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1. 发明公开

CN1720648A 含金刚石状体的材料的光学应用无效
公开(公告)号：CN1720648A
公开(公告)日：2006-01-11
申请号：CN03825780.7
申请日：2003-07-17
申请人：切夫里昂美国公司
发明人： J·E·达尔 , R·M·卡尔森 , 刘升高
IPC分类号： H01S3/16 , H01S5/30 , G02B1/11 , H01L51/30
CPC分类号： C23C16/27 , C23C16/278 , G02B1/111 , H01S3/14 , H01S3/163 , H01S3/1681 , Y10T428/30
摘要：公开了基于含金刚石状体材料的新型光学器件。可以由金刚石状体制造的材料包括金刚石状体形核的CVD薄膜，含金刚石状体CVD薄膜，分子晶体，和聚合物材料。这里公开的由含金刚石状体材料制造的器件包括固态染料激光器，半导体激光器，发光二极管，光电探测器，光敏电阻，光电晶体管，光生伏打电池，太阳能电池，抗反射涂层，透镜，镜面，压力窗，光波导，以及粒子和辐射探测器。

2. 发明公开

EP0275063A2 Light emitting element comprising diamond and method for producing the same 失效
标题翻译：元素和Verfahren zu seiner Herstellung的Diamanthaltiges lichtausstrahlendes
公开(公告)号：EP0275063A2
公开(公告)日：1988-07-20
申请号：EP88100252.1
申请日：1988-01-11
申请人： SUMITOMO ELECTRIC INDUSTRIES LIMITED
发明人： Satoh, Shyuichi Itami Works of Sumitomo El.Ind.Ltd , Tsuji, Kazuwo Itami Works of Sumitomo El.Ind.Ltd
IPC分类号： H01S3/16 , B01J3/06
CPC分类号： H01S3/1681 , C30B29/04 , C30B33/00
摘要： A light emitting element comprising diamond which contains N-V color centers in a maximum optical density of of 0.01 to 3.5 in a direction of excitation light, Ib type nitrogen atoms in a maximum optical density not larger than 0.2 in a wavelength range of 530 to 610 nm and optionally H3 color centers, which element can be efficiently produced from artificial diamond by a combination of irradiation by an electron beam or a neutron beam and annealing.
摘要翻译：包含金刚石的发光元件，其在激发光的方向上具有0.01至3.5的最大光密度的NV颜色中心，在530至610nm的波长范围内具有不大于0.2的最大光密度的Ib型氮原子和任选的H3颜色中心，通过电子束或中子束的照射和退火的组合，可以通过人造金刚石有效地产生该元素。

3. 发明申请

WO1986003347A1 SOLID STATE LASER EMPLOYING DIAMOND HAVING COLOR CENTERS AS A LASER ACTIVE MATERIAL 审中-公开
标题翻译：固体激光器作为激光活性材料使用彩色中心的钻石
公开(公告)号：WO1986003347A1
公开(公告)日：1986-06-05
申请号：PCT/US1985002122
申请日：1985-10-28
申请人： HUGHES AIRCRAFT COMPANY
发明人： HUGHES AIRCRAFT COMPANY , RAND, Stephen, C. , DeSHAZER, Larry, G.
IPC分类号： H01S03/16
CPC分类号： H01S3/1681 , C30B29/04 , C30B31/22 , C30B33/00
摘要： A diamond (10) containing H3 and N3 color centers is employed as a laser active material in a color center laser. When excited by a suitable optical pumping source (22), the H3 color centers exhibit laser action and provide a beam (26, 28) which is tunable over the range of 500 to 600 nanometers.

