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1. 发明公开

EP1603994A4 DIESEL STEAM REFORMING WITH CO sb 2 /sb FIXING 审中-公开
标题翻译：汽柴与固定CO2重整
公开(公告)号：EP1603994A4
公开(公告)日：2009-09-02
申请号：EP04713339
申请日：2004-02-20
申请人： TEXACO DEVELOPMENT CORP , BLOOMFIELD DAVID P
发明人： BLOOMFIELD DAVID P , STEVENS JAMES F
IPC分类号： C01B3/38 , B01J8/00 , B01J19/00 , C01B20060101 , C01B3/56 , C10J3/00 , C10J3/20 , H01M8/04 , H01M8/06
CPC分类号： C01B3/382 , B01J19/0006 , B01J2219/00006 , C01B3/38 , C01B3/56 , C01B2203/0233 , C01B2203/0425 , C01B2203/0475 , C01B2203/066 , C01B2203/1247 , C01B2203/127 , C01B2203/1288 , C01B2203/1294 , C01B2203/141 , C01B2203/142 , H01M8/04022 , H01M8/0618 , H01M8/0668 , H01M8/0675
摘要： Method and apparatus for steam reforming of sulfur containing hydrocarbon fuels. The apparatus includes a desulphurization unit (30), a pre-reformer (50), and a steam reforming unit (60). A carbon dioxide fixing material is present in the steam reforming catalyst bed. Fuel processors having multiple catalyst beds and methods and apparatus for generating electricity utilizing such fuel processors are also disclosed.

2. 发明申请

WO2004076346A3 DIESEL STEAM REFORMING WITH CO2 FIXING 审中-公开
标题翻译：具有CO2固定的柴油蒸汽改造
公开(公告)号：WO2004076346A3
公开(公告)日：2005-05-06
申请号：PCT/US2004005040
申请日：2004-02-20
申请人： TEXACO DEVELOPMENT CORP , BLOOMFIELD DAVID P , STEVENS JAMES F
发明人： BLOOMFIELD DAVID P , STEVENS JAMES F
IPC分类号： B01J8/00 , B01J19/00 , C01B20060101 , C01B3/38 , C01B3/56 , C10J3/00 , C10J3/20 , H01M8/04 , H01M8/06
CPC分类号： C01B3/382 , B01J19/0006 , B01J2219/00006 , C01B3/38 , C01B3/56 , C01B2203/0233 , C01B2203/0425 , C01B2203/0475 , C01B2203/066 , C01B2203/1247 , C01B2203/127 , C01B2203/1288 , C01B2203/1294 , C01B2203/141 , C01B2203/142 , H01M8/04022 , H01M8/0618 , H01M8/0668 , H01M8/0675
摘要： Method and apparatus for steam reforming of sulfur containing hydrocarbon fuels. The apparatus includes a desulphurization unit (30), a pre-reformer (50), and a steam reforming unit (60). A carbon dioxide fixing material is present in the steam reforming catalyst bed. Fuel processors having multiple catalyst beds and methods and apparatus for generating electricity utilizing such fuel processors are also disclosed.
摘要翻译：含硫烃燃料的蒸汽重整方法和装置。该设备包括脱硫单元（30），预重整器（50）和蒸汽重整单元（60）。二氧化碳固定材料存在于蒸汽转化催化剂床中。还公开了具有多个催化剂床的燃料处理器以及利用这种燃料处理器发电的方法和装置。

