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    • 1. 发明授权
    • Exhaust gas purification device for an engine
    • 发动机废气净化装置
    • US5746052A
    • 1998-05-05
    • US525892
    • 1995-09-08
    • Yukio KinugasaKouhei IgarashiTakaaki ItouTakehisa YaegashiToshifumi Takaoka
    • Yukio KinugasaKouhei IgarashiTakaaki ItouTakehisa YaegashiToshifumi Takaoka
    • B01D53/94F01N3/20F01N3/22F01N3/24F01N13/02F01N13/04F02D41/04
    • B01D53/9454B01D53/9431B01D53/9477B01D53/9495F01N13/009F01N13/011F01N3/20F01N3/206F01N2240/25F01N2570/14F01N2610/02Y02T10/22
    • In the present invention, the exhaust gas from the engine is divided into a first and a second branch exhaust passages after it passes through a three-way reducing and oxidizing catalyst, and the two branch exhaust passages merge into an exhaust gas outlet passage. In the first branch exhaust passage, an oxidizing catalyst is disposed, and in the exhaust gas outlet passage, a denitrating and oxidizing catalyst is disposed. NO.sub.x in the exhaust gas from the engine is all converted to N.sub.2 and NH.sub.3 by the three-way reducing and oxidizing catalyst and a part of the NH.sub.3 generated by the three-way catalyst flows into the first branch exhaust passage and is converted to NO.sub.x again by the oxidizing catalyst. The amount of NO.sub.x produced by the oxidizing catalyst and the amount of NO.sub.x flowing through the second branch exhaust passage is determined by the flow distribution ratio of the first and the second branch exhaust passages. In this invention, the flow ratio is determined in such a manner that the amount of the NO.sub.x produced by the oxidizing catalyst and the amount of the NH.sub.3 passing through the second branch exhaust passage are stoichiometric to produce N.sub.2 and H.sub.2 O. Therefore, when these exhaust gases flow into the denitrating and oxidizing catalyst after they mix with each other in the exhaust gas outlet passage, all the NO.sub.x and the NH.sub.3 are converted to N.sub.2 and H.sub.2 O by the denitrating and oxidizing catalyst without producing any surplus NO.sub.x or NH.sub.3.
    • 在本发明中,来自发动机的废气在通过三通还原氧化催化剂后被分成第一和第二分支排气通道,两个分支排气通道合流到废气出口通道中。 在第一分支排气通道中设置氧化催化剂,并且在排气出口通道中设置脱硝和氧化催化剂。 来自发动机的废气中的NOx通过三元还原氧化催化剂全部转化为N 2和NH 3,并且由三元催化剂产生的一部分NH 3流入第一分支排气通道并再次转化为NOx 通过氧化催化剂。 由氧化催化剂产生的NOx的量和流过第二分支排气通道的NOx的量由第一和第二分支排气通道的流量分配比确定。 在本发明中,流量比以如下方式确定:氧化催化剂产生的NOx的量和通过第二分支排气通道的NH 3的量是化学计量的,以产生N 2和H 2 O. 因此,当这些废气在废气出口通道中彼此混合后流入脱硝和氧化催化剂时,所有的NOx和NH 3都被脱硝和氧化催化剂转化为N 2和H 2 O,而不产生任何剩余的NOx或 NH3。
    • 3. 发明授权
    • Exhaust gas purification device for an engine
    • 发动机废气净化装置
    • US06409973B1
    • 2002-06-25
    • US08523455
    • 1995-09-05
    • Yukio KinugasaToshifumi TakaokaKouhei IgarashiTakaaki Itou
    • Yukio KinugasaToshifumi TakaokaKouhei IgarashiTakaaki Itou
    • B01D5314
    • B01D53/9481B01D53/9495F01N3/0842F01N3/0871F01N3/0878F01N3/22F01N13/011F01N2270/00F01N2410/12F01N2610/03F01N2610/04F02B1/04
    • The exhaust gas purification device according to the present invention utilizes two NOx absorbents in order to remove NOx from the exhaust gas of an engine operated at a lean air-fuel ratio. The NOx absorbents are disposed, in series, in the exhaust passage of the engine and a nozzle for supplying a reducing agent is disposed in the exhaust passage at a position between the two NOx absorbents. Further, the device includes switching valves for changing the direction of the exhaust gas flow in the exhaust gas passage. When the switching valves are set to direct the exhaust gas flow to one direction, the exhaust gas first flows through one of the NOx absorbents (first NOx absorbent), and after passing through the first NOx absorbent, the reducing agent is supplied to the exhaust gas before it flows into the other NOx absorbent (second NOx absorbent). Thus, the first NOx absorbent absorbs NOx in the exhaust gas, and the NOx absorbed by the second NOabsorbent is released from the second NOx absorbent. When the switching valves are switched, the exhaust gas flows in the opposite direction, and flows through the second NOx absorbent and the first NOx absorbent in this order. In this case, the second NOx absorbent absorbs NOx in the exhaust gas, and the NOx absorbed by the first NOx absorbent is released and reduced to N2. Therefore, by reversing the direction of the exhaust gas periodically, the absorbing operation of NOx and releasing/reducing operation of NOx are performed by two NOx absorbents alternately. Thus, it becomes possible to remove NOx in the exhaust gas continuously while the NOx absorbents are prevented from being saturated by the absorbed NOx.
