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    • 5. 发明专利
    • Polylactic acid-based resin composition, molded product and method for producing the same
    • 基于聚氨酯的树脂组合物,模制产品及其生产方法
    • JP2007332164A
    • 2007-12-27
    • JP2004256508
    • 2004-09-03
    • Adeka CorpToyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社Adeka株式会社豊田中央研究所
    • HIDA ETSUOKAWAMOTO HISAFUMIURUSHIBARA TAKESHISAITO HITOSHIOKUYAMA HISATSUGUKANAMORI KENJINAKANO MITSURUOKAMOTO HIROTAKA
    • C08L67/04B29C45/73B29C45/76B29K67/00C08K3/34C08K5/25C08L101/16
    • C08K5/25C08K3/34C08L67/04
    • PROBLEM TO BE SOLVED: To provide a polylactic acid-based resin composition affording a molded product having excellent heat resistance and impact strength with good moldability, to provide a heat-resistant polylactic acid-based resin molded product composed of the polylactic acid-based resin composition and to provide a method for producing the polylactic acid-based resin molded product.
      SOLUTION: The polylactic acid-based resin composition is obtained by compounding a polylactic acid with a dibasic acid bis(benzoic acid hydrazide) compound represented by general formula (I) (wherein, R represents a 1-12C alkylene group, an alkenylene group, a cycloalkylene group or an alkylene group having an ether bond; R
      1 , R
      2 , R
      3 and R
      4 represent each a hydrogen atom, a halogen atom, a 1-12C alkyl group, a cycloalkyl group, an aryl group, an arylalkyl group or an alkylaryl group or R
      1 and R
      2 and/or R
      3 and R
      4 are bound to form a 5- to an 8-membered ring). The method for producing the heat-resistant polylactic acid-based resin molded product comprises melting the polylactic acid-based resin composition, filling a metal mold of a molding machine set within the range of not higher than the crystallization starting temperature to not lower than the glass transition temperature with the molten polylactic acid-based resin composition and molding the composition while crystallizing the composition.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 解决问题的方案为了提供具有优异耐热性和冲击强度以及良好成型性的成型体的聚乳酸系树脂组合物,提供由聚乳酸组成的耐热性聚乳酸类树脂成型体 并提供聚乳酸类树脂成型体的制造方法。 聚乳酸类树脂组合物通过将聚乳酸与通式(I)表示的二元酸双(苯甲酸酰肼)化合物(其中,R表示1-12个亚烷基, 亚烯基,亚环烷基或具有醚键的亚烷基; R 1,R 2,R SP 3,R SP 3, 代表氢原子,卤素原子,1-12C烷基,环烷基,芳基,芳基烷基或烷基芳基,或者R > 2 和/或R 3 和R 4 结合形成5-至8-元环)。 制造耐热性聚乳酸类树脂成型体的方法包括使聚乳酸类树脂组合物熔融,将成型机的金属模填充在不高于结晶起始温度的范围内,成为不低于 玻璃化转变温度与熔融的聚乳酸类树脂组合物接触并在组合物结晶的同时模塑该组合物。 版权所有(C)2008,JPO&INPIT