3. 发明申请

WO2005102506A3 METHOD AND APPARATUS FOR PROVIDING A CONTINUOUS STREAM OF REFORMATE 审中-公开
标题翻译：提供改造连续流的方法和装置
公开(公告)号：WO2005102506A3
公开(公告)日：2007-01-18
申请号：PCT/US2005012760
申请日：2005-04-14
申请人： TEXACO DEVELOPMENT CORP , STEVENS JAMES F
发明人： STEVENS JAMES F
IPC分类号： C10J3/06 , B01J8/00 , B01J8/02 , B01J8/04 , B01J19/24 , C01B3/32 , C10B1/04
CPC分类号： B01J8/02 , B01J8/04 , B01J19/2485 , B01J2208/00132 , B01J2208/00141 , B01J2208/00256 , B01J2208/00309 , B01J2208/00398 , B01J2208/00504 , B01J2208/0053 , B01J2208/025 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , B01J2219/00081 , B01J2219/00083 , B01J2219/00135 , B01J2219/00157 , B01J2219/00159 , C01B3/384 , C01B3/48 , C01B3/56 , C01B2203/0283 , C01B2203/0405 , C01B2203/0425 , C01B2203/043 , C01B2203/044 , C01B2203/0445 , C01B2203/0475 , C01B2203/0805 , C01B2203/1241 , C01B2203/141 , C01B2203/1604 , C01B2203/1609 , C01B2203/1647 , C01B2203/169 , F17C11/005 , Y02E60/321 , Y02P30/30
摘要： Method and apparatus for converting hydrocarbon fuels to hydrogen-rich reformate that incorporate a carbon dioxide fixing mechanism into the initial hydrocarbon conversion process and for providing a continuous supply of hydrogen-rich reformate. The apparatus includes a reforming reactor that has a catalyst bed comprising a reforming catalyst, a carbon dioxide fixing material and an optional water gas shift catalyst; a hydrogen storage device for storing reformate; and a controller for controlling the delivery of reformate from the reactor and/or storage device to an outlet. Optionally, the apparatus can include a heating device for heating the catalyst bed and a polishing unit for removing impurities from the reformate. The reforming reactor is operable in reforming and non-reforming modes. During non-reforming modes, the hydrogen storage device provides reformate to the outlet so as to maintain a continuous supply of reformate. A method for providing a continuous supply of hydrogen-rich reformate for use in a hydrogen-consuming device or process is also provided.
摘要翻译：将碳氢化合物燃料转化为富氢重整产物的方法和装置，其将二氧化碳固定机构结合到初始烃转化过程中并提供连续供应富氢重整产物。该装置包括重整反应器，其具有包含重整催化剂，二氧化碳固定材料和任选的水煤气变换催化剂的催化剂床; 用于储存重整产品的氢存储装置; 以及用于控制重整产物从反应器和/或存储装置输送到出口的控制器。可选地，该装置可以包括用于加热催化剂床的加热装置和用于从重整产物中除去杂质的抛光单元。重整反应器可在重整和非重整模式中操作。在非重整模式下，氢存储装置向出口提供重整产品，以保持重整产品的连续供应。还提供了一种用于提供连续供应用于氢消耗装置或方法的富氢重整产物的方法。

4. 发明申请

WO2005102916A3 REACTOR WITH CARBON DIOXIDE FIXING MATERIAL 审中-公开
标题翻译：二氧化碳固定材料的反应器
公开(公告)号：WO2005102916A3
公开(公告)日：2006-12-28
申请号：PCT/US2005012737
申请日：2005-04-14
申请人： TEXACO DEVELOPMENT CORP , STEVENS JAMES F , ROVNER JERRY M
发明人： STEVENS JAMES F , ROVNER JERRY M
IPC分类号： C10J3/00 , B01J8/00 , B01J8/04 , C01B3/24 , C01B3/38 , C01B3/56
CPC分类号： B01J8/0453 , B01J2208/00141 , B01J2208/00504 , B01J2208/025 , B01J2219/00006 , B01J2219/00038 , C01B3/38 , C01B3/56 , C01B2203/0227 , C01B2203/0283 , C01B2203/0425 , C01B2203/0475 , C01B2203/82 , C01B2203/86 , Y02P20/52 , Y02P30/30
摘要： Apparatus and methods for converting hydrocarbon fuels to hydrogen-rich reformate that incorporate a carbon dioxide fixing mechanism into the initial hydrocarbon conversion process. The mechanism utilizes a carbon dioxide fixing material within the reforming catalyst bed to remove carbon dioxide from the reformate product. The removal of carbon dioxide from the product stream shifts the reforming reaction equilibrium towaxd higher hydrocarbon conversion with only small amounts of carbon oxides produced. Fixed carbon dioxide may be released by heating the catalyst bed to a calcination temperature. A non-uniform distribution of catalysts and carbon dioxide fixing material across catalyst bed yields higher conversion rates of hydrocarbon to hydrogen-rich reformate.
摘要翻译：将碳氢燃料转化为富含氢的重整产物的装置和方法，其将二氧化碳固定机构并入初始烃转化过程。该机构利用重整催化剂床内的二氧化碳固定材料从重整产品中除去二氧化碳。从产物流中除去二氧化碳使重整反应平衡与仅产生少量碳氧化物的高碳氢化合物转化相结合。可以通过将催化剂床加热至煅烧温度来释放固定的二氧化碳。在催化剂床上催化剂和二氧化碳固定材料的不均匀分布产生较高烃转化率的富氢重整产物。

