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1. 发明申请

WO2013191685A1 THERMOPLASTIC ELASTOMER COMPOSITION AND PROCESS TO PRODUCE SAME 审中-公开
标题翻译：热塑性弹性体组合物及其制备方法
公开(公告)号：WO2013191685A1
公开(公告)日：2013-12-27
申请号：PCT/US2012/043134
申请日：2012-06-19
申请人： THE YOKOHAMA RUBBER CO., LTD. , EXXONMOBIL CHEMICAL PATENTS INC. , HARA, Yuichi , SATO, Shun , BLOK, Edward, J. , ELLUL, Maria, D. , DIAS, Anthony, J. , RANDAL, Kerstetter, Howard, III
发明人： HARA, Yuichi , SATO, Shun , BLOK, Edward, J. , ELLUL, Maria, D. , DIAS, Anthony, J. , RANDAL, Kerstetter, Howard, III
IPC分类号： C08L9/00
CPC分类号： C08L23/283 , C08K5/18 , C08L23/16 , C08L2201/08 , C08L2207/04 , C08L2312/00 , C08L77/00
摘要： Disclosed herein is a thermoplastic elastomer composition having improved uv and processability, comprising a post-vulcanized dynamically vulcanized alloy (DVA) and a low molecular weight aromatic amine stabilizer, wherein the DVA comprises an isobutylene elastomeric component dispersed as a domain in a continuous phase comprising at least one thermoplastic resin. A method to produce the thermoplastic elastomer composition is also disclosed.
摘要翻译：本文公开了具有改进的紫外线和加工性的热塑性弹性体组合物，其包含后硫化动态硫化合金（DVA）和低分子量芳族胺稳定剂，其中所述DVA包含分散在连续相中的结构域的异丁烯弹性体组分，至少一种热塑性树脂。还公开了一种制备热塑性弹性体组合物的方法。

2. 发明申请

WO2011025593A1 ELASTOMERIC COMPOSITIONS AND THEIR USE IN ARTICLES 审中-公开
标题翻译：弹性体组合物及其在文章中的使用
公开(公告)号：WO2011025593A1
公开(公告)日：2011-03-03
申请号：PCT/US2010/041689
申请日：2010-07-12
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ELLUL, Maria, D. , DIAS, Anthony, J. , MAY, Rodney
发明人： ELLUL, Maria, D. , DIAS, Anthony, J. , MAY, Rodney
IPC分类号： C08L23/02 , C08L23/22 , C08L23/28 , B60C1/00 , C08L77/00
CPC分类号： C08L23/283 , B60C1/00 , C08K3/34 , C08K5/0016 , C08L23/02 , C08L23/0869 , C08L23/22 , C08L77/00 , C08L79/08 , C08L2205/08 , C08L2666/02
摘要： A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.
摘要翻译：动态硫化合金含有至少一种含异丁烯的弹性体和至少一种热塑性树脂，其中弹性体以热塑性树脂的连续相中的小硫化或部分硫化的颗粒的分散相存在。动态硫化合金还含有酸酐官能化的低聚物。该合金保持高的肖氏A硬度值，同时获得改进的流动性用于加工。

3. 发明申请

WO2015153059A2 DUAL REACTIVE FUNCTIONAL GROUPS FOR RESINS IN TIRES 审中-公开
标题翻译：轮胎树脂的双重反应功能组合
公开(公告)号：WO2015153059A2
公开(公告)日：2015-10-08
申请号：PCT/US2015/019214
申请日：2015-03-06
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BLOK, Edward, J. , STEWART, Ian, C. , DIAS, Anthony, J. , YANG, Yong , ZHANG, Jingwen
发明人： BLOK, Edward, J. , STEWART, Ian, C. , DIAS, Anthony, J. , YANG, Yong , ZHANG, Jingwen
IPC分类号： C08F8/42
CPC分类号： C08F8/42 , B60C1/0016 , C08C19/25 , C08F8/00 , C08K3/00 , C08L9/00 , C08L21/00 , C08L57/06 , C08L101/02
摘要： This invention relates to a functionalized resin composition having the formula P-X- S-W where S is a spacer selected from at least one of C 2 -C 40 straight chain and branched alkyl, C 6 -C 40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C 5 homopolymers and copolymer resins, C 5 -styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C 9 homopolymers and copolymer resins, C 5 /C 9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, X is one or more reactive groups, and W is a silane.
摘要翻译：本发明涉及具有式PX-SW的官能化树脂组合物，其中S是选自C 2 -C 40直链和支链烷基，C 6 -C 40芳烃，丁二烯，异戊二烯及其组合中的至少一种的间隔基，P是选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种的聚合物主链，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂，C9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂及其组合，X是一个或多个反应性基团，W是硅烷。

