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1. 发明授权

US4774067A Regenerative process for removing mercaptans contained in a gas 失效
标题翻译：用于除去气体中所含的硫醇的再生方法
公开(公告)号：US4774067A
公开(公告)日：1988-09-27
申请号：US13976
申请日：1987-01-02
申请人： Robert Voirin , Jean Elgue
发明人： Robert Voirin , Jean Elgue
IPC分类号： B01D53/14 , B01D53/48 , C07C7/148 , C10K1/34 , B01J8/00 , C10B17/00
CPC分类号： C10K1/34 , B01D53/485 , C07C7/1485
摘要： A regenerative process is provided for removing mercaptans contained in a gas by means of an absorbing agent based on at least one metal oxide capable of chemically fixing the mercaptans. The process comprises an absorption step to fix the mercaptans on the absorbing agent and a regeneration step for regenerating the absorbing agent laden with sulphur-containing products resulting from said fixation. The regeneration is carried out by sweeping the absorbing agent with a hot inert gas to bring the absorbing agent to a temperature between 250.degree. and 500.degree. C. and desorb the sulfur-containing products, and by contacting the absorbing agent thus treated with a gas containing free oxygen to reoxidize the absorbing agent and by cooling the reoxidized absorbing agent by sweeping with a cold inert gas.
摘要翻译： PCT No.PCT / FR86 / 00157 Sec。 371日期1987年1月2日 102（e）日期1987年1月2日PCT提交1986年5月6日PCT公布。出版物WO86 / 06649 日本公报1986年11月20日。提供一种再生方法，用于通过基于能够化学固定硫醇的至少一种金属氧化物的吸收剂除去气体中所含的硫醇。该方法包括将硫醇固定在吸收剂上的吸收步骤和用于使由所述固定产生的含硫产物负载的吸收剂再生的再生步骤。再生通过用热惰性气体吹扫吸收剂进行，以使吸收剂达到250-500℃的温度并解吸含硫产物，并通过将这样处理的吸收剂与气体接触含有游离氧气以再吸收吸收剂，并通过用冷惰性气体吹扫冷却再氧化吸收剂。

2. 发明授权

US5766567A Method for desulphurising a gaseous mixture containing H.sub.2 S and SO.sub . 失效
标题翻译：用于硫化含有H 2 S和SO 2的气体混合物并回收硫形式的化合物的方法
公开(公告)号：US5766567A
公开(公告)日：1998-06-16
申请号：US467914
申请日：1995-06-06
申请人： Robert Voirin , Andre Philippe
发明人： Robert Voirin , Andre Philippe
IPC分类号： B01D53/86 , C01B17/04 , B01D53/50 , B01D53/52
CPC分类号： C01B17/0439 , B01D53/8615
摘要： A single-stage low temperature catalytic process for desulphurisation of a gas which contains a mixture of H.sub.2 S and SO.sub.2 which process includes feeding the gas to be treated at a temperature below the dew point of sulphur to a Claus converter having a Claus catalyst in a reaction stage in which the catalyst includes a composite catalytic mass of alumina and one or more compounds of titanium, yttrium, lanthanum or the rare-earth elements of atomic number 58 to 71, and contacting the gas with the Claus catalyst at a temperature below the dew point of sulphur, by which sulphur deposits on the Claus catalyst and the gas is desulphurised.
摘要翻译：用于脱硫含有H 2 S和SO 2的混合物的气体的单级低温催化方法，该方法包括在低于硫的露点的温度下将待处理的气体进料到具有克劳斯催化剂的克劳斯转化器其中催化剂包括氧化铝的复合催化剂物质和一种或多种原子数为58至71的钛，钇，镧或稀土元素的化合物，并在低于露点的温度下使气体与克劳斯催化剂接触硫脱硫点，其中克劳斯催化剂上的硫沉积物和气体被硫化。