5. 发明申请

WO2004090074A3 FUEL PROCESSING REACTOR WITH INTERNAL HEAT EXCHANGE FOR LOW PRESSURE GAS STREAM 审中-公开
标题翻译：用于低压气体流的内部热交换器的燃料加工反应器
公开(公告)号：WO2004090074A3
公开(公告)日：2005-04-21
申请号：PCT/US2004009785
申请日：2004-03-30
申请人： TEXACO DEVELOPMENT CORP , STEVENS JAMES F , KRAUSE CURTIS L , MARTIN PAUL F , DESHPANDE VIJAY A
发明人： STEVENS JAMES F , KRAUSE CURTIS L , MARTIN PAUL F , DESHPANDE VIJAY A
IPC分类号： B01J8/00 , B01J8/02 , B01J8/04 , C01B3/16 , C01B3/26 , C01B3/38 , C10L20060101 , H01M8/06
CPC分类号： C01B3/16 , B01J8/025 , B01J8/0271 , B01J8/0285 , B01J8/0292 , B01J8/0453 , B01J8/0496 , B01J2208/00141 , C01B3/38 , C01B3/386 , C01B2203/0233 , C01B2203/0261 , C01B2203/0288 , C01B2203/0883 , C01B2203/1011 , H01M8/0618 , H01M8/0668 , Y02P70/56 , Y10T29/49391
摘要： A compact fuel processing reactor (10) includes a housing (90) having an inlet (40) for receiving a process gas (20) and an outlet (50) for a directing a product gas out (30) of the housing. A catalyst bed (60) that includes discrete particles (70) of a refractory material is located within the housing for contacting the process gas. A coiled tubing heat exchanger (80) is at least partially disposed within the catalyst bed for cooling the catalyst bed. The coiled tubing (86) can comprise a smooth continuous outer surface in intimate contact with the discrete particles (70). The circulating cooling medium (82), (84) comprises water in liquid, gas or a mixture of liquid and gas phases. The discrete particles (70) in the catalyst bed are in intimate contact with at least a portion of the coiled tubing (86) to promote heat transfer from the catalyst bed to the coiled tubing. The heat exchanger (80) has less than about 25, preferably less than about 20, more preferably less than about 15, and still more preferably less than about 10 square meters of heat exchanging surface area per cubic meter of catalyst bed. The catalyst bed (60) can be a water gas shift, desulfurization or reforming bed. The reactor can include one or more additional catalyst beds arranged in series such that the housing encloses a shift catalyst bed as well as a desulfurization bed and/or a reforming bed. Methods of cooling a catalyst bed within a compact reactor and methods of manufacturing a compact reactor are also provided.
摘要翻译：紧凑的燃料处理反应器（10）包括具有用于接收处理气体的入口（40）的外壳（90）和用于引导外壳的产品气体（30）的出口（50）。包括耐火材料的离散颗粒（70）的催化剂床（60）位于壳体内用于接触工艺气体。连续油管热交换器（80）至少部分地设置在催化剂床内以冷却催化剂床。连续油管（86）可以包括与离散颗粒（70）紧密接触的光滑的连续外表面。循环冷却介质（82）（84）包括液体中的水，气体或液相和气相的混合物。催化剂床中的离散颗粒（70）与至少一部分连续油管（86）紧密接触以促进从催化剂床到连续油管的热传递。热交换器（80）每立方米催化剂床的热交换表面积小于约25，优选小于约20，更优选小于约15，还更优选小于约10平方米。催化剂床（60）可以是水煤气变换，脱硫或重整床。反应器可以包括一个或多个另外的串联布置的催化剂床，使得壳体包含换档催化剂床以及脱硫床和/或重整床。还提供了在紧凑型反应器内冷却催化剂床的方法和制造紧凑型反应器的方法。

