量% P,0.01〜0.1重量%的Ti,0.001〜0.05重量%的选自La和Ce的稀土金属,0.05〜0.5重量%的Sn和/或0.05〜0.2重量%的Ni,余量为Cu和 不可避免的杂质。 在另一个实施方案中,合金可以是无硼的。 本发明的合金在铸造性,焊接性,切割性,电镀性,耐腐蚀性,机械性能方面优异。 该合金特别适用于在低压压铸中需要切割和焊接的铸件,例如供水系统中的水龙头铸件。 该合金也适用于通过模具锻造铸锭生产的部件。
    • 2. 发明授权
    • Lead-free, bismuth-free free-cutting phosphorous brass alloy
    • 无铅,无铋自由切铜黄铜合金
    • US08273192B2
    • 2012-09-25
    • US12644750
    • 2009-12-22
    • Chuankai XuZhenqing HuSiqi Zhang
    • Chuankai XuZhenqing HuSiqi Zhang
    • C22C9/04
    • C22C9/04
    • The present invention relates to a lead-free, bismuth-free free-cutting phosphorous brass alloy and its method of manufacture. The alloy comprises: Cu; Zn; 0.59 to 1.6 wt % P; and other elements in the amount of 0.005 to 0.6 wt %, which comprise at least two elements selected from the group consisting of Al, Si, Sb, Sn, Rare earth element (RE), Ti and B, and the balance being unavoidable impurities. The phosphorous brass alloy contains a combined wt % of Cu and Zn of between 97.0 wt % and 99.5 wt %, within which the content of Zn is above 40 wt %. Considering the solid solubility of P in the matrix of copper will be decreased rapidly with the temperature decrease and form the brittle intermetallic compounds Cu3P with Cu, the present invention relies upon P to ensure excellent cuttability of the invented alloy. The invented alloy is reasonably priced, and has excellent cuttability, castability, hot and cold workability, dezincification corrosion resistance, mechanical properties and weldability. The phosphorous brass alloy is a useful alloy for spare parts, forging and castings that require cutting, and particularly in forging and castings for low pressure die casting that requires cutting, grinding, welding and electroplating. The phosphorous brass alloy may also be used for faucets, valves and bushings of water supply systems, and for bar and wire materials that require high corrosion resistance and compactness.
    • 本发明涉及无铅,无铋自由切割磷铜合金及其制造方法。 该合金包括:Cu; 锌; 0.59〜1.6重量%P; 和0.005-0.6重量%的其它元素,其包含选自Al,Si,Sb,Sn,稀土元素(RE),Ti和B中的至少两种元素,余量是不可避免的杂质 。 磷黄铜合金含有Cu和Zn的组合wt%为97.0wt%至99.5wt%,其中Zn的含量高于40wt%。 考虑到铜在铜基体中的固溶度随着温度的降低而迅速降低,并与Cu形成脆性金属间化合物Cu3P,本发明依靠P来确保本发明合金的优良切割性。 本发明的合金价格合理,具有优良的切削性,铸造性,冷热加工性,脱锌腐蚀性,机械性能和焊接性。 磷黄铜合金是需要切割的备件,锻造和铸件的有用合金,特别是用于需要切割,研磨,焊接和电镀的低压压铸件的锻造和铸件。 磷黄铜合金还可用于供水系统的水龙头,阀门和衬套,以及需要高耐腐蚀性和紧凑性的棒和线材料。
    • 5. 发明申请
    • Lead-Free, Bismuth-Free Free-Cutting Phosphorous Brass Alloy And Its Manufacturing Method
    • 无铅,无铋自由切割磷黄铜合金及其制造方法
    • US20100098579A1
    • 2010-04-22
    • US12644750
    • 2009-12-22
    • Chuankai XuZhenqing HuSiqi Zhang
    • Chuankai XuZhenqing HuSiqi Zhang
    • C22C9/04
    • C22C9/04
    • The present invention relates to a lead-free, bismuth-free free-cutting phosphorous brass alloy and its method of manufacture. The alloy comprises: Cu; Zn; 0.59 to 1.6 wt % P; and other elements in the amount of 0.005 to 0.6 wt %, which comprise at least two elements selected from the group consisting of Al, Si, Sb, Sn, Rare earth element (RE), Ti and B, and the balance being unavoidable impurities. The phosphorous brass alloy contains a combined wt % of Cu and Zn of between 97.0 wt % and 99.5 wt %, within which the content of Zn is above 40 wt %. Considering the solid solubility of P in the matrix of copper will be decreased rapidly with the temperature decrease and form the brittle intermetallic compounds Cu3P with Cu, the present invention relies upon P to ensure excellent cuttability of the invented alloy. The invented alloy is reasonably priced, and has excellent cuttability, castability, hot and cold workability, dezincification corrosion resistance, mechanical properties and weldability. The phosphorous brass alloy is a useful alloy for spare parts, forging and castings that require cutting, and particularly in forging and castings for low pressure die casting that requires cutting, grinding, welding and electroplating. The phosphorous brass alloy may also be used for faucets, valves and bushings of water supply systems, and for bar and wire materials that require high corrosion resistance and compactness.
