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1. 发明专利

FI934863A 未知
公开(公告)号：FI934863A
公开(公告)日：1994-05-04
申请号：FI934863
申请日：1993-11-03
申请人： BASF AG
发明人： HAEBERLE KARL , BAUER GERHARD , MAEMPEL LOTHAR
IPC分类号： C08F20/44 , C08F12/00 , C08F14/00 , C08F20/42 , C08F212/04 , C08F214/00 , C08F220/36 , C08F246/00 , C08G18/00 , C08G18/81 , C09D4/02 , C09D133/06 , C09D157/04 , C09J133/06 , C09J157/04 , C08F271/00 , C08F200/18 , C08F200/42 , C08F210/04 , C08F210/14 , C09D4/00 , C09J4/00
摘要： The invention relates to copolymers built up from a) from 0.01 to 40% by weight of a copolymerised, ethylenically unsaturated compound containing at least one oxime-blocked isocyanate group, b) from 30 to 99.99% by weight of at least one C1 to C20-alkyl (meth)acrylate, vinyl ester of carboxylic acids containing 1 to 20 carbon atoms, vinylaromatic compounds up to 20 carbon atoms, ethylenically unsaturated nitrile having 3 to 6 carbon atoms, vinyl halide or nonaromatic hydrocarbon having 4 to 8 carbon atoms and at least 2 conjugated double bonds, c) from 0 to 30% by weight of at least one comonomer containing at least one ketone or aldehyde group, and d) from 0 to 50% by weight of at least one further monomer.

2. 再颁专利

USRE38676E1 Thermally initiated polymerization of olefins using ruthenium or osmium vinylidene complexes 失效
标题翻译：使用钌或锇亚乙烯基配合物进行热引发烯烃的聚合
公开(公告)号：USRE38676E1
公开(公告)日：2004-12-21
申请号：US10224679
申请日：2002-08-21
申请人： Robert H. Grubbs , Thomas E. Wilhelm
发明人： Robert H. Grubbs , Thomas E. Wilhelm
IPC分类号： C08F200
CPC分类号： C08G61/08 , Y10S526/922
摘要： The present invention generally relates to the use of certain ruthenium and osmium complexes that are substantially inactive at a first temperature (preferably about room temperature) but becomes progressively more active at a higher second temperature. This difference in reactivities allows the reaction mixture to be formed and manipulated at the first temperature until polymerization is desired. When appropriate, the reaction mixture is heated to a suitable temperature (preferably greater than 50° C.) to activate the catalyst and to initiate polymerization. Because both the initiation and the rate of polymerization may be controlled with temperature, the inventive methods are especially suitable for ring opening metathesis polymerization (“ROMP”) reactions and for molding polymer articles that require extended pot-lives.

3. 发明授权

US06831138B2 Polymer-containing organo-metal catalysts 失效
标题翻译：含聚合物的有机金属催化剂
公开(公告)号：US06831138B2
公开(公告)日：2004-12-14
申请号：US10040530
申请日：2002-01-07
申请人： Yi-Feng Wang
发明人： Yi-Feng Wang
IPC分类号： C08F200
CPC分类号： C08G63/85 , B01J31/0212 , B01J31/06 , B01J31/122
摘要： The invention relates to polymer-containing catalysts (e.g., polymer-containing organo-metal catalysts) that may be useful in various applications (e.g., polymerization of macrocyclic oligoesters). Advantages of these catalysts include the improved ability to prepare, store, and handle the catalyst in open air; higher molar volume and molecular weight; and the ability to produce a blend of reactants and a catalyst (e.g., a macrocyclic oligoester and a polymerization catalyst) for subsequent one-step reaction (e.g., polymerization of macrocyclic oligoesters).
摘要翻译：本发明涉及可用于各种应用（例如大环低聚酯的聚合）的含聚合物的催化剂（例如，含聚合物的有机金属催化剂）。这些催化剂的优点包括提高在露天空气中制备，储存和处理催化剂的能力; 较高的摩尔体积和分子量; 以及产生用于后续一步反应（例如大环低聚酯的聚合）的反应物和催化剂（例如，大环低聚酯和聚合催化剂）的共混物的能力。