6. 发明专利

JP2007326777A Apparatus and method for heating catalyst for start-up of compact fuel processor 有权
标题翻译：用于加热催化剂以启动紧凑型燃料加工器的装置和方法
公开(公告)号：JP2007326777A
公开(公告)日：2007-12-20
申请号：JP2007203941
申请日：2007-08-06
申请人： Texaco Development Corp , テキサコディベラップメントコーポレイション
发明人： MARTIN PAUL , SCOTT T GLENN , PHAN JENNIFER L , STEVENS JAMES F , KRAUSE CURTIS
IPC分类号： C01B3/38 , B01J8/00 , B01J8/02 , B01J8/04 , B01J8/06 , B01J19/00 , B01J19/24 , C01B3/16 , C01B3/36 , C01B3/48 , C01B3/58 , C10J1/207 , H01M8/04 , H01M8/06
CPC分类号： B01J8/0488 , B01J8/009 , B01J8/0278 , B01J8/0285 , B01J8/0423 , B01J8/0453 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J8/067 , B01J19/0013 , B01J19/2475 , B01J19/2485 , B01J2208/00141 , B01J2208/00176 , B01J2208/00194 , B01J2208/00203 , B01J2208/00407 , B01J2208/00415 , B01J2208/00716 , B01J2208/00814 , B01J2208/025 , B01J2219/0002 , B01J2219/00083 , B01J2219/00135 , B01J2219/182 , B01J2219/185 , B01J2219/1944 , C01B3/16 , C01B3/38 , C01B3/382 , C01B3/384 , C01B3/386 , C01B3/48 , C01B3/583 , C01B2203/0244 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/0455 , C01B2203/0465 , C01B2203/047 , C01B2203/0485 , C01B2203/0495 , C01B2203/066 , C01B2203/0805 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0894 , C01B2203/1011 , C01B2203/1017 , C01B2203/1023 , C01B2203/1035 , C01B2203/1041 , C01B2203/1082 , C01B2203/1205 , C01B2203/1235 , C01B2203/1276 , C01B2203/142 , C01B2203/146 , C01B2203/147 , C01B2203/1604 , C01B2203/80 , C01B2203/82 , H01M8/04022 , H01M8/04037 , H01M8/04059 , H01M8/0612 , H01M8/0631 , H01M8/0668 , Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide an apparatus and method for heating a catalyst for start-up of a compact fuel processor. SOLUTION: The apparatus heats a catalyst bed 410 for start-up and provides heat to the catalyst bed 410 during transient operation to maintain desired reaction temperatures. An electrical heating element 400 may directly or indirectly heat the catalyst. The direct heating of the catalyst is achieved by bringing the heater element 400 into direct contact with the catalyst. Indirect heating is achieved by direct heating of a fluid, such as a process flow, which in turn flows through the catalyst, thereby transferring heat to the catalyst. Additionally, the heating element 400 may be placed within a sheath that is brought into direct contact with the catalyst or fluid that flows through the catalyst. By these means, catalysts of many forms, including pellets, extrudates, spheres, and monoliths, may employ this catalyst heater 400. The catalyst heater 400 can be made of any resistive wire, cartridges, or rods that may be coupled to a power source to provide the energy to produce the heat. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于加热用于启动紧凑型燃料处理器的催化剂的装置和方法。解决方案：设备加热催化剂床410用于启动，并在瞬态操作期间向催化剂床410提供热量以保持所需的反应温度。电加热元件400可直接或间接加热催化剂。通过使加热器元件400与催化剂直接接触来实现催化剂的直接加热。间接加热通过直接加热诸如工艺流的流体来实现，该流体又流过催化剂，从而将热量传递到催化剂。此外，加热元件400可以放置在与流过催化剂的催化剂或流体直接接触的护套内。通过这些方式，许多形式的催化剂，包括颗粒，挤出物，球体和整料可以使用该催化剂加热器400.催化剂加热器400可以由可以耦合到电源的任何电阻丝，筒或棒制成以提供产生热量的能量。版权所有（C）2008，JPO＆INPIT

