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41. 发明授权

EP0113629B1 Process for the crystallization of high polymers in the presence of nucleant systems based on zeolites 失效
标题翻译：基于沸石的核系统存在下高聚物的结晶过程
公开(公告)号：EP0113629B1
公开(公告)日：1987-08-05
申请号：EP83402512.4
申请日：1983-12-22
申请人： Montedison S.p.A.
发明人： Zamboni, Valentino , Brichta, Corrado , Troglia, Claudio
IPC分类号： C08K9/04 , C08K3/34 , C08K5/09 , C08K5/42 , C08L23/02 , C08L67/02 , C08L77/00
CPC分类号： C08K5/42 , C08K3/34 , C08K5/0008 , C08K5/0083 , C08K5/098 , C08K9/04

42. 发明公开

EP0226225A2 Process for the preparation of (2,2)-paracyclophane and derivatives thereof 失效
标题翻译： Verfahren zur Herstellung von（2,2）-Paracyclophan und dessenAbkömmlinge。
公开(公告)号：EP0226225A2
公开(公告)日：1987-06-24
申请号：EP86117793.9
申请日：1986-12-19
申请人： Montedison S.p.A.
发明人： Ungarelli, Raffaele , Beretta, Maurizio Augusto , Malacrida, Allessandro , Sogli, Loris
IPC分类号： C07C13/70 , C07C1/32
CPC分类号： C07C1/323 , C07C17/263 , C07C2603/92 , C07C13/70 , C07C25/22
摘要： A process for the preparation of (2,2)-paracyclophane or derivatives thereof by Hofmann elimination of p.-methyl- benzyltrimethylammonium hydroxide or derivatives thereof, in an aqueous solution of an alkali metal hydroxide, wherein said elimination is carried out in the presence of a ketone of formula:
wherein R is hydrogen, a halogen or an alkyl-carboxylic group.
摘要翻译：在碱金属氢氧化物的水溶液中，通过霍夫曼消除对甲基苄基三甲基氢氧化铵或其衍生物制备（2,2） - 对环磷烷或其衍生物的方法，其中所述消除在酮：其中R是氢，卤素或烷基 - 羧基。

43. 发明公开

EP0222561A2 Process for enzymatic separation of optical isomers of 2-aminobutanol 失效
标题翻译： Verfahren zur enzymematischen Trennung von optisch aktiven Isomeren des 2-氨基丁醇。
公开(公告)号：EP0222561A2
公开(公告)日：1987-05-20
申请号：EP86308486.9
申请日：1986-10-30
申请人： Montedison S.p.A.
发明人： Francalanci, Franco , Cesti, Pietro , Foá, Marco , Martinengo, Tiziano
IPC分类号： C12P13/02 , C12P41/00
CPC分类号： C12P41/004 , C12P13/02
摘要： A process for the enzymatic separation of optical isomers (S + ) and (R ) of 2-aminobutanol comprises esterifying a N-carbamovl derivative of formula:
wherein R is a C 1 -C 3 alkyl group or a benzyl group, with an ester of formula:
wherein R, R, which may be the same or different, are C 1 -C 6 alkyl groups, at a temperature from 0 to 60°C, in the presence of a lipase capable of giving rise to the esterification, in a stereoselective way, on optical isomer (R') of the N-carbamoyl derivative, and separating and hydrolyzing, by means of known methods, the obtained products (non-reacted (S) N-carbamoyl derivative, and the formed ester) to give rise to (S + ) 2-aminobutanol and (R ) 2-aminobutanol respectively.
摘要翻译：用于酶分离2-氨基丁醇的光学异构体（S +）和（R）的方法包括酯化下式的N-氨基甲酰基衍生物：其中R是C1-C3烷基或苄基，与下式的酯：其中R，R min可以相同或不同，为C 1 -C 6烷基，在0至60℃的温度下，在能够引起的脂肪酶存在下以立体选择性方式对N-氨基甲酰基衍生物的旋光异构体（R min）进行酯化，并通过已知方法分离和水解得到的产物（未反应的（S）N-氨基甲酰基衍生物，形成酯），分别产生（S）2-氨基丁醇和（R）2-氨基丁醇。

44. 发明授权

EP0086472B1 Catalyst for the polymerization of olefins 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：EP0086472B1
公开(公告)日：1987-05-20
申请号：EP83101331.3
申请日：1983-02-11
申请人： Montedison S.p.A.
发明人： Albizzati, Enrico , Parodi, Sandro , Barbe, Pier Camillo
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , C08F4/6495 , C08F4/6543 , C08F4/646 , C08F4/6425 , C08F4/6565

45. 发明授权

EP0122804B1 Process for preparing carboxylic acids from olefins or vicinal dihydroxy compounds 失效
标题翻译：从烯烃或维生素二羟基化合物制备羧酸的方法
公开(公告)号：EP0122804B1
公开(公告)日：1986-12-10
申请号：EP84302586.7
申请日：1984-04-16
申请人： Montedison S.p.A.
发明人： Venturello, Carlo , Ricci, Marco
IPC分类号： C07C51/285 , C07C53/126 , C07C55/14 , C07C63/06
CPC分类号： C07C51/285 , C07C63/06 , C07C55/14 , C07C53/126

46. 发明授权

EP0075871B1 A composition based on a fluorohydrocarbon solvent, suitable for removing water from the surface of manufactured articles 失效
标题翻译：基于氟氢溶剂的组合物，适用于从制造商品表面除去水分
公开(公告)号：EP0075871B1
公开(公告)日：1986-12-10
申请号：EP82108809.3
申请日：1982-09-23
申请人： Montedison S.p.A.
发明人： Bargigia, Gianangelo , Carniselli, Giuliano
IPC分类号： C11D3/43 , C11D3/30 , C11D3/36
CPC分类号： C11D3/43 , C11D3/30 , C23G5/02809