4. 发明授权

US06825290B2 Process for the preparation of latices using block copolymers as surfactants 有权
标题翻译：使用嵌段共聚物作为表面活性剂制备胶乳的方法
公开(公告)号：US06825290B2
公开(公告)日：2004-11-30
申请号：US10137944
申请日：2002-05-02
申请人： Hervé Adam , Wan-Li Liu
发明人： Hervé Adam , Wan-Li Liu
IPC分类号： C08F200
CPC分类号： C08F2/24 , C08F2/38 , C08F8/00 , C08F2800/20 , C08F2810/40 , Y10S526/922 , C08F293/005
摘要： A subject-matter of the present invention is a process for the preparation of a latex by radical aqueous emulsion polymerization in the presence of at least one ethylenically unsaturated monomer, of at least one radical polymerization initiator and of at least one surface-active block copolymer comprising at least one hydrophilic block and at least one hydrophobic block which is prepared by a “living” or “controlled” preparation process, the said copolymer exhibiting a number-average molecular mass of between 2 000 and 20 000, preferably between 4 000 and 16 000, a glass transition temperature of the hydrophobic block of less than 30° C., preferably of less than 25° C., and greater than −100° C., and a surface tension of less than 60 millinewtons per metre (mN/m), preferably of less than 50 mN/m, measured at a concentration in demineralized water of less than or equal to 10−4 mol/l at 20° C. and under one atmosphere, and the transfer agent having been rendered inert with respect to the said radical polymerization. The latices obtained can be used in particular in paints, adhesives and building materials.
摘要翻译：本发明的主题是在至少一种烯键式不饱和单体，至少一种自由基聚合引发剂和至少一种表面活性嵌段共聚物的存在下，通过自由基水乳液聚合制备胶乳的方法包括至少一个亲水性嵌段和至少一个通过“活性”或“受控”制备方法制备的疏水嵌段，所述共聚物的数均分子量在2000至20000之间，优选在4000和 16000，疏水嵌段的玻璃化转变温度小于30℃，优选小于25℃，大于-100℃，表面张力小于60毫牛顿/米（mN / m），优选小于50mN / m，在20℃和一个大气压下在软化水中的浓度小于或等于10 -4 mol / l测量，转移剂已经相对而言是惰性的到所述自由基聚合。所得的胶乳特别可用于油漆，粘合剂和建筑材料中。

5. 发明授权

US06800698B2 Continuous slurry polymerization volatile removal 有权
标题翻译：连续淤浆聚合挥发性去除
公开(公告)号：US06800698B2
公开(公告)日：2004-10-05
申请号：US10260011
申请日：2003-03-11
申请人： James Austin Kendrick , Thomas W. Towles , Scott Thomas Roger
发明人： James Austin Kendrick , Thomas W. Towles , Scott Thomas Roger
IPC分类号： C08F200
CPC分类号： B01D3/06 , B01J8/003 , B01J8/005 , B01J8/0055 , B01J8/007 , B01J8/20 , B01J8/382 , B01J19/0053 , B01J19/1837 , B01J2208/0007 , B01J2208/00539 , B01J2208/00761 , B01J2208/00769 , B01J2208/00867 , B01J2219/00006 , B01J2219/00033 , B01J2219/00103 , B01J2219/00114 , B01J2219/00162 , B01J2219/00164 , B01J2219/00191 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B01J2219/00236 , B01J2219/0024 , C08F2/00 , C08F6/003 , C08F10/00 , C08F210/16 , C08F2/14 , C08F210/14
摘要： A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of the first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the polymer solids which remain after removal of about 50 to 100% of the inert diluent therefrom to a second flash tank at a lower pressure.
摘要翻译：公开了一种用于从包含稀释剂，未反应单体和聚合物固体的聚合流出物连续分离包含稀释剂和未反应单体的液体介质的方法/装置，其包括通过排放阀将淤浆反应器的聚合流出物连续排出并将传输导管具有锥形底部的第一中间压力闪蒸罐，该锥形底部由基本上直的侧面倾斜的水平面倾斜，该水平面等于或大于浆料/聚合物固体的滑动角度以及直径（d）的出口密封室，长度（l）以在出口密封室中保持所需体积的浓缩聚合物固体/浆料，以形成压力密封，同时连续地将第一闪蒸罐的浓缩聚合物固体/浆料底部产物的塞流从出口密封室通过密封室出口减速器，斜面大致直线形成以等于或大于在较低压力下将约50至100％的惰性稀释剂从其中除去至第二闪蒸罐后残留的聚合物固体的滑动角度等于或大于水平的角度。