7. 发明申请

WO2004090072A3 ANODE TAILGAS OXIDIZER 审中-公开
标题翻译： ANODE TAILGAS氧化剂
公开(公告)号：WO2004090072A3
公开(公告)日：2005-05-06
申请号：PCT/US2004009789
申请日：2004-03-30
申请人： TEXACO DEVELOPMENT CORP , DESHPANDE VIJAY A , KRAUSE CURTIS L , MARTIN PAUL F , NGUYEN KEVIN H , STEVENS JAMES F , WHEAT WILLIAMS S
发明人： DESHPANDE VIJAY A , KRAUSE CURTIS L , MARTIN PAUL F , NGUYEN KEVIN H , STEVENS JAMES F , WHEAT WILLIAMS S
IPC分类号： C10G20060101 , F23C13/00 , F23D14/66 , F24H1/00 , H01M8/06
CPC分类号： F23C13/02 , C01B3/34 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/1258 , F23C13/00 , F23C2900/03002 , F23D14/66 , F23L2900/07009 , H01M8/0631 , Y02E20/348 , Y02P20/128 , Y02P70/56 , Y10T29/49348
摘要： A combustor for oxidizing a combustion fuel and pre-heating one or more reactants for fuel reforming. The combustor includes an elongated housing (220) having an inlet (236) for receiving a combustion fuel and an outlet (238) for exhausting combustion products. The elongated housing (220) further includes a cylindrical side wall (244), a bottom wall (242), and a top wall (240). Inert particles (250) are disposed within the housing (220) adjacent the inlet (236). A combustion catalyst bed (260) is disposed within the housing (220) above the inert particles (250) that is a mixture of inert particles and combustion catalyst. The combustor has at least one heat exchanger (230, 232) within the combustion catalyst bed (260) for heating a reformer reactant and generating steam. The combustor can include at least one sensor (224, 226) for measuring temperature within the combustor.
摘要翻译：一种用于氧化燃烧燃料并预热一种或多种用于燃料重整的反应物的燃烧器。燃烧器包括具有用于接收燃烧燃料的入口（236）和用于排出燃烧产物的出口（238）的细长壳体（220）。细长壳体（220）还包括圆柱形侧壁（244），底壁（242）和顶壁（240）。惰性颗粒（250）设置在邻近入口（236）的壳体（220）内。燃烧催化剂床（260）设置在作为惰性颗粒和燃烧催化剂的混合物的惰性颗粒（250）之上的壳体（220）内。燃烧器具有在燃烧催化剂床（260）内的至少一个热交换器（230,232），用于加热重整器反应物并产生蒸汽。燃烧器可以包括用于测量燃烧器内的温度的至少一个传感器（224,226）。