    • 根据本发明的排气净化装置利用两个NOx吸收剂来从以稀空燃比运转的发动机的废气中除去NOx。 NOx吸收剂串联设置在发动机的排气通道中,并且用于供给还原剂的喷嘴设置在排气通道中的两个NOx吸收剂之间的位置。 此外,该装置包括用于改变排气通道中的排气流的方向的切换阀。 当切换阀被设定为将废气流引导到一个方向时,废气首先流过NOx吸收剂之一(第一NOx吸收剂),并且在通过第一NOx吸收剂之后,还原剂被供给到排气 气体在其流入另一个NOx吸收剂(第二NOx吸收剂)之前。 因此,第一NOx吸收剂吸收废气中的NOx,并且由第二NO吸收剂吸收的NOx从第二NOx吸收剂释放。 当切换阀切换时,排气沿相反方向流动,并且依次流过第二NOx吸收剂和第一NOx吸收剂。 在这种情况下,第二NOx吸收剂吸收废气中的NOx,并且由第一NOx吸收剂吸收的NOx被释放并且还原成N2。 因此,通过周期性地反转排气的方向,NOx的吸收运转和NOx的释放/还原运转由两个NOx吸收剂交替进行。 因此,可以连续地除去排气中的NOx,同时防止NOx吸收剂被吸收的NOx饱和。
    • 4. 发明授权
    • Method for purifying combustion exhaust gas
    • 燃烧废气净化方法
    • US5783160A
    • 1998-07-21
    • US590714
    • 1996-01-24
    • Yukio KinugasaKouhei IgarashiTakaaki ItouToshifumi TakaokaMichihiro OhashiKoji Yokota
    • Yukio KinugasaKouhei IgarashiTakaaki ItouToshifumi TakaokaMichihiro OhashiKoji Yokota
    • B01D53/94F01N3/08F01N3/20F01N3/22F01N13/02B01D53/58
    • B01D53/9481B01D53/9409B01D53/9436B01D53/9495F01N13/009F01N3/0842F01N3/0871F01N3/206F01N3/22F01N3/222F01N2230/04F01N2240/25F01N2250/12F01N2610/02Y02T10/22
    • The method for purifying combustion exhaust gas according to the present invention utilizes a NH.sub.3 decomposing catalyst. The NH.sub.3 decomposing catalyst in the present invention is capable of converting substantially all of the NH.sub.3 in the combustion exhaust gas to N.sub.2 when the air-fuel ratio of the exhaust gas is lean and the temperature of the catalyst is within a predetermined optimum temperature range. Further, when the exhaust gas contains NO.sub.x in addition to NH.sub.3, the NH.sub.3 decomposing catalyst is capable of reducing the NO.sub.x in the optimum temperature range even though the air-fuel ratio of the exhaust gas is lean. In the present invention, the conditions of the exhaust gas containing NO.sub.x are adjusted before it is fed to the NH.sub.3 decomposing catalyst in such a manner that the temperature of the exhaust gas is within the optimum temperature range and the air-fuel ratio of the exhaust gas is lean. Further, NH.sub.3 is added to the exhaust gas before it is fed to the NH.sub.3 decomposing catalyst. Therefore, a lean air-fuel ratio exhaust gas, at a temperature within the optimum temperature range, which contains both the NO.sub.x and NH.sub.3 is fed to the NH.sub.3 decomposing catalyst, and the NO.sub.x, as well as the NH.sub.3, in the exhaust gas is completely resolved by the NH.sub.3 decomposing catalyst.
    • 根据本发明的用于净化燃烧废气的方法利用NH 3分解催化剂。 本发明中的NH 3分解催化剂能够在排气的空燃比稀薄且催化剂的温度在预定的最佳温度范围内时将燃烧废气中的NH 3基本上全部转化成N2。 此外,当排气中含有除NH 3之外的NOx时,NH 3分解催化剂即使在排气的空燃比较稀的情况下也能够将NOx还原到最佳温度范围。 在本发明中,在将废气的温度设定在最佳温度范围内并排气的空燃比的方式调节含有NOx的废气的条件,然后送入NH 3分解催化剂 气体很瘦 此外,在将其输入到NH 3分解催化剂之前,将NH 3加入到废气中。 因此,在含有NOx和NH 3的最佳温度范围内的温度下,贫空燃比废气被供给到NH 3分解催化剂中,排气中的NOx以及NH 3是 完全由NH3分解催化剂分解。