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1. 发明专利

BR8306767A 未知
公开(公告)号：BR8306767A
公开(公告)日：1984-07-31
申请号：BR8306767
申请日：1983-12-09
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F4/00 , C08F4/60 , C08F36/00 , C08F136/06 , C08F4/64
摘要： This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in tetrahydrofuran comprising polymerizing 1,3-butadiene in said tetrahydrofuran in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoXn, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amines, alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide. This polymerization technique is very useful in the synthesis of syndiotactic 1,2-polybutadiene which will be used in articles for packaging, transportation, or storing of foods since it employs tetrahydrofuran as its polymerization medium.

2. 发明专利

AU2251383A BUTADIENE POLYMERISATION 未知
公开(公告)号：AU2251383A
公开(公告)日：1984-06-28
申请号：AU2251383
申请日：1983-12-19
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F4/00 , C08F4/60 , C08F36/00 , C08F136/06 , C08F4/70
摘要： This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in tetrahydrofuran comprising polymerizing 1,3-butadiene in said tetrahydrofuran in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoXn, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amines, alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide. This polymerization technique is very useful in the synthesis of syndiotactic 1,2-polybutadiene which will be used in articles for packaging, transportation, or storing of foods since it employs tetrahydrofuran as its polymerization medium.

3. 发明专利

DE3371524D1 SYNDIOTACTIC 1,2-POLYBUTADIENE SYNTHESIS PROCESS 未知
公开(公告)号：DE3371524D1
公开(公告)日：1987-06-19
申请号：DE3371524
申请日：1983-12-16
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F4/00 , C08F4/60 , C08F36/00 , C08F136/06
摘要： This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in tetrahydrofuran comprising polymerizing 1,3-butadiene in said tetrahydrofuran in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoXn, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amines, alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide. This polymerization technique is very useful in the synthesis of syndiotactic 1,2-polybutadiene which will be used in articles for packaging, transportation, or storing of foods since it employs tetrahydrofuran as its polymerization medium.

4. 发明专利

ZA836676B MICROENCAPSULATED AQUEOUS POLYMERIZATION CATALYST 未知
公开(公告)号：ZA836676B
公开(公告)日：1984-06-27
申请号：ZA836676
申请日：1983-09-08
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , DONBAR KEN WEIKART , BELL ANTHONY JOSEPH , HENDERSON JAMES NEIL
IPC分类号： C08F4/00 , B01J33/00 , C08F2/18 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/70 , C08F36/00 , C08F36/04 , C08F136/06 , C08F
摘要： The present invention discloses an aqueous polymerization medium comprising (1) a catalyst composition which contains (a) an organometallic compound and (b) a transition metal compound wherein said catalyst composition is microencapsulated in a polyene product; and (2) water. This invention also discloses an aqueous polymerization medium comprising (1) a catalyst composition which is prepared by dissolving in an inert organic solvent containing at least one polyene (a) a transition metal compound, and (b) an organometallic compound; and (2) water. This aqueous polymerization medium is very useful in the polymerization of unsaturated hydrocarbon monomers. It is of greatest value in the polymerization of conjugated diolefin monomers into stereo-regulated polymers. This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in an aqueous medium comprising polymerizing 1,3-butadiene in said aqueous medium in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoX n, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide.

5. 发明专利

AU558298B2 BUTADIENE POLYMERISATION 未知
公开(公告)号：AU558298B2
公开(公告)日：1987-01-22
申请号：AU2251383
申请日：1983-12-19
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F4/00 , C08F4/60 , C08F36/00 , C08F136/06 , C08F4/70
摘要： This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in tetrahydrofuran comprising polymerizing 1,3-butadiene in said tetrahydrofuran in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoXn, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amines, alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide. This polymerization technique is very useful in the synthesis of syndiotactic 1,2-polybutadiene which will be used in articles for packaging, transportation, or storing of foods since it employs tetrahydrofuran as its polymerization medium.

6. 发明专利

BR8304990A 未知
公开(公告)号：BR8304990A
公开(公告)日：1984-09-04
申请号：BR8304990
申请日：1983-09-15
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F4/00 , B01J33/00 , C08F2/18 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/70 , C08F36/00 , C08F36/04 , C08F136/06 , C08F4/42 , C08F2/16
摘要： The present invention discloses an aqueous polymerization medium comprising (1) a catalyst composition which contains (a) an organometallic compound and (b) a transition metal compound wherein said catalyst composition is microencapsulated in a polyene product; and (2) water. This invention also discloses an aqueous polymerization medium comprising (1) a catalyst composition which is prepared by dissolving in an inert organic solvent containing at least one polyene (a) a transition metal compound, and (b) an organometallic compound; and (2) water. This aqueous polymerization medium is very useful in the polymerization of unsaturated hydrocarbon monomers. It is of greatest value in the polymerization of conjugated diolefin monomers into stereo-regulated polymers. This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in an aqueous medium comprising polymerizing 1,3-butadiene in said aqueous medium in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoX n, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide.

