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    • 3. 发明公开
    • CONJUGATED DIENE POLYMER AND METHOD FOR PRODUCING SAME
    • KONJUGIERTES DIENPOLYMER UND HERSTELLUNGSVERFAHRENDAFÜR
    • EP2749579A1
    • 2014-07-02
    • EP12832404.3
    • 2012-09-04
    • Zeon CorporationKyoto University
    • BANDO FumiakiOKUNO ShingoHAYANO ShigetakaSAWAMOTO MitsuoOUCHI Makoto
    • C08F36/04C07F9/50C07F15/00C07F19/00C08F4/80
    • C08F136/08C07F9/5022C07F15/0046C07F17/02C08C19/12C08F4/72C08F4/80C08F36/04C08F236/04C08F236/08C08F236/10C08F236/12C08F236/16C08F220/44C08F12/08C08F4/6192
    • [PTOBLEM TO BE SOLVED]
      To provide a conjugated diene polymer that bears a halogen atom at a terminal of a polymer chain, the halogen atom permitting easy introduction of a desired functional group into the terminal of the polymer chain, and exhibits excellent moldability, and a method for producing the same.
      [SOLUTION]
      The conjugated diene polymer comprising at least a conjugated diene monomer unit, wherein the conjugated diene polymer has a number-average molecular weight (Mn) in terms of polystyrene of 1,000 to 1,000,000, a ratio (Mw/Mn) of a weight-average molecular weight (Mw) to the number-average molecular weight (Mn) of lower than 2.0 and the polymer bears a halogen atom at a terminal of the polymer chain. The method for producing the conjugated diene polymer comprises subjecting a monomer containing at least a conjugated diene to living radical polymerization using a polymerization initiator comprising a halogenocyclopentadienyl triorganophosphine η 2 -olefin ruthenium complex represented by formula (6) (wherein R 11 , R 12 , R 13 and R 14 each represent a hydrogen atom, a cyano group, a carbonyl group, an ester group, an amide group, a nitro group or a halogen atom (with the proviso that at least one of R 11 , R 12 , R 13 and R 14 is not a hydrogen atom) ; R 15 represents a chlorine atom, a bromine atom or an iodine atom; R 16 , R 17 and R 18 each represent an optionally substituted organic group having 1 to 10 carbon atoms; R 16 , R 17 and R 18 may be the same as or different from each other; and L represents an optionally substituted cyclopentadienyl ring) and an organic halide.
    • 要解决的问题为了提供在聚合物链的末端具有卤素原子的共轭二烯聚合物,可以容易地将所需的官能团引入聚合物链的末端的卤素原子,并且显示出优异的成型性,以及 其制造方法。 [解决方案]至少包含共轭二烯单体单元的共轭二烯聚合物,其中共聚二烯聚合物的聚苯乙烯换算的数均分子量(Mn)为1,000至1,000,000,重量比(Mw / Mn) - 平均分子量(Mw)至数均分子量(Mn)低于2.0,并且聚合物在聚合物链末端具有卤素原子。 共轭二烯系聚合物的制造方法包括使用包含式(6)表示的卤代环戊二烯基三有机膦化合物·2-烯烃钌络合物的聚合引发剂(其中,R 11,R 12, R 13和R 14各自表示氢原子,氰基,羰基,酯基,酰胺基,硝基或卤素原子(条件是R 11,R 12,R 13和R 14不是氢原子); R 15表示氯原子,溴原子或碘原子; R 16,R 17和R 18各自表示可以具有取代基的碳原子数为1〜10的有机基团; R 16 ,R 17和R 18可以彼此相同或不同; L表示任选取代的环戊二烯基环)和有机卤化物。
    • 6. 发明公开
    • DYE-SENSITIZED SOLAR-CELL ELEMENT
    • 染料敏化太阳能电池元件
    • EP2978001A1
    • 2016-01-27
    • EP14770584.2
    • 2014-03-20
    • Zeon Corporation
    • OHTA KeisukeHAYANO Shigetaka
    • H01G9/20
    • H01G9/2009H01G9/2013H01G9/2022H01G9/2027H01G9/2031H01G9/2059Y02E10/542
    • The present invention is a dye-sensitized solar cell element comprising a semiconductor electrode that comprises an electrode substrate, and a metal oxide semiconductor porous film that is provided on the electrode substrate and supports a dye, a counter electrode that is disposed opposite to the semiconductor electrode, and an electrolyte layer that is provided between the semiconductor electrode and the counter electrode, the counter electrode comprising a nano-carbon material, and the electrolyte layer comprising a polyether compound that has a specific onium-structure repeating unit. The present invention makes it possible to provide a dye-sensitized solar cell element that exhibits high photoelectric conversion efficiency as compared with a known dye-sensitized solar cell element.
    • 本发明是一种染料敏化太阳能电池元件,其包括:半导体电极,其包括电极基板和设置在电极基板上并支撑染料的金属氧化物半导体多孔膜;对向电极,其与半导体相对设置 以及设置在所述半导体电极与所述对电极之间的电解质层,所述对电极包含纳米碳材料,并且所述电解质层包含具有特定鎓结构重复单元的聚醚化合物。 本发明使得可以提供与已知的染料敏化太阳能电池元件相比表现出高光电转换效率的染料敏化太阳能电池元件。