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1. 发明申请

US20160137807A1 POLYARYLENE SULFIDE RESIN COMPOSITION AND METHOD FOR PRODUCING SAME 有权
标题翻译：聚亚烷基硫酸酯树脂组合物及其生产方法
公开(公告)号：US20160137807A1
公开(公告)日：2016-05-19
申请号：US14901322
申请日：2014-06-18
申请人： TORAY INDUSTRIES, INC.
发明人： Shu Kaiho , Shunsuke Horiuchi , Kenji Ishitake , Koji Yamauchi
IPC分类号： C08K3/08
CPC分类号： C08K3/08 , C08K2003/0862 , C08K2201/003 , C08L81/02
摘要： A polyarylene sulfide resin composition containing nickel microparticles having an average particle diameter of 0.5 to 20 nm is produced by heating a cyclic polyarylene sulfide in the presence of at least one component selected from components (i), (ii) and (iii).
摘要翻译：含有平均粒径为0.5〜20nm的镍微粒的聚芳硫醚树脂组合物是通过在至少一种选自组分（ⅰ），（ⅱ）和（ⅲ）的组分存在下，加热环状聚芳硫醚来制备的。

2. 发明授权

US10294330B2 Polyphenylene sulfide resin composition and method of manufacturing same 有权
公开(公告)号：US10294330B2
公开(公告)日：2019-05-21
申请号：US15748584
申请日：2016-07-22
申请人： Toray Industries, Inc.
发明人： Hidenobu Takao , Shu Kaiho , Shunsuke Horiuchi
IPC分类号： C08K3/08 , C08L81/02 , C08G75/0209
摘要： A polyphenylene sulfide resin composition includes a polyphenylene sulfide resin (a) of 90 to 50% by weight and a polyphenylene sulfide resin (b) and/or a polyphenylene sulfide resin (c) of the total of 10 to 50% by weight blended with the polyphenylene sulfide resin (a), relative to the total of the polyphenylene sulfide resins (a) to (c) as 100% by weight, in which the polyphenylene sulfide resin composition has a change rate of viscosity of 1.5 times or less when the composition is heated at 320° C. for 5 hours.

3. 发明授权

US09029484B2 Production method of polyarylene sulfide, cyclic polyarylene sulfide pellet and production method thereof 有权
标题翻译：聚芳硫醚，环状聚芳硫醚丸的制造方法及其制造方法
公开(公告)号：US09029484B2
公开(公告)日：2015-05-12
申请号：US14381803
申请日：2013-02-27
申请人： Toray Industries, Inc.
发明人： Akinori Kanomata , Yosuke Nishimura , Shunsuke Horiuchi , Shu Kaiho , Kazusada Takeda , Koji Yamauchi , Junya Suzuki
IPC分类号： C08F283/00 , C08G75/14 , C08G75/06 , C08J3/12 , B29B13/00
CPC分类号： C08G75/14 , B29B13/00 , C08G75/02 , C08G75/06 , C08J3/12 , C08J2381/04
摘要： A production method includes a process (I) of heating a cyclic polyarylene sulfide composition under reduced pressure and a process (II) of heating and polymerizing a cyclic polyarylene sulfide composition. This simple method allows for production of a polyarylene sulfide of the higher molecular weight and can produce a polyarylene sulfide having a narrow molecular weight distribution, low gas generation and high industrial usability. Additionally, pelletization after the process (I) can produce a cyclic polyarylene sulfide pellet having ease of conveyance, excellent molding processability, less gas generation amount and high industrial usability.
摘要翻译：制备方法包括在减压下加热环状聚芳硫醚组合物的方法（I）和加热和聚合环状聚芳硫醚组合物的方法（II）。这种简单的方法允许生产较高分子量的聚芳硫醚，并且可以生产具有窄分子量分布，低气体产生和高工业可用性的聚芳硫醚。另外，工序（I）之后的造粒可以制造出具有易于输送，优异的成型加工性，较少气体产生量和高工业可用性的环状聚芳硫醚丸粒。

4. 发明申请

US20150057429A1 PRODUCTION METHOD OF POLYARYLENE SULFIDE, CYCLIC POLYARYLENE SULFIDE PELLET AND PRODUCTION METHOD THEREOF 有权
标题翻译：聚亚烷基硫化物，环状聚亚烷基硫酸酯粒料的生产方法及其生产方法
公开(公告)号：US20150057429A1
公开(公告)日：2015-02-26
申请号：US14381803
申请日：2013-02-27
申请人： Toray Industries, Inc.
发明人： Akinori Kanomata , Yosuke Nishimura , Shunsuke Horiuchi , Shu Kaiho , Kazusada Takeda , Koji Yamauchi , Junya Suzuki
IPC分类号： C08G75/14 , C08J3/12
CPC分类号： C08G75/14 , B29B13/00 , C08G75/02 , C08G75/06 , C08J3/12 , C08J2381/04
摘要： A production method includes a process (I) of heating a cyclic polyarylene sulfide composition under reduced pressure and a process (II) of heating and polymerizing a cyclic polyarylene sulfide composition. This simple method allows for production of a polyarylene sulfide of the higher molecular weight and can produce a polyarylene sulfide having a narrow molecular weight distribution, low gas generation and high industrial usability. Additionally, pelletization after the process (I) can produce a cyclic polyarylene sulfide pellet having ease of conveyance, excellent molding processability, less gas generation amount and high industrial usability.
摘要翻译：制备方法包括在减压下加热环状聚芳硫醚组合物的方法（I）和加热和聚合环状聚芳硫醚组合物的方法（II）。这种简单的方法允许生产较高分子量的聚芳硫醚，并且可以生产具有窄分子量分布，低气体产生和高工业可用性的聚芳硫醚。另外，工序（I）之后的造粒可以制造出具有易于输送，优异的成型加工性，较少气体产生量和高工业可用性的环状聚芳硫醚丸粒。