4. 发明申请

WO2010024447A2 COLOR CENTER-CONTAINING MAGNESIUM OXIDE AND THIN FILM OF SAME, WAVELENGTH-VARIABLE LASER MEDIUM, LASER DEVICE, AND LIGHT SOURCE DEVICE 审中-公开
标题翻译：含颜料中心氧化镁和薄膜，波长可变激光介质，激光器件和光源设备
公开(公告)号：WO2010024447A2
公开(公告)日：2010-03-04
申请号：PCT/JP2009065252
申请日：2009-09-01
申请人： NEW IND RES ORGANIZATION , UCHINO TAKASHI , OKUTSU DAISUKE
发明人： UCHINO TAKASHI , OKUTSU DAISUKE
IPC分类号： H01S3/16 , C01F5/04 , C09K11/55 , H01J29/20 , H01J31/12
CPC分类号： H01J31/12 , C01F5/04 , C09K11/636 , C30B1/10 , C30B29/16 , H01S3/163 , H01S3/1681 , H01S3/1685 , H01S3/30
摘要： Provided is a color center laser medium that is a wide-spectrum laser medium with a laser oscillation wavelength band that ranges from a near-ultraviolet region, with a shorter wavelength than that of a conventional laser medium utilizing color centers, to the visible region, and that is capable of operating at room temperature without requiring a laser cavity and liquid nitrogen cooling. The color center-containing magnesium oxide is created by means of a solid-phase reaction between silicon monoxide (SiO), boron trioxide (B2O3), or ferric oxide (Fe2O3) and metallic magnesium. The wavelength-variable laser medium then utilizes color centers (color center) in the magnesium oxide created by the solid-phase reaction. More specifically, silicon monoxide and metallic magnesium are heated for several hours in an argon atmosphere at a prescribed temperature in order to obtain a magnesium oxide sublimate. Laser oscillation occurs by the sublimate being directly irradiated with an excitation pulsed laser beam using a pump energy higher than a prescribed energy that is the laser oscillation threshold value.
摘要翻译：提供了一种彩色中心激光介质，其是具有激光振荡波长带的宽频激光介质，其波长比使用彩色中心的传统激光介质的波长短的近紫外区域到可见光区域，并且能够在室温下操作而不需要激光腔和液氮冷却。含有着色中心的氧化镁通过一氧化硅（SiO），三氧化硼（B2O3）或氧化铁（Fe2O3）和金属镁之间的固相反应产生。然后，波长可变激光介质利用由固相反应产生的氧化镁中的色心（色心）。更具体地说，一氧化硅和金属镁在规定温度下在氩气气氛中加热数小时，以获得氧化镁升华。使用高于作为激光振荡阈值的规定能量的泵浦能量，通过激发脉冲激光束直接照射的升华发生激光振荡。

5. 发明授权

US07260127B2 Dual layer color-center patterned light source 失效
公开(公告)号：US07260127B2
公开(公告)日：2007-08-21
申请号：US10934251
申请日：2004-09-03
申请人： Anthony D. Kurtz , Joseph R. Van DeWeert
发明人： Anthony D. Kurtz , Joseph R. Van DeWeert
IPC分类号： H01S3/16 , H01S3/14 , H01S3/06
CPC分类号： C30B29/12 , C30B23/00 , C30B33/04 , H01S3/0612 , H01S3/0809 , H01S3/163 , H01S3/1681 , H01S3/2375 , H01S3/2383
摘要： A thin layer of ionic crystal is grown on a substrate. The crystal could be any type of ionic crystal, such as sodium chloride or potassium chloride. The crystal is a pure form of the chosen compound and may contain contaminants which would shift the wavelength of created color centers. On top of the first crystal layer, a second thin layer of a different type of crystal is deposited, such as lithium fluoride or sodium fluoride. When these two layers are radiated with gamma rays, they will each form color centers at the spots radiated. Because of the difference in crystalline properties of the two different ionic crystal centers, their color centers would be at different wavelengths. Each of the two separate ionic crystals will emit light at different characteristic wavelengths when illuminated at their unique absorption frequencies. Each layer can be made to lase separately. The top layer has an absorption energy greater than that of the bottom layer, so that the layer energy of the bottom layer absorption peak will pass through the top layer and be absorbed only by the bottom layer. There are many ways of forming F-centers in the two superimposed layers, such as by the use of selective gamma radiation by heating of an anion layer of the particular compound and then depositing the second ionic crystal on the first ionic crystal and then depositing an anion layer on the second crystal and then heating to produce a structure which will lase it to the different frequencies.