8. 发明申请

WO2004090077A3 AUTOTHERMAL REFORMING IN A FUEL PROCESSOR UTILIZING NON-PYROPHORIC SHIFT CATALYST 审中-公开
标题翻译：使用非磷酸盐转移催化剂的燃料加工机中的自动化改造
公开(公告)号：WO2004090077A3
公开(公告)日：2005-01-20
申请号：PCT/US2004009832
申请日：2004-03-30
申请人： TEXACO DEVELOPMENT CORP , WHEAT WILLIAM S , MIRKOVIC VESNA R , NGUYEN KEVIN H , KRAUSE CURTIS L , STEVENS JAMES F , CASEY DANIEL G
发明人： WHEAT WILLIAM S , MIRKOVIC VESNA R , NGUYEN KEVIN H , KRAUSE CURTIS L , STEVENS JAMES F , CASEY DANIEL G
IPC分类号： B01J8/02 , B01J8/04 , B01J19/00 , B01J19/24 , C01B3/38 , C01B3/48 , H01M8/10 , B01J8/00
CPC分类号： B01J8/0453 , B01J8/025 , B01J8/0496 , B01J19/0013 , B01J19/0033 , B01J19/24 , B01J2208/00132 , B01J2208/00141 , B01J2208/00203 , B01J2208/00398 , B01J2208/00415 , B01J2208/0053 , B01J2208/00646 , B01J2208/00716 , B01J2208/00849 , B01J2219/00263 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/066 , C01B2203/0844 , C01B2203/127 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/169 , H01M8/0618 , H01M8/0668 , H01M2008/1095
摘要： A method for start-up and shut down of a fuel processor (102) including an autothermal reformer (110) employing a non-pyrophoric shift catalyst is disclosed. Also disclosed are a computer (106) programmed to start-up or shut-down a fuel processor (102) including an autothermal reformer (110) employing a non-pyrophoric shift catalyst or a program storage medium encoded with instruction that, when executed by a computer (106), start-up or shu-down a fuel processor (102) including an autothermal reformer (110) employing a non-pyrophoric shift catalyst.
摘要翻译：公开了一种用于启动和关闭包括使用非自发变换催化剂的自热重整器（110）的燃料处理器（102）的方法。还公开了一种被编程为启动或关闭燃料处理器（102）的计算机（106），该燃料处理器（102）包括使用非自燃换档催化剂的自热重整器（110）或编码有指令的程序存储介质，当由计算机（106），启动或关闭包括使用非自发变换催化剂的自热重整器（110）的燃料处理器（102）。

9. 发明申请

WO02085783A3 INTEGRATED FUEL PROCESSOR, FUEL CELL STACK AND TAIL GAS OXIDIZER WITH CARBON DIOXIDE REMOVAL 审中-公开
标题翻译：集成燃料处理器，燃料电池堆和带二氧化碳去除的尾气氧化器
公开(公告)号：WO02085783A3
公开(公告)日：2002-12-12
申请号：PCT/US0212368
申请日：2002-04-18
申请人： TEXACO DEVELOPMENT CORP
发明人： STEVENS JAMES F
IPC分类号： C01B3/40 , B01J8/02 , C01B3/32 , C01B3/38 , C01B3/56 , C01B3/58 , H01M8/06
CPC分类号： H01M8/0612 , B01J8/0242 , B01J2219/00006 , B01J2219/00038 , C01B3/323 , C01B3/38 , C01B3/56 , C01B3/583 , C01B3/586 , C01B2203/0425 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , H01M8/0618 , H01M8/0662 , H01M8/0668
摘要： An illustrative method for converting hydrocarbon fuel to hydrogen rich gas, includes the steps of: reacting the hydrocarbon fuel with steam in the presence of reforming catalyst and a carbon dioxide fixing material to produce a first hydrogen gas; and removing carbon monoxide from the first hydrogen gas to produce the hydrogen rich gas, wherein the removing step utilizes a process selected from methanation or selective oxidation. In one illustrative embodiment the carbon dioxide fixing material is selected from calcium oxide, calcium hydroxide, strontium oxide, strontium hydroxide, allanite, andralite, ankerite, anorthite, aragoniter, calcite, dolomite, clinozoisite, huntite, hydrotalcite, lawsonite, meionite, strontianite, vaterite, jutnohorite, minrecordite, benstonite, olekminskite, nyerereite, natrofairchildite, farichildite, zemkorite, butschlite, shrtite, remondite, petersenite, calcioburbankite, khanneshite, carboncernaite, brinkite, pryrauite, strontio dressenite, and similar such materials and any combinatio of these. The reforming catalyst in one preferred and illustrative embodiment is selected from nickel, platinum, rhodium, palladium, ruthenium, or similar supported reforming catalyst or combinations of these. In such instances the reforming catalyst is preferably supported on a high surface area support thus promoting the reforming reaction and more preferably is selected from alumina, titania, zirconia, or similar such compounds or combinations of these. It is preferred that in one illustrative embodiment that the temperature of the reacting step is from about 400 DEG C to about 800 DEG C.
摘要翻译：用于将烃燃料转化成富氢气体的说明性方法包括以下步骤：在重整催化剂和二氧化碳固定材料的存在下使烃燃料与蒸汽反应以产生第一氢气; 和从第一氢气中除去一氧化碳以产生富氢气体，其中除去步骤使用选自甲烷化或选择性氧化的过程。在一个说明性实施方案中，二氧化碳固定材料选自氧化钙，氢氧化钙，氧化锶，氢氧化锶，褐煤，红柱石，铁白云石，钙长石，硅酸盐，方解石，白云石，斜方辉石，菱镁矿，水滑石，球霰石，j石，微粒石，石英，橄榄石，钇闪石，钠陨石，铬铁矿，锌绿石，丁子石，shrtite，蛭石，钙石，钙硅石，khanneshite，碳酸钠岩，岩镁石，石榴石，strontio dressenite和类似的材料及其组合。一个优选和说明性实施方案中的重整催化剂选自镍，铂，铑，钯，钌或类似的负载型重整催化剂或这些的组合。在这种情况下，重整催化剂优选负载在高表面积载体上，由此促进重整反应，更优选选自氧化铝，二氧化钛，氧化锆或类似的这样的化合物或这些化合物的组合。在一个说明性实施方案中，反应步骤的温度优选为约400℃至约800℃