4. 发明申请

WO2012050667A1 SILANE-FUNCTIONALIZED HYDROCARBON POLYMER MODIFIERS FOR ELASTOMERIC COMPOSITIONS 审中-公开
标题翻译：用于弹性体组合物的硅烷官能化聚合物改性剂
公开(公告)号：WO2012050667A1
公开(公告)日：2012-04-19
申请号：PCT/US2011/049139
申请日：2011-08-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BLOK, Edward, J. , DIAS, Anthony, J. , CLAASSEN II, Robert, J. , UHI, Eugene, R.
发明人： BLOK, Edward, J. , DIAS, Anthony, J. , CLAASSEN II, Robert, J. , UHI, Eugene, R.
IPC分类号： C08F10/14 , C08F32/06 , C08L23/20
CPC分类号： C08F279/00 , B29B9/065 , B29D30/06 , B29K2009/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0041 , C08C19/25 , C08F8/42 , C08F10/14 , C08J3/12 , C08J2351/00 , C08K3/36 , C08L21/00 , C08L23/22 , C08L45/00 , C08L47/00 , C08L51/003 , C08L101/02 , C08L101/10 , Y02T10/862 , Y10T156/10 , C08F240/00
摘要： An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane- functionalized hydrocarbon polymer modifier (Si-HPM) adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof. The method comprises melt processing a mixture to form the elastomeric composition in the shape of an article, wherein the mixture comprises elastomer, Si-HPM, silica, bifunctional organosilane crosslinking agent; and curing the elastomeric composition to form the article. Also disclosed are a silylated hydrocarbon polymer modifier coupled with a bifunctional organosilane crosslinking agent, and a silica-coupled hydrocarbon polymer modifier coupled to the silica via the bifunctional organosilane crosslinking agent.
摘要翻译：一种具有改进的耐久性的烃聚合物改性剂的弹性体组合物和方法。该组合物包括适于将Si-HPM偶联到弹性体，填料或两者的弹性体，填料和硅烷官能化烃聚合物改性剂（Si-HPM），其中Si-HPM包含选自胡椒基，环戊二烯，芳族化合物，柠檬烯，蒎烯，二烯类及其组合。该方法包括熔融加工混合物以形成制品形状的弹性体组合物，其中该混合物包含弹性体，Si-HPM，二氧化硅，双功能有机硅烷交联剂; 并固化弹性体组合物以形成制品。还公开了与双功能有机硅烷交联剂偶联的甲硅烷基化烃聚合物改性剂和通过双官能有机硅烷交联剂与二氧化硅偶联的二氧化硅偶合烃聚合物改性剂。

5. 发明申请

WO2012050657A1 HYDROCARBON POLYMER MODIFIERS FOR ELASTOMERIC COMPOSITIONS 审中-公开
标题翻译：用于弹性体组合物的烃聚合物改性剂
公开(公告)号：WO2012050657A1
公开(公告)日：2012-04-19
申请号：PCT/US2011/048049
申请日：2011-08-17
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BLOK, Edward, J , DIAS, Anthony, J. , CLAASSEN II, Robert, J. , BARBEE, Thomas, R.
发明人： BLOK, Edward, J , DIAS, Anthony, J. , CLAASSEN II, Robert, J. , BARBEE, Thomas, R.
IPC分类号： C08L21/00 , B60C1/00 , C08L23/20
CPC分类号： C08L47/00 , B60C1/00 , C08L7/00 , C08L9/06 , C08L21/00 , C08L2666/06
摘要： An elastomeric composition incorporating a hydrocarbon polymer modifier including piperylene, cyclic pentadiene and aromatic components, and having a softening point from 80°C to 160°C, z-average molecular weight greater than 10,000, and at least 1 mole percent aromatic hydrogen, based on the total moles of hydrogen in the modifier. In a method, the elastomeric composition is processed with a cure package into a composition in the desired shape, which is cured to form the article. The modifier may optionally be immiscible with an elastomer in the composition and/or co-cured with the elastomer or filler in the composition. A tire or tire component may include the elastomeric composition.
摘要翻译：一种包含烃聚合物改性剂的弹性体组合物，其包括戊间二烯，环戊二烯和芳族组分，并且具有80℃至160℃的软化点，大于10,000的平均分子量和至少1摩尔％的芳香族氢，基于关于改性剂中氢的总摩尔数。在一种方法中，将弹性体组合物用固化包装处理成期望形状的组合物，其被固化以形成制品。改性剂可以任选地与组合物中的弹性体不混溶和/或在组合物中与弹性体或填料共固化。轮胎或轮胎部件可以包括弹性体组合物。