6. 发明授权

US06762253B2 Process for the preparation of ethylene copolymers, and their use as additives to mineral oil and mineral oil distillates 有权
标题翻译：制备乙烯共聚物的方法及其作为矿物油和矿物油馏出物添加剂的用途
公开(公告)号：US06762253B2
公开(公告)日：2004-07-13
申请号：US09956544
申请日：2001-09-18
申请人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Heinz Dieter Bühnen , Gerhard Bettermann
发明人： Matthias Krull , Werner Reimann , Wilhelm Zoller , Heinz Dieter Bühnen , Gerhard Bettermann
IPC分类号： C08F200
CPC分类号： B01J3/042 , B01J19/2415 , B01J2219/00168 , B01J2219/00184 , B01J2219/00186 , C08F210/02 , C08F210/16 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1641 , C10L1/195 , C10L1/1955 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1985 , C10L1/221 , C10L1/224 , C10L1/2364 , C08F2/00 , C08F218/08 , C08F218/10 , C08F210/14
摘要： The invention relates to a process for the preparation of terpolymers of ethylene and at least 2 further olefinically unsaturated compounds by polymerization in a tubular reactor fitted with at least one side branch, wherein the fresh monomer components, which are introduced into the tubular reactor via the reactor inlet (the primary stream) or via the side branch or side branches (secondary stream or secondary streams), in each of the streams contain ethylene and at most one further olefinically unsaturated compound.
摘要翻译：本发明涉及一种通过在装有至少一个侧枝的管式反应器中聚合制备乙烯和至少2种其它烯属不饱和化合物的三元共聚物的方法，其中新鲜单体组分通过反应器入口（主流）或经由侧分支或副分支（二级流或二级流）在每个流中含有乙烯和至多一种其它烯属不饱和化合物。

7. 发明授权

US06716935B1 Continuous process for the production of controlled architecture materials under high solids loading conditions 有权
标题翻译：在高固体负载条件下生产受控结构材料的连续工艺
公开(公告)号：US06716935B1
公开(公告)日：2004-04-06
申请号：US10324242
申请日：2002-12-19
申请人： James Michael Nelson , Ryan E. Marx , Michael John Annen , Duane Douglas Fansler , Maureen Ann Kavanagh , Babu Nana Gaddam
发明人： James Michael Nelson , Ryan E. Marx , Michael John Annen , Duane Douglas Fansler , Maureen Ann Kavanagh , Babu Nana Gaddam
IPC分类号： C08F200
CPC分类号： C08F2/02 , B01J19/0066 , B01J19/1812 , B01J2219/00081 , B01J2219/00094 , B01J2219/00166
摘要： The present invention discloses a continuous process for the production of polymerized controlled architectures materials under high solids loading conditions. The materials are made under stirred, plug-flow and temperature-controlled conditions.
摘要翻译：本发明公开了一种用于在高固体负载条件下生产聚合的受控结构材料的连续方法。材料在搅拌，插塞流和温度控制条件下制成。

8. 发明授权

US06713580B2 Quaternary amino acids on solid supports 失效
标题翻译：固体支持物上的第四元氨基酸
公开(公告)号：US06713580B2
公开(公告)日：2004-03-30
申请号：US10008953
申请日：2001-12-06
申请人： Michael Johnson , Keqiang Li , Elso DiFranco , Daljit S. Dhanoa
发明人： Michael Johnson , Keqiang Li , Elso DiFranco , Daljit S. Dhanoa
IPC分类号： C08F200
CPC分类号： C07D317/72 , C07B2200/11 , C07C271/22 , C07C2601/08 , C07C2601/14 , C07C2603/18 , C07D211/60 , C07D211/66 , C07D309/14 , C07D335/02
摘要： The present invention relates to novel templates useful for generating novel compounds and to compounds produced utilizing the templates. The templates comprise quaternary amino acids that may be linked to solid supports. These templates make possible the production of novel classes of chemical compounds through a plurality of chemical reactions. The templates are advantageous for use in drug discovery regimes.
摘要翻译：本发明涉及可用于产生新化合物的新模板和利用该模板生产的化合物。模板包括可以连接到固体支持物的季氨基酸。这些模板使得可以通过多个化学反应生产新类型的化合物。该模板有利于用于药物发现方案。

