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    • 2. 发明专利
    • DE1940065A1
    • 1970-02-12
    • DE1940065
    • 1969-08-06
    • STANDARD OIL CO
    • ARTHUR BOLTON BENJAMIN
    • C08G73/14C08G51/24
    • 1,271,399. Polyamide acid solutions. STANDARD OIL CO. 30 July, 1969 [6 Aug., 1968], No. 38267/69. Heading C3R. The viscosity of a solution containing 15 to 50 wt. per cent of a polyamide-acid of trimellitic acid and an aromatic diamine in a solvent comprising an N-alkyl amide, a phenol or a sulphoxide-group-containing solvent is reduced by heating the solution at 70‹ to 150‹ C. in the presence of 1 to 10 wt. per cent of water. The solution may be obtained by preparing the polymer in a specified solvent or in a different solvent, e.g. a 165‹ to 235‹ C. semi-refined coal tar distillate, or by dissolving a solid polymer. The polymer may have been prepared from the acid chloride and treated with propylene oxide to scavenge HCl. The process is stated to improve the storage stability of wire enamel solutions and may be applied to an already aged enamel.
    • 9. 发明专利
    • FR2170266B1
    • 1976-11-05
    • FR7303956
    • 1973-02-05
    • STAMICARBON
    • C08L61/00C01B33/32C08G12/32C08K3/34C08L61/20C08G37/30C08G51/24
    • 1406771 Silicate-modified melamine-formaldehyde resins STAMICARBON BV 31 Jan 1973 [5 Feb 1972 28 July 1972] 4847/73 Heading C3R [Also in Division B5] A modified melamine-formaldehyde resin is prepared by reaction of melamine with formaldehyde in alkaline solution, a water soluble inorganic or quaternary ammonium silicate being incorporated before, during, or after the condensation, in amounts giving at most 1-5 wt. per cent SiO 2 in the product solution. When added before or during condensation, as pH adjuster, the silicate preferably provides up to 0À15 wt. per cent SiO 2 (from sodium silicate) or 0À1 wt. per cent (from tetraethanolammonium silicate). When added after the condensation the silicate preferably contains 10-20 wt. per cent SiO 2 and the resin solution is below pH 10; a stabilized silicate solution suitable for addition to the'resin solution contains 2-15 wt. per cent SiO 2 , acid to give a pH of 0À5-3, and 10-50 wt. per cent of a C 1-15 alcohol, a C 2-12 polyol or C 1-6 alkyl ether thereof, an N,N-di-(C 1-4 )alkyl C 1-4 carboxylic amide, a di-(C 1-4 ) alkyl sulphoxide or a C 4-7 lactam. In preparations 1-4 stable silicate solutions are prepared by adding 18% water glass (Na 2 O : SiO 2 1 : 3À3) to 25% aqueous toluenesulphonic acid, followed by triethylene glycol monoethyl ether, caprolactam, dimethyl formamide, or dimethylsulphoxide. In Examples I and II water glass is added both during and after the condensation of melamine with formaldehyde to give a pH of 9À7 and SiO 2 content of 0À08%; in Example III it is added during the condensation of melamine with formaldehyde and minor amounts of caprolactam, toluenesulphonamide and sugar; in Example IV the solution from Preparation 1 is added to a preformed MF resin solution followed by untreated water glass. The resin solutions are used to impregnate paper for laminating to chipboard.