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    • 4. 发明申请
    • MODIFIED CARBON NANOTUBES AND THEIR COMPATIBILITY
    • 改性碳纳米管及其相容性
    • WO2011153629A1
    • 2011-12-15
    • PCT/CA2011/000683
    • 2011-06-10
    • NATIONAL RESEARCH COUNCIL OF CANADAGUAN, JingwenANDERSON, RobinSIMARD, Benoit
    • GUAN, JingwenANDERSON, RobinSIMARD, Benoit
    • C09C1/44C08K9/04C09C3/10C08J5/06C01B31/00
    • C08F226/02B82Y30/00B82Y40/00C01B32/174C01B2202/02C01B2202/06C01P2002/88C01P2004/03C01P2004/04C09C1/44Y10S977/746
    • Modified carbon nanotubes are provided having carbon nanotube core covalently bound through C-C bonds to a polymer shell surrounding the carbon nanotube core. The polymer shell is a polymer having functional groups pointing outwardly from the shell. The functional groups are compatible with or able to covalently connect to another polymer. Such modified carbon nanotubes are more readily dispersed in a homogeneous manner in another polymer and may be used as a reinforcing filler in a polymer matrix. The modified carbon nanotubes with a core-shell structure in which the core has a substantially unidirectional orientation within the shell are produced by reacting neutral carbon nanotubes with 4-vinylaniline through a diazonium reaction in presence of one or more types of multifunctional monomers carrying a vinyl moiety and one or more functional groups for compatibilization with or connection to another polymer. The reaction is conducted at an elevated temperature without isolation of intermediates and without addition of any extra initiator or catalyst to form a polymer shell in situ around the carbon nanotube. The polymer shell is covalently bound to CNT sidewall through C-C bonds and has functional groups outwardly pointing from the shell for compatibilization with or connection to another polymer.
    • 提供了具有通过C-C键共价键合到碳纳米管芯周围的聚合物壳的碳纳米管芯的改性碳纳米管。 聚合物壳是具有从壳向外指向的官能团的聚合物。 官能团与另一种聚合物相容或能够共价连接。 这种改性碳纳米管更容易以均匀的方式分散在另一种聚合物中,并且可以用作聚合物基质中的增强填料。 具有核 - 壳结构的改性碳纳米管通过在一种或多种携带乙烯基的多官能单体的存在下,通过重氮反应将中性碳纳米管与4-乙烯基苯胺反应,从而制备芯在壳内具有基本上单向取向 部分和一个或多个用于与另一种聚合物相容或连接的官能团。 反应在升高的温度下进行,而不分离中间体,并且不加入任何额外的引发剂或催化剂以在碳纳米管周围原位形成聚合物壳。 聚合物壳通过C-C键共价结合到CNT侧壁上,并且具有从壳体向外指向的与另一种聚合物增容或连接的官能团。
    • 9. 发明申请
    • PROCESS FOR PURIFYING SEMICONDUCTING SINGLE-WALLED CARBON NANOTUBES
    • 净化半导体碳纳米管的工艺
    • WO2015024115A1
    • 2015-02-26
    • PCT/CA2014/050788
    • 2014-08-18
    • NATIONAL RESEARCH COUNCIL OF CANADA
    • DING, JianfuMALENFANT, PatrickLI, ZhaoLEFEBVRE, JacquesCHENG, FuyongSIMARD, Benoit
    • B01D11/00B82Y30/00
    • B82Y30/00B01D11/0257B01D11/0265B82Y40/00
    • A two-step sc-SWCNT enrichment process involves a first step based on selective dispersion and extraction of semiconducting SWCNT using conjugated polymer followed by a second step based on an adsorptive process in which the product of the first step is exposed to an inorganic absorptive medium to selectively bind predominantly metallic SWCNTs such that what remains dispersed in solution is further enriched in semiconducting SWCNTs. The process is easily scalable for large-diameter semi- conducting single-walled carbon nanotube (sc-SWCNT) enrichment with average diameters in a range, for example, of about 0.6 to 2.2 nm. The first step produces an enriched sc-SWCNT dispersion with a moderated sc-purity (98%) at a high yield, or a high purity (99% and up) at a low yield. The second step can not only enhance the purity of the polymer enriched sc-SWCNTs with a moderate purity, but also further promote the highly purified sample to an ultra-pure level. Therefore, this two-step hybrid process provides sc-SWCNT materials with a super high purity, as well as both a high sc-purity (for example greater than 99%) and a high yield (up to about 20% or higher).
    • 两步sc-SWCNT富集方法包括基于使用共轭聚合物的半导体SWCNT的选择性分散和萃取的第一步骤,然后基于吸附过程的第二步骤,其中第一步骤的产物暴露于无机吸收介质 以选择性地结合主要金属的SWCNT,使得在溶液中分散的物质进一步富集在半导体SWCNT中。 该方法可以容易地扩展到大直径半导体单壁碳纳米管(sc-SWCNT)富集,其平均直径在例如约0.6至2.2nm的范围内。 第一步以高产率或高纯度(99%及以上)以低产率产生具有缓和sc-纯度(98%)的富集的sc-SWCNT分散体。 第二步不仅可以提高中等纯度的富集聚合物的sc-SWCNT的纯度,还可以进一步促进高纯度样品达到超纯水平。 因此,这种两步混合工艺提供具有超高纯度的sc-SWCNT材料,以及高sc纯度(例如大于99%)和高产率(高达约20%或更高)两者。