3. 发明授权

US4605546A Catalytic process for the production of sulfur from a gas containing H.sub.2 S 失效
标题翻译：用于从含H2S气体生产硫的催化过程
公开(公告)号：US4605546A
公开(公告)日：1986-08-12
申请号：US574911
申请日：1984-01-30
申请人： Robert Voirin
发明人： Robert Voirin
IPC分类号： B01J23/00 , B01J23/18 , B01J23/24 , B01J23/76 , B01J23/89 , C01B17/04 , B01D53/36
CPC分类号： C01B17/0456 , C01B17/0434
摘要： A catalytic process for the production of sulphur from an acid gas containing H.sub.2 S, in which a part of H.sub.2 S is catalytically oxidized in order to form an effluent containing H.sub.2 S and SO.sub.2 in a molar ratio of 2:1 and a given quantity of sulphur, then said effluent is contacted with a CLAUS catalyst to form a further quantity of sulphur.The catalytic oxidation of H.sub.2 S is carried out in the presence of an oxidation catalyst consisting of agglomerates comprising an active alumina thermally stabilized by at least one oxide from the group consisting of SiO.sub.2, ZrO.sub.2, the rare-earth metal oxides and the alkaline-earth metal oxides to which are associated one or more compounds of metals such as iron that promote the oxidation of H.sub.2 S.
摘要翻译：用于从含有H 2 S的酸性气体生产硫的催化方法，其中一部分H 2 S被催化氧化以形成含有2:1摩尔比的H2S和SO2的流出物和给定量的硫，然后所述流出物与CLAUS催化剂接触以形成另外的硫。 H2S的催化氧化是在氧化催化剂的存在下进行的，所述氧化催化剂由包含由至少一种由SiO 2，ZrO 2，稀土金属氧化物和碱土金属组成的组中的至少一种氧化物热稳定的活性氧化铝的附聚物组成氧化物与一种或多种促进H 2 S的氧化的金属化合物（例如铁）相关联。

4. 发明授权

US5030438A Catalytic removal of hydrogen sulfides from liquid sulfur 失效
标题翻译：从液硫中催化除去硫化氢
公开(公告)号：US5030438A
公开(公告)日：1991-07-09
申请号：US323559
申请日：1989-03-14
申请人： Robert Voirin , Andre Pepy
发明人： Robert Voirin , Andre Pepy
IPC分类号： B01J31/02 , C01B17/02 , C01B17/027
CPC分类号： C01B17/0232
摘要： The invention is a catalytic process for removing H.sub.2 S and hydrogen polysulfides from liquid sulfur. The process comprises mixing a heterocyclic compound with the liquid sulfur and removing the hydrogen sulfide from the liquid sulfur by contact with a gas which is inert to the liquid sulfur at the treating temperature.

5. 发明授权

US4735788A Process of removing of COS and CS.sub.2 compounds contained in an industrial gas 失效
标题翻译：除去工业气体中所含的COS和CS2化合物的方法
公开(公告)号：US4735788A
公开(公告)日：1988-04-05
申请号：US900100
申请日：1986-08-08
申请人： Robert Voirin
发明人： Robert Voirin
IPC分类号： C01B3/56 , B01D53/86 , B01J21/06 , B01J27/053 , C01B17/10 , C01B17/16 , C10K3/00 , B01J8/00 , C01B17/00 , C01B31/20
CPC分类号： B01J21/063 , B01D53/8606 , C01B17/16
摘要： A process is provided for eliminating COS and CS.sub.2 compounds contained in an industrial gas. The gas containing an appropriate quantity of water vapor is contacted with a titanium oxide catalyst arranged in a high temperature reaction zone. The reaction is carried out while maintaining at specific values the ratio R between the number of water vapor moles and the number of moles of the compound(s) COS and CS.sub.2 in the supplied gas in contact with the catalyst, as well as the temperature at the outlet from the reaction zone. The process is applicable to the treatment of industrial gases usable in organic synthesis and containing COS and CS.sub.2 as impurities susceptible of perturbating synthesis reactions.
摘要翻译： PCT No.PCT / FR85 / 00358 Sec。 371日期1986年9月11日 102（e）日期1986年9月11日PCT提交1985年12月11日PCT公布。出版物WO86 / 03426 日期：1986年6月19日。提供了用于消除工业气体中包含的COS和CS2化合物的方法。含有适量水蒸汽的气体与布置在高温反应区中的氧化钛催化剂接触。在保持特定值的同时，保持与催化剂接触的供给气体中的水蒸气摩尔数与化合物COS和CS2的摩尔数之比R以及温度来自反应区的出口。该方法适用于可用于有机合成的工业气体的处理，并且含有COS和CS2作为易扰动合成反应的杂质。