    • 本发明涉及一种无铅,无铋自由切割磷铜合金及其制造方法。 该合金包括:Cu; 锌; 0.59〜1.6重量%P; 和0.005-0.6重量%的其它元素,其包含选自Al,Si,Sb,Sn,稀土元素(RE),Ti和B中的至少两种元素,余量是不可避免的杂质 。 磷黄铜合金含有Cu和Zn的组合wt%为97.0wt%至99.5wt%,其中Zn的含量高于40wt%。 考虑到铜在铜基体中的固溶度随着温度的降低而迅速降低,并与Cu形成脆性金属间化合物Cu3P,本发明依靠P来确保本发明合金的优良切割性。 本发明的合金价格合理,具有优良的切削性,铸造性,冷热加工性,脱锌腐蚀性,机械性能和焊接性。 磷黄铜合金是需要切割的备件,锻造和铸件的有用合金,特别是用于需要切割,研磨,焊接和电镀的低压压铸件的锻造和铸件。 磷黄铜合金还可用于供水系统的水龙头,阀门和衬套,以及需要高耐腐蚀性和紧凑性的棒和线材料。
    • 6. 发明申请
    • LEAD-FREE FREE-CUTTING MAGNESIUM BRASS ALLOY AND ITS MANUFACTURING METHOD
    • 无铅自由切割镁合金及其制造方法
    • US20090311127A1
    • 2009-12-17
    • US12354582
    • 2009-01-15
    • Chuankai XuZhenging HuSiqi Zhang
    • Chuankai XuZhenging HuSiqi Zhang
    • C22C9/04B22D7/00
    • C22C9/04C22F1/08
    • A lead-free free-cutting magnesium brass alloy comprises 56.0 to 64.0 wt % Cu, 0.6 to 2.5 wt % Mg, 0.15 to 0.4 wt % P and other elements 0.002 to 0.9 wt % which comprise at least two elements selected from the group consisting of Al, Si, Sb, Sn, Re, Ti and B and the balance being Zn and unavoidable impurities. The process for producing such alloy is also proposed. The invented alloy is excellent in cuttability, castability, hot and cold workability, corrosion resistance, mechanical properties and weldability and particularly applicable in spare parts, forging and castings which need cutting, grinding and electroplating process. The cost of necessary metal materials of the invented alloy is lower than lead-free free-cutting bismuth and antimony brass alloy and is equivalent to lead-contained brass alloy.
    • 无铅自由切割镁黄铜合金包含56.0至64.0重量%的Cu,0.6至2.5重量%的Mg,0.15至0.4重量%的P和0.002至0.9重量%的其它元素,其包含至少两种选自以下的元素: 的Al,Si,Sb,Sn,Re,Ti和B,余量为Zn和不可避免的杂质。 还提出了生产这种合金的方法。 本发明的合金的切削性,浇铸性,冷加工性,耐腐蚀性,机械性能和焊接性优异,特别适用于需要切割,研磨和电镀工艺的备件,锻造和铸件。 本发明合金所需金属材料的成本低于无铅自由切割铋和锑黄铜合金,相当于含铅黄铜合金。
    • 7. 发明申请
    • Lead-Free Free-Cutting Aluminum Brass Alloy And Its Manufacturing Method
    • 无铅自由切割铝黄铜合金及其制造方法
    • US20100155011A1
    • 2010-06-24
    • US12644254
    • 2009-12-22
    • Chuankai XuZhenqing HuSiqi Zhang
    • Chuankai XuZhenqing HuSiqi Zhang
    • B22D11/00C22C9/01B22D17/02C22C9/00C22C9/02C22C9/04
    • B22D11/004B22D21/027C22C9/00C22C9/01
    • The present invention provides a lead-free free-cutting aluminum brass alloy and its manufacturing method. The alloy comprises: 57.0˜63.0 wt % Cu, 0.3˜0.7 wt % Al, 0.1˜0.5 wt % Bi, 0.2˜0.4 wt % Sn, 0.1˜0.5 wt % Si, 0.01˜0.15 wt % P, at least two elements selected from the group of 0.01-0.15 wt % Mg, 0.0016-0.0020 wt % B, and 0.001-0.05 wt % rare earth elements and the balance being Zn and unavoidable impurities. The inventive alloy has excellent castability, weldability, cuttability and corrosion resistance. It is suitable for low pressure die casting, gravity casting, horizontal continuous casting, forging and extrusion. Its metal material cost is lower than bismuth brass. It is particularly applicable for components used in drinking water supply systems and other structural components. It is a new environmentally-friendly free-cutting aluminum brass alloy.
