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    • 7. 发明专利
    • NOVEL BENZIMIDAZOLES
    • ZA734064B
    • 1974-04-24
    • ZA734064
    • 1973-06-15
    • HOECHST AG
    • GOEBEL HBOECHLING HHAERTEL K
    • A01N47/18C07D235/32
    • 1377354 2 - Methoxycarbonylamino - benzimidazole derivatives FARBWERKE HOECHST AG 19 June 1973 [21 June 1972] 29008/73 Heading C2C Novel 2 - methoxycarbonylamino - benzimidazole derivatives having the general formula wherein each of R 1 and R 2 is a (C 1 -C 18 ) alky group, (C 3 -C 18 ) alkenyl group, (C 4 -C 8 ) cycloalkyl group, a cycloalkylalkyl or alkylcycloalkyl group having 5 or 6 ring carbon atoms and from 1 to 3 carbon atoms in the alkyl or alkylene moiety, a (C 2 -C 12 ) alkoxyalkyl or alkylthioalkyl group, a (C 3 -C 9 ) carboalkoxyalkyl group, a cyanoethyl, phenyl, benzyl or phenethyl group, or R 1 is a (C 1 -C 4 ) alkoxy group, or R 1 and R 2 together form a (C 4 -C 7 ) alkylene group optionally interrupted by O, S, or substituted by methyl or ethyl groups or bridged by a methylene group, are prepared by reacting 2-methoxycarbonylamino benzimidazole with formaldehyde and a secondary amine of the formula The reaction is preferably carried out in a solvent using a one or two molar amount of the amine and, while stirring, a one to four molar amount of gaseous formaldehyde or an aqueous formaldehyde solution at a temperature of from 0‹ to 80‹ C. The novel compounds possess fungicidal or anthelmintic properties.
    • 10. 发明专利
    • DK137538B
    • 1978-03-20
    • DK276573
    • 1973-05-17
    • HOECHST AG
    • ROECHLING HHAERTEL K
    • C07D471/04A01N47/16A01N57/24C07D487/04C07F9/6561A01N9/22
    • 1377458 Triazino-benzimidazoles FARBWERKE HOECHST AG 15 May 1973 [18 May 1972 19 Feb 1973] 23108/73 Headings C2C and C2P Novel triazino-benzimidazoles of the formula wherein R represents an alkyl group having from 1 to 18 carbon atoms; an alkenyl group having from 3 to 18 carbon atoms, an alkinyl group having from 2 to 8 carbon atoms, a cycloalkyl group having from 3 to 12 carbon atoms, which may be substituted by one or more alkyl groups having from 1 to 4 carbon atoms or by a hydroxy group; a cyclohexylalkyl, cyclohexylalkenyl, or cyclohexylalkinyl group each having from 1 to 3 carbon atoms in the aliphatic chain, an endomethylene-cyclohexylmethyl, endomethylene - cyclohexenylmethyl, tricyelodecyl, or tricyclodecenyl group; a phenylalkyl, diphenylalkyl or triphenylalkyl group each having from I to 6 carbon atoms in the alkyl radical, the phenyl nucleus being unsubstituted or substituted by a halogen atom or an alkyl, alkoxy or alkylthio group each having from 1 to 4 carbon atoms or a di-(C 1 -C 4 )- amino group; a phenyl or naphthyl group, which may be substituted by an alkyl group having from 1 to 4 carbon atoms, a halogen atom, a halogeno-alkyl group having from 1 to 4 carbon atoms, a trifluoromethyl or hydroxyl group, an alkoxy group having from 1 to 4 carbon atoms, a phenoxy or (C 1 -C 4 )-alkylthio group; a di-(C 1 -C 4 )-alkyl-amino-(C 2 -C 6 ). alkyl group; a hydroxy-(C 2 -C 12 )-alkyl, (C 2 - C 18 )-alkoxyalkyl or dialkoxyalkyl group, a (C 2 -C 18 ) - alkylmercaptoalkyl, (C 3 -C 9 )- dialkylphosphinyl - alkyl, furfuryl - alkyl, morpholino - (C 1 -C 4 ) - alkyl pyrrolidino- (C 1 -C 4 ) - alkyl, piperidino - (C 1 -C 4 ) - alkyl or (C 2 -C 12 )-carbalkoxyalkyl group, are prepared by reacting 2-methoxycarbonylaminobenzimidazole with an amine of the formula R.NH 2 and formaldehyde. The reaction is preferably carried out in a solvent at a temperature of from 0‹ to 80‹ C. The novel compounds possess fungicidal and anthelmintic properties.