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1. 发明专利

DE952666C 未知
公开(公告)号：DE952666C
公开(公告)日：1956-11-22
申请号：DEN0005783
申请日：1952-07-13
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS

2. 发明专利

DE968105C 未知
公开(公告)号：DE968105C
公开(公告)日：1958-01-23
申请号：DEN0007723
申请日：1952-11-07
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS , PEL WILLEM ALBERTUS
IPC分类号： A01N47/42

3. 发明专利

DE818121C 未知
公开(公告)号：DE818121C
公开(公告)日：1951-10-22
申请号：DEN0000598
申请日：1950-03-10
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS
IPC分类号： C08C19/20
摘要： Unsaturated polymeric materials having molecular weights of at least 5000 are reacted with sulphur dioxide in the presence of a chlorine oxide, e.g. chlorine peroxide and chlorine heptoxide. Examples of polymers include those of butadiene, methyl butadiene and chloroprene, copolymers of these with each other and with isobutylene, styrene and vinyl chloride, and polymers of acetylene. Low molecular weight unsaturated compounds such as butadiene, 1 : 5 - hexadiene and diallyl phthalate may also take part in the reaction. The chlorine oxide is preferably added in the form of a solution in a halogenated hydrocarbon to a solution of the polymer in a solvent which is miscible with the halogenated hydrocarbon. The mixture may be poured or extruded into a solution of sulphur dioxide, forming by the latter method threads, fibres and tapes. The polymeric materials may be treated with a mild oxidizing agent such as hydrogen peroxide or hypochlorous acid before adding the chlorine oxide.

4. 发明专利

DE971267C 未知
公开(公告)号：DE971267C
公开(公告)日：1958-12-31
申请号：DEN0006138
申请日：1952-09-27
申请人： BATAAFSCHE PETROLEUM
发明人： DIERICK GERARDA FRANCISCA ELIS , HACKMANN JOHANNES THOMAS , HAKEN PIETER TEN

5. 发明专利

DE970787C 未知
公开(公告)号：DE970787C
公开(公告)日：1958-10-30
申请号：DEN0009361
申请日：1954-08-20
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS , DOST NICOLAAS
IPC分类号： A01N47/42

6. 发明专利

DE956548C 未知
公开(公告)号：DE956548C
公开(公告)日：1957-01-17
申请号：DEN0006135
申请日：1952-09-26
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS

7. 发明专利

DE947209C 未知
公开(公告)号：DE947209C
公开(公告)日：1956-08-09
申请号：DEN0006104
申请日：1952-09-21
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS , PEL WILLEM ALBERTUS
IPC分类号： A01N47/42

8. 发明专利

DE742255C 未知
公开(公告)号：DE742255C
公开(公告)日：1943-12-01
申请号：DEN0045102
申请日：1941-09-26
申请人： BATAAFSCHE PETROLEUM
发明人： OVERHOFF JOHAN , HACKMANN JOHANNES THOMAS
IPC分类号： C01B21/082 , C01B21/092 , C07D213/73

9. 发明专利

DE940554C 未知
公开(公告)号：DE940554C
公开(公告)日：1956-03-22
申请号：DEN0004949
申请日：1952-01-09
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS
IPC分类号： A01N47/42

10. 发明专利

DE813893C 未知
公开(公告)号：DE813893C
公开(公告)日：1951-09-17
申请号：DEN0000030
申请日：1949-10-11
申请人： BATAAFSCHE PETROLEUM
发明人： HACKMANN JOHANNES THOMAS , RUMSCHEIDT GOTTFRIED ERNST
IPC分类号： C08C19/20
摘要： Polydienes are reacted with sulphur dioxide in the presence of a hydroperoxide derived from a hydrocarbon containing at least one aliphatic chain containing not more than three carbon atoms and one or more aromatic nuclei. The term "polydienes" signifies polymers, having a number of unsaturated carbon-to-carbon bonds and a molecular weight above 5000, derived from dienes such as butadiene, pentadiene, isoprene and chloroprene, alone or with vinyl compounds, e.g. styrene and acrylonitrile, and includes natural rubber, guttapercha and balata. Specified hydroperoxides are ethylbenzene-, diethylbenzene-, xylene-, triphenylmethyl- and cumene hydroperoxides. The reaction products may be obtained in the form of threads, fibres, ribbons, films and foils by extruding a solution of the polydiene and hydroperoxide into a solution of sulphur dioxide. The polydienes may be mixed with low molecular unsaturated compounds, e.g. alkadienes and allyl compounds, as described in Specification 659,083. The examples describe the reaction of plasticized natural rubber, dissolved in a mixture of benzene and toluene, with sulphur dioxide dissolved in ethanol and water, at a temperature of -5 DEG C. The coagulated threads, after washing with ethanol and drying, have a sulphur content of 21 per cent.

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