    • 本发明提供一种无铅自由切割铝黄铜合金及其制造方法。 该合金包括:57.0〜63.0重量%的Cu,0.3〜0.7重量%的Al,0.1〜0.5重量%的Bi,0.2〜0.4重量%的Sn,0.1〜0.5重量%的Si,0.01〜0.15重量%的P, 选自0.01-0.15重量%Mg,0.0016-0.0020重量%B和0.001-0.05重量%稀土元素,余量为Zn和不可避免的杂质。 本发明合金具有优异的浇铸性,焊接性,切割性和耐腐蚀性。 适用于低压压铸,重力铸造,卧式连铸,锻压挤压。 其金属材料成本低于铋黄铜。 它特别适用于饮用水供应系统和其他结构部件中使用的部件。 它是一种新型环保型自由切割铝黄铜合金。
    • 8. 发明申请
    • Lead-free free-cutting silicon brass alloy
    • 无铅自由切割硅黄铜合金
    • US20100135848A1
    • 2010-06-03
    • US12407720
    • 2009-03-19
    • Chuankai XuZhenqing HuSiqi Zhang
    • Chuankai XuZhenqing HuSiqi Zhang
    • C22C9/04
    • C22C9/04
    • The present invention supplies a lead-free free-cutting silicon brass alloy with high zinc which preferably comprises 35.0 to 42.0 wt % Zn, 0.1 to 1.5 wt % Si, 0.03 to 0.3 wt % Al, 0.01 to 0.36 wt % P, 0.01 to 0.1 wt % Ti, 0.001 to 0.05 wt % rare earth metals selected from the group consisting of La and Ce, 0.05 to 0.5 wt % Sn, and/or 0.05 to 0.2 wt % Ni, and the balance being Cu and unavoidable impurities. The invented alloy is excellent in castability, weldability, cuttability, electroplating properties, corrosion resistance, mechanical properties. The alloy is especially applicable in castings which need cutting and welding under low pressure die casting, such as castings for faucet bodies in the water supply system. The alloy is also suitable for use in components which are produced from casting ingots by die forging.
    • 本发明提供一种具有高锌的无铅自由切割硅黄铜合金,其优选包含35.0至42.0重量%的Zn,0.1至1.5重量%的Si,0.03至0.3重量%的Al,0.01至0.36重量%的P,0.01至 0.1重量%的Ti,0.001〜0.05重量%的选自La和Ce的稀土金属,0.05〜0.5重量%的Sn和/或0.05〜0.2重量%的Ni,余量为Cu和不可避免的杂质。 本发明的合金在铸造性,焊接性,切割性,电镀性,耐腐蚀性,机械性能方面优异。 该合金特别适用于在低压压铸中需要切割和焊接的铸件,例如供水系统中的水龙头铸件。 该合金也适用于通过模具锻造铸锭生产的部件。
    • 10. 发明授权
    • Brass alloys having superior stress corrosion resistance and manufacturing method thereof
    • 具有优异的耐应力腐蚀性的黄铜合金及其制造方法
    • US08580191B2
    • 2013-11-12
    • US12928428
    • 2010-12-09
    • Chuankai XuZhenqing HuSiqi Zhang
    • Chuankai XuZhenqing HuSiqi Zhang
    • C22C9/00B22D7/00B22D11/00
    • C22C9/04C22F1/08
    • The present invention relates to a brass alloy having superior stress corrosion comprising: 59.0-64.0 wt % Cu, 0.6-1.2 wt % Fe, 0.6-1.0 wt % Mn, 0.4-1.0 wt % Bi, 0.6-1.4 wt % Sn, at least one element selected from Al, Cr and B, the balance being Zn and unavoidable impurities, wherein the content of Al is 0.1-0.8 wt %, the content of Cr is 0.01-0.1 wt %, the content of B is 0.001-0.02 wt %. The alloy according to the present invention does not contain toxic elements such as lead and antimony, has superior corrosion resistance and good cuttingability and is suitable for the accessories in the potable water supply systems produced by casting, forging and extruding.
    • 本发明涉及一种具有优异应力腐蚀性的黄铜合金,其包括:59.0-64.0重量%的Cu,0.6-1.2重量%的Fe,0.6-1.0重量%的Mn,0.4-1.0重量%的Bi,0.6-1.4重量%的Sn, 选自Al,Cr和B中的至少一种元素,余量为Zn和不可避免的杂质,其中Al的含量为0.1-0.8重量%,Cr的含量为0.01-0.1重量%,B的含量为0.001-0.02 重量%。 根据本发明的合金不含有铅,锑等有毒元素,具有优异的耐腐蚀性和良好的切割性,适用于通过铸造,锻造和挤压生产的饮用水供给系统中的附件。