47. 发明授权

EP0105664B1 Process for the preparation of 3-carboxy-1-methylpyrrol-2-acetic-acid and alkali metal salts thereof 失效
标题翻译：制备3-羧基-1-甲基吡咯-2-酮酸及其碱金属盐的方法
公开(公告)号：EP0105664B1
公开(公告)日：1986-11-20
申请号：EP83305548.6
申请日：1983-09-21
申请人： Montedison S.p.A.
发明人： Bottaccio, Giorgio , Campolmi, Stefano , Carletti, Vittorio , Marchi, Marcello
IPC分类号： C07D207/34
CPC分类号： C07D207/34

48. 发明公开

EP0145377A3 Process for preparing 3,4'-Amino-Nitro-Diphenylether 失效
标题翻译：制备3,4'-氨基 - 二硝基苯的方法
公开(公告)号：EP0145377A3
公开(公告)日：1986-10-29
申请号：EP84308090
申请日：1984-11-21
申请人： Montedison S.p.A.
发明人： Beretta, Maurizio Augusto , Bausani, Giovanni , Bottaccio, Giorgio , Campolmi, Stefano , Montanari, Fernando
IPC分类号： C07C93/14
CPC分类号： C07C213/06 , C07C217/90
摘要： A process for preparing 3,4'-amino-nitro-diphenylether in a heterogenous phase, according to the phase-transfer catalysis method, in which para-chloro-nitrobenzene is reacted with an alkali metal or alkaline-earth metal salt, preferably sodium or potassium, of meta-amino-phenol, preferably at a temperature ranging from 50°C to 120°C, in the presence of a phase-transfer catalyst, preferably (1) an onium salt, more preferably a quaternary alkylammonium salt (QR 4 R wherein 0 is selected from N, P, As, Sb etc., R is an alkyl radical containing up to 20 carbon atoms and Y is Cl, Br, or i, or (2) a crown ether, in a two-phase system consisting of (a) an organic phase represented by the para-chloro-nitrobenzene, optionally in an organic solution, and (b) by the meta-amino-phenol in the form of an alkali metal or alkaline-earth metal salt in an aqueous solution which is substantially immiscible with the first phase. In this way, 3,4'-amino-nitro-diphenylether is obtained, which is a particularly useful intermediate for preparing fibres.

49. 发明公开

EP0195717A2 Process for the biotechnological preparation of optically active alpha-arylalkanoic acids 失效
标题翻译： Verfahren zur生物技术Herstellung von optisch aktiven alpha-Arylalkansäuren。
公开(公告)号：EP0195717A2
公开(公告)日：1986-09-24
申请号：EP86400558.2
申请日：1986-03-17
申请人： Montedison S.p.A.
发明人： Cesti, Pietro , Piccardi, Paolo
IPC分类号： C12P7/40 , C12P17/14 , C12P41/00
CPC分类号： C12P41/005 , C12P7/40 , C12P17/10 , Y10S435/921
摘要： The present invention concerns the preparation of S(+) α-aryl-alkanoic acids through reacting a racemic ester (R,S) of the formula:
wherein:

R represents a -C≡CH, - CH=CH 2 , -CN, -COCH 3 , -COO alk or -CH 2 -O-alk group where the alkyl group contains 1 to 4 carbon atoms;
Ar represents an aryl or an aryl substituted or condensed with other groups, in particular a group of the formula:
or
wherein:
R' is a C 1 -C 8 alkyl; a C 1 -C 4 alkenyl, an alcoxy; a phenyl, a phenoxy, a tenoyl, a heterocycle.
R" is hydrogen or halogen;
R"' is a C 1 -C 4 alkyl,
with an esterase, produced by microorganisms capable of selectively hydrolysing the S(+) form of said racemic ester and successively separating the S(+) acid from the unreacted ester.
摘要翻译：本发明涉及通过使下式的外消旋酯（R，S）反应来制备S（+） - 芳基 - 链烷酸：其中：... R代表-CIDENTICAL CH，-CH = CH 2，-CN，-COCH 3，-COO烷基或CH 2 -O-烷基，其中烷基含有1至4个碳原子; Ar表示与其它基团取代或缩合的芳基或芳基，特别是式：... ...其中：... R min是C 1 -C 8烷基; C 1 -C 4烯基，烷氧基; 苯基，苯氧基，十甲酰基，杂环，R sec是氢或卤素; R“'是具有酯酶的C1-C4烷基，由能够选择性水解S（+）形式的微生物产生的所述外消旋酯，并连续地将S（+）酸与未反应的酯分离。

50. 发明公开

EP0194152A1 Soldering electronic components on a support 失效
标题翻译：在基板上的电子部件的软钎焊。
公开(公告)号：EP0194152A1
公开(公告)日：1986-09-10
申请号：EP86301611.9
申请日：1986-03-06
申请人： Montedison S.p.A.
发明人： Johns, Ken , Briggs, Stuart , Flabbi, Luciano
IPC分类号： H05K3/34
CPC分类号： B23K35/3616 , H05K3/3489
摘要： Electronic components are arranged on the surface of a support and/or in holes piercing the support, in the presence of soldering material with binding properties. The thus obtained assembly is then put in contact with a perfluoropolyether in the liquid state, the perfluoropolyether having a temperature at least equal to that at which the soldering material develops its binding properties.

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