6. 发明申请

WO2013052206A1 TIRE CURING BLADDERS 审中-公开
标题翻译：轮胎固化刀
公开(公告)号：WO2013052206A1
公开(公告)日：2013-04-11
申请号：PCT/US2012/051738
申请日：2012-08-21
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , RODGERS, Michael, B. , DIAS, Anthony, J. , CLAASSEN, Robert, J., II
发明人： RODGERS, Michael, B. , DIAS, Anthony, J. , CLAASSEN, Robert, J., II
IPC分类号： B29C33/00 , B60C1/00 , C08L23/22 , C08L23/28
CPC分类号： B29D30/0061 , B29C33/505 , B29D30/0654 , B29D2030/0655 , C08K3/04 , C08K5/01 , C08L11/00 , C08L23/20 , C08L23/22 , C08L91/00 , C08L93/00
摘要： An elastomeric composition for a curing bladder comprises isobutylene based elastomer, curative and a hydrocarbon polymer modifier comprising monomers selected from the group consisting of piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof, wherein the cyclic pentadienes comprise at least 10 weight percent of the monomers by total weight of the monomers. Also disclosed are a tire curing bladder made from the elastomeric composition, a tire curing press containing the bladder, a method of making the tire curing bladder, an improvement to the process of making the tire curing bladder to improve processability of the mixture and fatigue life and DeMattia cut growth, a method of making a tire using the tire curing bladder, and an improvement to the process of making a tire to extend a pull point of the curing bladder and/or to reduce the curing time for the tire construct.
摘要翻译：用于固化囊的弹性体组合物包括异丁烯基弹性体，固化剂和烃聚合物改性剂，其包含选自胡椒基，环戊二烯，芳族化合物，柠檬烯，蒎烯，戊烯和其组合的单体，其中环戊二烯包含至少单体总重量为10重量％。还公开了由弹性体组合物制成的轮胎硫化胶囊，包含气囊的轮胎硫化机，制造轮胎硫化胶囊的方法，改进制造轮胎硫化胶囊的过程以改善混合物的加工性和疲劳寿命和DeMattia切割生长，使用轮胎硫化胶囊制造轮胎的方法，以及改进制造轮胎以延长固化囊的拉伸点和/或减少轮胎构造体的固化时间的方法。

7. 发明申请

WO2002100935A1 LOW PERMEABILITY NANOCOMPOSITES 审中-公开
标题翻译：低渗透性纳米复合材料
公开(公告)号：WO2002100935A1
公开(公告)日：2002-12-19
申请号：PCT/US2002/016796
申请日：2002-05-29
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DIAS, Anthony, J. , GONG, Caiguo , WENG, Weiqing , CHUNG, David, Y. , TSOU, Andy, H.
发明人： DIAS, Anthony, J. , GONG, Caiguo , WENG, Weiqing , CHUNG, David, Y. , TSOU, Andy, H.
IPC分类号： C08K3/00
CPC分类号： B60C1/0008 , C08K3/346 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/283 , C08L77/00 , C08L23/28 , C08L2666/20 , C08L2666/04
摘要： The present invention is a blend of an halogenated elastomer and a clay, desirably an exfoliated clay, to form a nanocomposite suitable for an air barrier. In one embodiment, the halogenated elastomer is a polymer comprising C 4 to C 7 isoolefin derived units, a para-methylstyrene derived units, and para-(halomethylstyrene) derived units. In another embodiment, the halogenated elastomer is a butyl-type rubber. The clay may or may not have an additional exfoliating treatment present prior to blending with the interpolymer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an innerliner or innertube.
摘要翻译：本发明是卤化弹性体和粘土的混合物，理想地是剥离粘土，以形成适合于空气屏障的纳米复合材料。在一个实施方案中，卤化弹性体是包含C4-C7异烯烃衍生单元，对甲基苯乙烯衍生单元和对 - （卤代甲基苯乙烯）衍生单元的聚合物。在另一个实施方案中，卤化弹性体是丁基型橡胶。在与共聚体共混之前，粘土可以或可以不具有额外的去角质处理。互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。本发明的共混物具有改善的空气阻隔性能，并且适合作为内衬或内管。