6. 发明申请

US20040028101A1 Solid-state devices with radial dopant valence profile 有权
标题翻译：具有径向掺杂剂价态的固态器件
公开(公告)号：US20040028101A1
公开(公告)日：2004-02-12
申请号：US10119462
申请日：2002-08-06
发明人： Robert W. Byren , David S. Sudima
IPC分类号： H01S003/14
CPC分类号： H01S3/113 , H01S3/061 , H01S3/0617 , H01S3/094084 , H01S3/0941 , H01S3/1623 , H01S3/1643 , H01S3/1681
摘要： A solid state, laser light control device (20, 30) and material (10), and methods of producing same. The device (20, 30) and material (10) consist essentially of a host material (14) which contains: a dopant species (16) at a first valence state (a), the concentration of which increases with distance from the surface (18); and the same dopant species (16) at a second valence state (b), the concentration which decreases with distance from the surface (18). The method comprises the steps of: obtaining a doped solid state material (14); exposing the solid state material (14) to elevated temperature, for a period of time, in an oxidizing or reducing atmosphere. The elevated temperature and time of exposure are selected to change the valence state (a) of the dopant (16) in direct proportion to distance from the surface (18) of the solid state material (16). What is thereby produced is a solid state device (20, 30) in which the concentration of the dopant 16 at the second valence state (b) decreases with radius, the concentration of the dopant (16) at the first valence state (a) increases with radius, and the sum of these concentrations remains constant.
摘要翻译：固态激光控制装置（20,30）和材料（10）及其制造方法。装置（20,30）和材料（10）基本上由主体材料（14）组成，其包含：处于第一价态（a）的掺杂剂物质（16），其浓度随距离表面的距离而增加 18）; 和与第二价态（b）相同的掺杂剂物质（16），其浓度随距表面18的距离而减小。该方法包括以下步骤：获得掺杂固体材料（14）; 在氧化或还原气氛中将固态材料（14）暴露于升高的温度一段时间。选择升高的温度和曝光时间以与固态材料（16）的表面（18）的距离成正比的方式改变掺杂剂（16）的化合价态（a）。由此产生的是固态装置（20,30），其中第二价态（b）的掺杂剂16的浓度随着半径而减小，掺杂剂（16）处于第一价态（a）的浓度，半径增加，这些浓度的总和保持不变。

7. 发明申请

US20030193978A1 Dual layer color-center patterned light source 失效
标题翻译：双层彩色中心图案光源
公开(公告)号：US20030193978A1
公开(公告)日：2003-10-16
申请号：US10120698
申请日：2002-04-11
发明人： Anthony D. Kurtz , Joseph R. Van DeWeert
IPC分类号： H01S003/14
CPC分类号： C30B29/12 , C30B23/00 , C30B33/04 , H01S3/0612 , H01S3/0809 , H01S3/163 , H01S3/1681 , H01S3/2375 , H01S3/2383
摘要： A thin layer of ionic crystal is grown on a substrate. The crystal could be any type of ionic crystal, such as sodium chloride or potassium chloride. The crystal is a pure form of the chosen compound and may contain contaminants which would shift the wavelength of created color centers. On top of the first crystal layer, a second thin layer of a different type of crystal is deposited, such as lithium fluoride or sodium fluoride. When these two layers are radiated with gamma rays, they will each form color centers at the spots radiated. Because of the difference in crystalline properties of the two different ionic crystal centers, their color centers would be at different wavelengths. Each of the two separate ionic crystals will emit light at different characteristic wavelengths when illuminated at their unique absorption frequencies. Each layer can be made to lase separately. The top layer has an absorption energy greater than that of the bottom layer, so that the layer energy of the bottom layer absorption peak will pass through the top layer and be absorbed only by the bottom layer. There are many ways of forming F-centers in the two superimposed layers, such as by the use of selective gamma radiation by heating of an anion layer of the particular compound and then depositing the second ionic crystal on the first ionic crystal and then depositing an anion layer on the second crystal and then heating to produce a structure which will lase it to the different frequencies.
摘要翻译：在衬底上生长薄层的离子晶体。该晶体可以是任何类型的离子晶体，例如氯化钠或氯化钾。晶体是所选化合物的纯形式，并且可能含有污染物，这些污染物将使所产生的色心的波长发生偏移。在第一晶体层的顶部，沉积不同类型晶体的第二薄层，例如氟化锂或氟化钠。当这两层用伽马射线照射时，它们将在辐射的点处形成彩色中心。由于两个不同的离子晶体中心的晶体性质的差异，它们的色心将处于不同的波长。当以其独特的吸收频率照射时，两个分离的离子晶体中的每一个将发射不同特征波长的光。每个层可以分开制作。顶层的吸收能量大于底层的吸收能，使得底层吸收峰的层能量将通过顶层并且仅被底层吸收。在两个叠加层中形成F中心的方法有很多种，例如通过加热特定化合物的阴离子层，然后将第二离子晶体沉积在第一离子晶体上，然后沉积阴离子层在第二个晶体上，然后加热，以产生一个结构，将其延伸到不同的频率。