5. 发明申请

US20180223046A1 POLYPHENYLENE SULFIDE RESIN COMPOSITION AND METHOD OF MANUFACTURING SAME 审中-公开
公开(公告)号：US20180223046A1
公开(公告)日：2018-08-09
申请号：US15748584
申请日：2016-07-22
申请人： Toray Industries, Inc.
发明人： Hidenobu Takao , Shu Kaiho , Shunsuke Horiuchi
IPC分类号： C08G75/0209 , C08L81/02 , C08K3/08
CPC分类号： C08G75/0209 , C08K3/08 , C08K2003/0818 , C08L81/02
摘要： A polyphenylene sulfide resin composition includes a polyphenylene sulfide resin (a) of 90 to 50% by weight and a polyphenylene sulfide resin (b) and/or a polyphenylene sulfide resin (c) of the total of 10 to 50% by weight blended with the polyphenylene sulfide resin (a), relative to the total of the polyphenylene sulfide resins (a) to (c) as 100% by weight, in which the polyphenylene sulfide resin composition has a change rate of viscosity of 1.5 times or less when the composition is heated at 320° C. for 5 hours.

6. 发明授权

US10000620B2 Polyarylene sulfide resin composition and method for producing same 有权
公开(公告)号：US10000620B2
公开(公告)日：2018-06-19
申请号：US14901322
申请日：2014-06-18
申请人： TORAY INDUSTRIES, INC.
发明人： Shu Kaiho , Shunsuke Horiuchi , Kenji Ishitake , Koji Yamauchi
IPC分类号： C08G75/14 , C08K3/08
CPC分类号： C08K3/08 , C08K2003/0862 , C08K2201/003 , C08L81/02
摘要： A polyarylene sulfide resin composition containing nickel microparticles having an average particle diameter of 0.5 to 20 nm is produced by heating a cyclic polyarylene sulfide in the presence of at least one component selected from components (i), (ii) and (iii).

7. 发明授权

US09796850B2 Polyarylene sulfide resin composition, manufacturing method of resin composition and molded product of resin composition 有权
公开(公告)号：US09796850B2
公开(公告)日：2017-10-24
申请号：US14396857
申请日：2013-04-26
申请人： Toray Industries, Inc.
发明人： Akinori Kanomata , Shunsuke Horiuchi , Shu Kaiho , Koji Yamauchi
IPC分类号： C08L81/04 , C08J3/00 , C08K5/5435 , C08G75/02 , C08L81/02
CPC分类号： C08L81/04 , C08G75/02 , C08J3/005 , C08J2381/04 , C08J2481/04 , C08K5/5435 , C08L81/02 , C08L2201/02 , C08L2203/202 , C08L2205/025
摘要： A reactive functional group-containing polyarylene sulfide resin composition having a narrow polydispersity and a low gas generation amount is manufactured by mixing a polyarylene sulfide resin (a) and a polyarylene sulfide resin (b), wherein the polyarylene sulfide (a) has a weight reduction ratio ΔWr of not higher than 0.18% under heating and an increase rate of melt viscosity of less than 1.05 times by addition of a reactive compound (c) having a reactive group relative to melt viscosity prior to addition of the reactive compound (c), and the polyarylene sulfide (b) has the weight reduction ratio ΔWr of not higher than 0.18% under heating and the increase rate of melt viscosity of not less than 1.05 times by addition of the reactive compound (c) having the reactive group relative to melt viscosity prior to addition of the reactive compound (c).