10. 发明申请

WO2005105289A3 REACTOR AND APPARATUS FOR HYDROGEN GENERATION 审中-公开
标题翻译：氢生成反应器和装置
公开(公告)号：WO2005105289A3
公开(公告)日：2007-02-01
申请号：PCT/US2005012759
申请日：2005-04-14
申请人： TEXACO DEVELOPMENT CORP , STEVENS JAMES F , ROVNER JERRY M
发明人： STEVENS JAMES F , ROVNER JERRY M
IPC分类号： B01J8/00 , B01J8/02 , B01J35/00 , C01B3/38
CPC分类号： B01J8/025 , B01J35/0006 , B01J2208/00132 , B01J2208/00141 , B01J2208/00309 , B01J2208/00371 , B01J2208/00398 , B01J2208/00415 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00884 , B01J2208/025 , B01J2219/00006 , C01B3/382 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/041 , C01B2203/0475 , C01B2203/0844 , C01B2203/127 , C01B2203/142 , C01B2203/82 , C01B2203/86 , Y02P20/52 , Y02P30/30
摘要： Apparatus and methods for converting hydrocarbon fuels to hydrogen-rich reformate that incorporate a carbon dioxide fixing mechanism into the initial hydrocarbon conversion process. The mechanism utilizes a carbon dioxide fixing material within the reforming catalyst bed to remove carbon dioxide from the reformate product. The removal of carbon dioxide from the product stream shifts the reforming reaction equilibrium toward higher hydrocarbon conversion with only small amounts of carbon oxides produced. Fixed carbon dioxide may be released by heating the catalyst bed to a calcination temperature. Heat for releasing fixed carbon dioxide from the catalyst bed is generated internally within the reactor through oxidation. A non-uniform distribution of catalysts and carbon dioxide fixing material across catalyst bed can be utilized to achieve higher conversion rates of hydrocarbon to hydrogen-rich reformate.
摘要翻译：将碳氢燃料转化为富含氢的重整产物的装置和方法，其将二氧化碳固定机构并入初始烃转化过程。该机构利用重整催化剂床内的二氧化碳固定材料从重整产品中除去二氧化碳。从产物流中除去二氧化碳将重整反应平衡转化为较高的碳氢化合物转化率，只产生少量的碳氧化物。可以通过将催化剂床加热至煅烧温度来释放固定的二氧化碳。通过氧化在反应器内部产生用于从催化剂床释放固定二氧化碳的热量。可以利用催化剂床上的催化剂和二氧化碳固定材料的不均匀分布来实现烃与富氢重整产物的更高转化率。

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