8. 发明授权

US4880613A Light emitting element comprising diamond and method for producing the same 失效
标题翻译：包含金刚石的发光元件及其制造方法
公开(公告)号：US4880613A
公开(公告)日：1989-11-14
申请号：US143114
申请日：1988-01-12
申请人： Shyuichi Satoh , Kazuwo Tsuji
发明人： Shyuichi Satoh , Kazuwo Tsuji
IPC分类号： C30B33/00 , H01S3/16
CPC分类号： H01S3/1681 , C30B29/04 , C30B33/00
摘要： A light emitting element comprising diamond which contains N-V color centers in a maximum optical density of of 0.01 to 3.5 in a direction of excitation light, Ib type nitrogen atoms in a maximum optical density not larger than 0.2 in a wavelength range of 530 to 610 nm and optionally H3 color centers, which element can be efficiently produced from artificial diamond by a combination of irradiation by an electron beam or a neutron beam and annealing.

9. 发明专利

JPWO2010024447A1 カラーセンター含有酸化マグネシウムとその薄膜、波長可変レーザー媒体、レーザー装置、光源デバイス审中-公开
公开(公告)号：JPWO2010024447A1
公开(公告)日：2012-01-26
申请号：JP2010526818
申请日：2009-09-01
申请人：公益財団法人新産業創造研究機構
发明人：隆司内野 , 隆司内野 , 大輔奥津 , 大輔奥津
IPC分类号： H01S3/16 , C01F5/04 , C09K11/08 , C09K11/55 , C30B1/10 , C30B29/16 , H01S3/094 , H01S3/0959
CPC分类号： H01J31/12 , C01F5/04 , C09K11/636 , C30B1/10 , C30B29/16 , H01S3/163 , H01S3/1681 , H01S3/1685 , H01S3/30
摘要：レーザー発振波長域が従来の色中心を利用したレーザー媒体より短波長の近紫外域から可視域におよぶ広帯域レーザー媒体であって、レーザーキャビティーおよび液体窒素冷却を必要とせず室温で動作可能な色中心レーザー媒体を提供する。本発明の色中心含有酸化マグネシウムは、一酸化珪素(SiO),三酸化ホウ素(B2O3),三酸化二鉄(Fe2O3)のいずれかと金属マグネシウムとの固相反応により生成される。そして、波長可変レーザー媒体は、かかる固相反応により生成される酸化マグネシウムの色中心(カラーセンター)を利用する。具体的には、一酸化珪素等と金属マグネシウムをアルゴン雰囲気下・所定温度で数時間加熱することにより、酸化マグネシウムの昇華物が得る。この昇華物に直接励起パルスレーザー光をレーザー発振閾値となる所定のエネルギー以上のポンプエネルギーで照射するとレーザー発振が生じる。

10. 发明专利

JPS598078B2 JPS598078B2 - 失效
公开(公告)号：JPS598078B2
公开(公告)日：1984-02-22
申请号：JP6276079
申请日：1979-05-23
申请人： Western Electric Co
发明人： DEIBITSUDO MAIKERU BURUUMU , RIN FUREDERITSUKU MORENOAA
IPC分类号： C09K11/00 , C09K11/08 , H01S3/00 , H01S3/094 , H01S3/16
CPC分类号： H01S3/1681

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