7. 发明专利

AU1866083A MICROENCAPSULATED AQUEOUS POLYMERISATION CATALYST 未知
公开(公告)号：AU1866083A
公开(公告)日：1984-03-22
申请号：AU1866083
申请日：1983-09-02
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F4/00 , B01J33/00 , C08F2/18 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/70 , C08F36/00 , C08F36/04 , C08F136/06 , C08F110/14 , C08F132/04 , C08F132/06
摘要： The present invention discloses an aqueous polymerization medium comprising (1) a catalyst composition which contains (a) an organometallic compound and (b) a transition metal compound wherein said catalyst composition is microencapsulated in a polyene product; and (2) water. This invention also discloses an aqueous polymerization medium comprising (1) a catalyst composition which is prepared by dissolving in an inert organic solvent containing at least one polyene (a) a transition metal compound, and (b) an organometallic compound; and (2) water. This aqueous polymerization medium is very useful in the polymerization of unsaturated hydrocarbon monomers. It is of greatest value in the polymerization of conjugated diolefin monomers into stereo-regulated polymers. This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in an aqueous medium comprising polymerizing 1,3-butadiene in said aqueous medium in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoX n, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide.

8. 发明专利

DE3376425D1 MICROENCAPSULATED AQUEOUS POLYMERIZATION CATALYST 未知
公开(公告)号：DE3376425D1
公开(公告)日：1988-06-01
申请号：DE3376425
申请日：1983-09-07
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F4/00 , B01J33/00 , C08F2/18 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/70 , C08F36/00 , C08F36/04 , C08F136/06
摘要： The present invention discloses an aqueous polymerization medium comprising (1) a catalyst composition which contains (a) an organometallic compound and (b) a transition metal compound wherein said catalyst composition is microencapsulated in a polyene product; and (2) water. This invention also discloses an aqueous polymerization medium comprising (1) a catalyst composition which is prepared by dissolving in an inert organic solvent containing at least one polyene (a) a transition metal compound, and (b) an organometallic compound; and (2) water. This aqueous polymerization medium is very useful in the polymerization of unsaturated hydrocarbon monomers. It is of greatest value in the polymerization of conjugated diolefin monomers into stereo-regulated polymers. This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in an aqueous medium comprising polymerizing 1,3-butadiene in said aqueous medium in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoX n, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide.

9. 发明专利

AU556017B2 MICROENCAPSULATED AQUEOUS POLYMERISATION CATALYST 未知
公开(公告)号：AU556017B2
公开(公告)日：1986-10-16
申请号：AU1866083
申请日：1983-09-02
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , BELL ANTHONY JOSEPH , DONBAR KEN WEIKART , HENDERSON JAMES NEIL
IPC分类号： C08F4/00 , B01J33/00 , C08F2/18 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/70 , C08F36/00 , C08F36/04 , C08F136/06 , C08F110/14 , C08F132/04 , C08F132/06
摘要： The present invention discloses an aqueous polymerization medium comprising (1) a catalyst composition which contains (a) an organometallic compound and (b) a transition metal compound wherein said catalyst composition is microencapsulated in a polyene product; and (2) water. This invention also discloses an aqueous polymerization medium comprising (1) a catalyst composition which is prepared by dissolving in an inert organic solvent containing at least one polyene (a) a transition metal compound, and (b) an organometallic compound; and (2) water. This aqueous polymerization medium is very useful in the polymerization of unsaturated hydrocarbon monomers. It is of greatest value in the polymerization of conjugated diolefin monomers into stereo-regulated polymers. This invention reveals a very useful process for producing polybutadiene composed essentially of syndiotactic 1,2-polybutadiene in an aqueous medium comprising polymerizing 1,3-butadiene in said aqueous medium in the presence of (1) a catalyst composition microencapsulated in a polyene product which contains (a) at least one cobalt compound selected from the group consisting of (i) beta -diketone complexes of cobalt, (ii) beta -keto acid ester complexes of cobalt, (iii) cobalt salts of organic carboxylic acids having 6 to 15 carbon atoms, and (iv) complexes of halogenated cobalt compounds of the formula CoX n, wherein X represents a halogen atom and n represents 2 or 3, with an organic compound selected from the group consisting of tertiary amine alcohols, tertiary phosphines, ketones and N,N-dialkylamides, and (b) at least one organoaluminum compound of the formula AlR3, wherein R represents a hydrocarbon radical of 1 to 6 carbon atoms; and (2) carbon disulfide.

10. 发明专利

ZA8306676B MICROENCAPSULATED AQUEOUS POLYMERIZATION CATALYST 未知
公开(公告)号：ZA8306676B
公开(公告)日：1984-06-27
申请号：ZA8306676
申请日：1983-09-08
申请人： GOODYEAR TIRE & RUBBER
发明人： BARBOUR JOHN JOSEPH , DONBAR KEN WEIKART , BELL ANTHONY JOSEPH , HENDERSON JAMES NEIL
IPC分类号： C08F4/00 , B01J33/00 , C08F2/18 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/70 , C08F36/00 , C08F36/04 , C08F136/06 , C08F
CPC分类号： C08F36/04 , B01J33/00 , C08F136/06 , C08F2/16 , C08F4/7096

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