9. 发明授权

US06706826B1 Copolymer, process for producing the same, and resist composition 有权
标题翻译：共聚物，其制造方法和抗蚀剂组合物
公开(公告)号：US06706826B1
公开(公告)日：2004-03-16
申请号：US09646117
申请日：2000-09-27
申请人： Tadayuki Fujiwara , Masayuki Tooyama , Yukiya Wakisaka , Koji Nishida , Akira Yanagase
发明人： Tadayuki Fujiwara , Masayuki Tooyama , Yukiya Wakisaka , Koji Nishida , Akira Yanagase
IPC分类号： C08F200
CPC分类号： G03F7/039 , G03F7/0045
摘要： The present invention relates to a copolymer for use in paints, resists, and the like; a method for manufacturing the same; and a resist composition using the same. The copolymer according to the present invention is obtained by means of polymerizing at least one monomer containing an alicyclic structure and one monomer containing a lactone structure, and the distribution of the copolymer composition of said monomer containing a lactone structure in said copolymer is in the range of −10 to +10 mol % of the average copolymer composition of said monomer containing a lactone structure in said entire copolymer. In addition, the copolymer according to the present invention is obtained by means of polymerizing a monomer containing an alicyclic structure, a monomer containing a lactone structure, and another vinyl monomer comprising a higher polarity than said monomer containing an alicyclic structure, but a lower polarity than said monomer containing a lactone structure. The copolymer according to the present invention exhibits superior adhesion properties to surfaces possessing a high polarity, such as metal surfaces and the like, in addition to excellent hydrophobic and thermal resistance properties, and also displays a favorable solubility in solvents used for paints, resists, and the like.
摘要翻译：本发明涉及一种用于涂料，抗蚀剂等的共聚物; 其制造方法; 和使用其的抗蚀剂组合物。本发明的共聚物是通过聚合至少一种含有脂环结构的单体和含有内酯结构的单体而得到的，所述共聚物中含有内酯结构单体的共聚物组成的分布范围为在所述全部共聚物中含有内酯结构的所述单体的平均共聚物组成为-10〜+ 10mol％。此外，根据本发明的共聚物是通过使包含脂环结构的单体，含有内酯结构的单体和另外的含有比所述含有脂环结构的单体极性高的极性的乙烯基单体聚合而得到的，比所述含有内酯结构的单体。根据本发明的共聚物除了具有优异的疏水和耐热性能之外，还具有对具有高极性的表面，例如金属表面等的优异的粘合性，并且在用于涂料，抗蚀剂，等等。

10. 发明授权

US06703454B2 Adsorber system to replace water column in a polyester process 有权
标题翻译：吸附剂系统在聚酯工艺中替代水柱
公开(公告)号：US06703454B2
公开(公告)日：2004-03-09
申请号：US10013317
申请日：2001-12-07
申请人： Bruce Roger DeBruin
发明人： Bruce Roger DeBruin
IPC分类号： C08F200
CPC分类号： B01D19/0042 , B01F5/106 , B01J8/0035 , B01J19/1862 , B01J19/1881 , B01J19/2415 , B01J19/242 , B01J19/2425 , B01J19/243 , B01J19/2435 , B01J19/245 , B01J2219/00033 , B01J2219/00058 , B01J2219/00069 , B01J2219/00081 , B01J2219/00083 , B01J2219/00094 , B01J2219/00121 , B01J2219/0013 , B01J2219/00139 , B01J2219/00159 , B01J2219/00162 , B01J2219/00164 , B01J2219/00168 , B01J2219/00182 , C08G63/183 , C08G63/199 , C08G63/78 , C08G63/785 , Y02P20/582
摘要： The present invention provides a process for recovering a dihydroxy compound from a fluid stream that results from the preparation of a polyester by use of an adsorption system to selectively recover the dihydroxy compound.
摘要翻译：本发明提供从通过使用吸附系统选择性回收二羟基化合物制备聚酯的流体流中回收二羟基化合物的方法。

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