6. 发明授权

US4283380A Process and installation for desulphurizing gases containing SO.sub.2 失效
标题翻译：包含SO2的脱硫气体的处理和安装
公开(公告)号：US4283380A
公开(公告)日：1981-08-11
申请号：US731654
申请日：1976-10-12
申请人： Robert Voirin , Pierre Mathieu , Claude Chambu
发明人： Robert Voirin , Pierre Mathieu , Claude Chambu
IPC分类号： B01D53/14 , B01D53/50 , B01D53/81 , B01J20/08
CPC分类号： B01D53/1418 , B01D53/1481 , B01D53/508
摘要： In a process for desulphurizing gases containing SO.sub.2 and SO.sub.3 by absorption of the sulphur containing compounds by means of absorbents based on alumina free of alkaline substances, activated alumina or alumina carrying salts or oxides of at least one element selected from the groups IB, IIB, IVB, VB, VIB, VIIB, VIII of the Periodic Classification, the absorption takes place at temperatures comprised between 100.degree. and 400.degree. C., and the absorbent loaded with said compounds in the form of sulphates is heated with a gas containing a reducing gas, especially H.sub.2 S, to a temperature of 250.degree. C. to 450.degree. C., while the elementary sulphur thus formed is separated from said absorbent, whereafter the latter is re-used in a subsequent absorption operation.
摘要翻译：在通过基于不含碱性物质的氧化铝的吸收剂吸收含硫化合物来脱硫含SO 2和SO 3的气体的方法中，活性氧化铝或氧化铝携带选自IB，IIB， IVB，VB，VIB，VIIB，VIII，吸收发生在100-400℃的温度下，加载硫酸盐形式的化合物的吸收剂用含有还原剂的气体加热气体，特别是H 2 S，至250℃至450℃的温度，同时所形成的元素硫与所述吸收剂分离，之后再次用于随后的吸收操作。

7. 发明授权

US4849204A Catalytic removal of hydrogen sulfides from liquid sulfur 失效
标题翻译：从液硫中催化除去硫化氢
公开(公告)号：US4849204A
公开(公告)日：1989-07-18
申请号：US171425
申请日：1988-03-09
申请人： Robert Voirin , Andre Pepy
发明人： Robert Voirin , Andre Pepy
IPC分类号： B01J31/02 , C01B17/02 , C01B17/027
CPC分类号： C01B17/0232
摘要： The invention is a catalytic process for removing H.sub.2 S and hydrogen polysulfides from liquid sulfur. The process comprises mixing a heterocyclic compound with the liquid sulfur and removing the hydrogen sulfide from the liquid sulfur by contact with a gas which is inert to the liquid sulfur at the treating temperature.
摘要翻译： PCT No.PCT / FR87 / 00269 Sec。 371日期：1988年3月9日 102（e）1988年3月9日PCT PCT 1987年7月8日PCT公布。公开号WO88 / 00571 日期1988年1月28日。本发明是从液体硫中除去H 2 S和氢多硫化物的催化方法。该方法包括将杂环化合物与液态硫混合，并在处理温度下与液态硫惰性的气体接触，从液态硫中除去硫化氢。