8. 发明申请

WO2008045012A2 FUNCTIONALIZED ISOBUTYLENE POLYMER-INORGANIC CLAY NANOCOMPOSITES AND ORGANIC-AQUEOUS EMULSION PROCESS 审中-公开
标题翻译：功能化异丁烯聚合物 - 无机粘土纳米复合材料和有机 - 水乳液法
公开(公告)号：WO2008045012A2
公开(公告)日：2008-04-17
申请号：PCT/US2006/020572
申请日：2006-05-26
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , WENG, Weiqing , GONG, Caiguo , DIAS, Anthony, J. , AYERS, James, R. , NEAGU, Carmen , KARP, Kriss, P. , POOLE, Beverly, J. , JOHNSTON, Molly, W.
发明人： WENG, Weiqing , GONG, Caiguo , DIAS, Anthony, J. , AYERS, James, R. , NEAGU, Carmen , KARP, Kriss, P. , POOLE, Beverly, J. , JOHNSTON, Molly, W.
CPC分类号： C08J5/005 , B82Y30/00 , C08J3/12 , C08J3/14 , C08J3/215 , C08J2323/28 , C08K9/04 , C08L23/283 , C08L15/02
摘要： A nanocomposite of a halogenated elastomer and an inorganic, exfoliated clay, suitable for use as an air barrier, is disclosed. The halogenated elastomer can be a polymer comprising C4 to C7 isoolefin derived units, para-methylstyrene derived units, and para-(halomethylstyrene) derived units, or can be a butyl-type rubber. The nanocomposite can be formed by contacting an aqueous slurry of inorganic clay with a polymer cement while agitating vigorously to form emulsions or micro-emulsions to intimately mix the inorganic clay and the elastomer. The nanocomposite so formed has improved air barrier properties and is suitable for use as an innerliner or innertube.
摘要翻译：公开了适合用作空气阻挡层的卤化弹性体和无机剥离粘土的纳米复合材料。卤化弹性体可以是包含C 4 -C 7异烯烃衍生单元，对甲基苯乙烯衍生单元和对 - （卤甲基苯乙烯）衍生单元的聚合物，或者可以是丁基型橡胶。纳米复合材料可通过使无机粘土的含水浆料与聚合物胶泥接触，同时剧烈搅拌以形成乳液或微乳液以密切混合无机粘土和弹性体来形成。这样形成的纳米复合材料具有改进的空气阻隔性能，并且适合用作内衬或内管。

9. 发明申请

WO2004005387A1 FUNCTIONALIZED ELASTOMER NANOCOMPOSITE 审中-公开
标题翻译：功能性弹性体纳米复合材料
公开(公告)号：WO2004005387A1
公开(公告)日：2004-01-15
申请号：PCT/US2003/016944
申请日：2003-05-30
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , GONG, Caiguo , DIAS, Anthony, J. , TSOU, Andy, H. , POOLE, Beverly, J. , KARP, Kriss, R.
发明人： GONG, Caiguo , DIAS, Anthony, J. , TSOU, Andy, H. , POOLE, Beverly, J. , KARP, Kriss, R.
IPC分类号： C08K3/34
CPC分类号： C08K3/346 , C08L51/00 , C08L23/22
摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C 2 to C 10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene- co-p -alkylstyrene) elastomers and poly(isobutylene- co -isoprene) elastomers, which are functionalized via Friedel-Crafts reaction with a Lewis acid and a functionalizing agent such as acid anhydrides and/or acylhalides. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.
摘要翻译：本发明的一个实施方案是纳米复合材料，其包含粘土和包含至少C2-C10烯烃衍生单元的弹性体; 其中弹性体还包括垂直于弹性体的官能化单体单元。弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过与路易斯酸和官能化试剂如酸酐和/ 或酰卤。粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。本发明的纳米复合材料具有改进的空气阻隔性能，例如可用于轮胎内衬和内管。

10. 发明申请

WO2002100923A2 LOW PERMEABILITY NANOCOMPOSITES 审中-公开
标题翻译：低渗透性纳米复合材料
公开(公告)号：WO2002100923A2
公开(公告)日：2002-12-19
申请号：PCT/US2002/016794
申请日：2002-05-29
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , TSOU, Andy, H. , DIAS, Anthony, J.
发明人： TSOU, Andy, H. , DIAS, Anthony, J.
IPC分类号： C08J
CPC分类号： C08L23/22 , C08K3/346 , C08L21/00 , C08L23/283 , C08L77/00 , C08L23/28 , C08L2666/20 , C08L2666/04 , C08L2666/02
摘要： The present invention is a blend of a thermoplastic engineering resin and an interpolymer of, an one embodiment, a C 4 to C 7 isomonoolefin, a para-methylstyrene and a para-(halomethylstyrene), the interpolymer having been premixed with an exfoliated-clay, the entire blend forming a nanocomposite. The resin may or may not have a clay present prior to blending with the interpolymer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an air barrier.
摘要翻译：本发明是一种热塑性工程树脂和一种互聚物的混合物，一种实施方案是C4至C7异单烯烃，对甲基苯乙烯和对 - （卤代甲基苯乙烯），该互聚物已经与剥落粘土预混合，整个共混物形成纳米复合材料。在与共聚体共混之前，树脂可以具有也可以不具有粘土。互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。本发明的共混物具有改善的空气阻隔性能，并且适合作为空气屏障。

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