8. 发明申请

US20150126668A1 POLYARYLENE SULFIDE RESIN COMPOSITION, MANUFACTURING METHOD OF RESIN COMPOSITION AND MOLDED PRODUCT OF RESIN COMPOSITION 有权
标题翻译：聚酰亚胺树脂组合物，树脂组合物的制造方法和树脂组合物的成型产品
公开(公告)号：US20150126668A1
公开(公告)日：2015-05-07
申请号：US14396857
申请日：2013-04-26
申请人： Toray Industries, Inc.
发明人： Akinori Kanomata , Shunsuke Horiuchi , Shu Kaiho , Koji Yamauchi
IPC分类号： C08L81/04 , C08J3/00
CPC分类号： C08L81/04 , C08G75/02 , C08J3/005 , C08J2381/04 , C08J2481/04 , C08K5/5435 , C08L81/02 , C08L2201/02 , C08L2203/202 , C08L2205/025
摘要： A reactive functional group-containing polyarylene sulfide resin composition having a narrow polydispersity and a low gas generation amount is manufactured by mixing a polyarylene sulfide resin (a) and a polyarylene sulfide resin (b), wherein the polyarylene sulfide (a) has a weight reduction ratio ΔWr of not higher than 0.18% under heating and an increase rate of melt viscosity of less than 1.05 times by addition of a reactive compound (c) having a reactive group relative to melt viscosity prior to addition of the reactive compound (c), and the polyarylene sulfide (b) has the weight reduction ratio ΔWr of not higher than 0.18% under heating and the increase rate of melt viscosity of not less than 1.05 times by addition of the reactive compound (c) having the reactive group relative to melt viscosity prior to addition of the reactive compound (c).
摘要翻译：通过混合聚芳硫醚树脂（a）和聚芳硫醚树脂（b）制备具有窄多分散性和低气体产生量的反应性官能团聚芳硫醚树脂组合物，其中聚芳硫醚（a）具有重量减少率＆Dgr; Wr在加热下不高于0.18％，并且在加入反应性化合物之前加入相对于熔体粘度具有反应性基团的反应性化合物（c），熔体粘度的增加速率小于1.05倍（ c），聚芳硫醚（b）在加热下的重量减少率＆Dgr; Wr不高于0.18％，熔体粘度的增加率不低于1.05倍，反应性化合物（c）反应性基团相对于加入反应性化合物（c）之前的熔体粘度。

9. 发明授权

US09000104B2 Polyarylene sulfide 有权
标题翻译：聚芳硫醚
公开(公告)号：US09000104B2
公开(公告)日：2015-04-07
申请号：US14296869
申请日：2014-06-05
申请人： Toray Industries, Inc.
发明人： Akinori Kanomata , Shunsuke Horiuchi , Shu Kaiho , Koji Yamauchi
IPC分类号： C08G75/14 , C08G75/02
CPC分类号： C08G75/14 , C08G75/02
摘要： A polyarylene sulfide includes 0.01 to 5 mol %, per mol of arylene sulfide structural units, of a function group selected from the group consisting of an amino group, a carboxyl group, a hydroxyl group, an acid anhydride group, an isocyanate group, an epoxy group, a silanol group, and an alkoxysilane group having a dispersity represented by (weight average molecular weight)/(number average molecular weight) of 2.5 or less and a weight loss ratio at 100° C. to 330° C. of 0.2% by weight or less when the polyarylene sulfide is subjected to thermogravimetric analysis from 50° C. to 340° C. at a temperature ramp-up rate of 20° C./min under a non-oxidative atmosphere of normal pressure.
摘要翻译：聚芳硫醚包括0.01mol％至5mol％的芳族硫醚结构单元，其选自氨基，羧基，羟基，酸酐基，异氰酸酯基，异氰酸酯基，环氧基，硅烷醇基和具有由（重均分子量）/（数均分子量）表示的分散度为2.5以下，100℃〜330℃的重量减少率为0.2的烷氧基硅烷基，为0.2 当聚芳撑硫醚在常压下的非氧化性气氛下以20℃/ min的升温速度从50℃至340℃进行热重分析时，重量％以下。

10. 发明申请

US20140288263A1 POLYARYLENE SULFIDE 审中-公开
标题翻译：聚氨酯硫化物
公开(公告)号：US20140288263A1
公开(公告)日：2014-09-25
申请号：US14296869
申请日：2014-06-05
申请人： Toray Industries, Inc.
发明人： Akinori Kanomata , Shunsuke Horiuchi , Shu Kaiho , Koji Yamauchi
IPC分类号： C08G75/14
CPC分类号： C08G75/14 , C08G75/02
摘要： A polyarylene sulfide includes 0.01 to 5 mol %, per mol of arylene sulfide structural units, of a function group selected from the group consisting of an amino group, a carboxyl group, a hydroxyl group, an acid anhydride group, an isocyanate group, an epoxy group, a silanol group, and an alkoxysilane group having a dispersity represented by (weight average molecular weight)/(number average molecular weight) of 2.5 or less and a weight loss ratio at 100° C. to 330° C. of 0.2% by weight or less when the polyarylene sulfide is subjected to thermogravimetric analysis from 50° C. to 340° C. at a temperature ramp-up rate of 20° C./min under a non-oxidative atmosphere of normal pressure.
摘要翻译：聚芳硫醚包括0.01mol％至5mol％的芳族硫醚结构单元，其选自氨基，羧基，羟基，酸酐基，异氰酸酯基，异氰酸酯基，环氧基，硅烷醇基和具有由（重均分子量）/（数均分子量）表示的分散度为2.5以下，100℃〜330℃的重量减少率为0.2的烷氧基硅烷基，为0.2 当聚芳撑硫醚在常压下的非氧化性气氛下以20℃/ min的升温速度从50℃至340℃进行热重分析时，重量％以下。

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