8. 发明授权

US4436716A Process for the production of sulphur with increased energy recovery from a gas containing H.sub.2 S, SO.sub.2, H.sub.2 and/or CO 失效
标题翻译：从含有H 2 S，SO 2，H 2和/或CO的气体中增加能量回收的硫的生产方法
公开(公告)号：US4436716A
公开(公告)日：1984-03-13
申请号：US320846
申请日：1981-11-12
申请人： Georges Kvasnikoff , Robert Voirin
发明人： Georges Kvasnikoff , Robert Voirin
IPC分类号： B01J23/00 , C01B17/04
CPC分类号： C01B17/0434 , Y02P20/129
摘要： Improved process for the production of sulphur from a gas containing H.sub.2 S, SO.sub.2, H.sub.2 and/or CO, in which the gas is caused to pass through a CLAUS catalyst in a primary catalytic stage operating at between 200.degree. and 460.degree. C. in order to form sulphur, and thereafter the sulphur contained in the reaction mixture issuing from this stage is condensed through indirect heat exchange with water to produce steam.The improved process consists in constituting at least the final eighth of the catalyst volume in this stage by a composite mass formed from a refractory oxide on which is fixed a transition metal compound, for example Co and/or Mo, and in entering into contact the gas with this composite mass at between 300.degree. and 460.degree. C. in order to oxidize H.sub.2 and CO.The energy resulting from this oxidation is recovered in the form of a supplementary quantity of steam during the sulphur condensation.
摘要翻译：改进的方法是从含有H 2 S，SO 2，H 2和/或CO的气体中产生硫，其中使气体在200-460℃之间的初级催化阶段中通过CLAUS催化剂形成硫，此后从该阶段发出的反应混合物中所含的硫通过与水的间接热交换而冷凝，产生蒸汽。改进的方法在于通过由难熔氧化物形成的复合材料构成至少在该阶段催化剂体积的最后八分之一，在该难熔氧化物上固定过渡金属化合物，例如Co和/或Mo，并且与气体在300〜460℃之间，以便氧化H 2和CO，在硫磺冷凝期间以这种补充量的蒸汽的形式回收由此产生的能量。

9. 发明授权

US4192857A Sulphur production 失效
标题翻译：硫磺生产
公开(公告)号：US4192857A
公开(公告)日：1980-03-11
申请号：US851509
申请日：1977-11-14
申请人： Jacques Tellier , Andre Philippe , Pierre Mathieu , Robert Voirin
发明人： Jacques Tellier , Andre Philippe , Pierre Mathieu , Robert Voirin
IPC分类号： B01J35/10 , C01B17/04
CPC分类号： B01J35/10 , C01B17/0426 , B01J35/1019 , B01J35/1038
摘要： The Claus process for the production of sulphur is improved by employing a deoxidation catalyst prior to the conventional Claus oxide catalyst.
摘要翻译：通过在常规的克劳斯氧化物催化剂之前使用脱氧催化剂来改善用于生产硫的Claus工艺。

10. 发明授权

US4037035A Hydrophilic modified acrylic polymers particularly hydrodispersible or hydrosoluble modified acrylic polymers and method of preparing the same 失效
标题翻译：亲水改性丙烯酸聚合物，特别是可分散水解或水溶性改性丙烯酸聚合物及其制备方法
公开(公告)号：US4037035A
公开(公告)日：1977-07-19
申请号：US598185
申请日：1975-07-23
申请人： Jean-Henri Blanc , Rene Pornin , Robert Voirin
发明人： Jean-Henri Blanc , Rene Pornin , Robert Voirin
IPC分类号： C08F8/00 , C08F8/12 , C08F8/32 , C08F8/42 , C08F8/44 , C08F220/04 , C08F220/12 , C08F220/58 , C08F220/06 , C08F220/14 , C08F220/18
CPC分类号： C08F220/58 , C08F220/04 , C08F220/12 , C08F8/32 , C08F8/44
摘要： Novel hydrophilic modified acrylic polymers, which are, in particular, hydrosoluble or hydrodispersible. These novel polymers contain, expressed in molar percentages, p % of units derived from an acrylic acid or ester, q % of units derived from an alkanolamine of said acid, r % of units derived from the alkali metal, alkaline earth metal or ammonium salt of the said acid, and s % of units derived from a vinylic monomer, p, q, r and s representing integers and being so selected that 1.ltoreq.p.ltoreq.99, O.ltoreq.q.ltoreq.96, O.ltoreq.r.ltoreq.99 and O.ltoreq.s.ltoreq.40, and the sum (p+q+r+s) is equal to 100.
摘要翻译：新型的亲水改性丙烯酸聚合物，特别是可溶于水或可分散的。这些新型聚合物含有以丙烯酸或酯衍生的单元的p％的百分比表示，q％来自所述酸的链烷醇胺的单元，r％的源自碱金属，碱土金属或铵盐的单元的所述酸和s％的衍生自乙烯基单体的单元，p，q，r和s表示整数，并且被选择为1 = 99，O = q = 0

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