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    • 3. 发明申请
    • MAGNESIUM BATTERY ELECTROLYTE
    • 镁电池电解液
    • US20140147754A1
    • 2014-05-29
    • US14232732
    • 2012-07-30
    • Jun YangYongsheng GuoFan ZhangFeifei Wang
    • Jun YangYongsheng GuoFan ZhangFeifei Wang
    • H01M10/0568
    • H01M10/0568H01M10/054H01M10/0569H01M2300/0037
    • A magnesium battery electrolyte with a wide electrochemical window was developed. The electrolyte includes an organic boron magnesium salt and an aprotic polar solvent. The organic boron magnesium salt is an organic boron magnesium salt complex formed by compounding a Lewis acid with a boron center and a magnesium-containing Lewis base R′2-nMgXn, wherein n is 0 or 1, R and R′ respectively represent a fluoroaryl group, an alkylated aryl group, an aryl group, an alkyl group, or a pyrrolidinyl group, and X represents a halogen. The solvent is an aprotic polar solvent such as ether or a mixed solvent thereof. The concentration of the electrolyte is 0.25 to 1 mol/L, and the electric conductivity is 0.5 to 10 mS/cm. The electrolyte allows reversible deposition/dissolution of magnesium, features good cycling stability, and has a wide electrochemical window (>3.0V vs.Mg/Mg2+).
    • 开发了具有宽电化学窗口的镁电池电解质。 电解质包括有机硼镁盐和非质子极性溶剂。 有机硼镁盐是通过将路易斯酸与硼中心配合而形成的有机硼镁盐络合物和含镁的路易斯碱R'2-nMgXn,其中n为0或1,R和R'分别表示氟代芳基 基团,烷基化芳基,芳基,烷基或吡咯烷基,X表示卤素。 溶剂是非质子极性溶剂如醚或其混合溶剂。 电解液的浓度为0.25〜1mol / L,电导率为0.5〜10mS / cm。 电解液允许镁的可逆沉积/溶解,具有良好的循环稳定性,并且具有宽的电化学窗口(> 3.0V vs.Mg/Mg2+)。