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    • 6. 发明公开
    • Near IR sensitive photoimageable/photopolymerizable compositions, media, and associated processes
    • Nahinfrarot-empfindliche abbildbare / photopolymerisierbare Zusammensetzungen,Media und versund Verfahren
    • EP0889363A1
    • 1999-01-07
    • EP98100692.7
    • 1998-01-16
    • E.I. DU PONT DE NEMOURS AND COMPANY
    • Weed, Gregory CharlesFabricius, Dietrich Max
    • G03F7/031G03C1/73B41M5/36
    • G03F7/031B41C1/1008B41C2210/04B41C2210/06B41C2210/22B41C2210/24B41M5/368G03C1/732G03C5/164G03C2200/37G03F3/10H05K3/0082H05K3/3452
    • Novel photopolymer compositions are disclosed which contain dyes that absorb strongly in the near infrared (near IR) region of the electromagnetic spectrum. These dyes are useful as photosensitizers for initiating a variety of photoimaging and photopolymerization reactions. Imaging Media are disclosed herein which are sensitive in the near infrared (near IR) region of the electromagnetic spectrum and which can initiate polymerization of ethylenically unsaturated monomer components in negative-acting photopolymer systems and/or which can initiate conversion of a leuco dye to its corresponding colored dye form. These imaging media comprise either a near IR dye photochemical sensitizer, a hexaarylbiimidazole (HABI) photoinitiator, a chain transfer agent, and a photopolymerizable material or a near IR dye photochemical sensitizer, a hexaarylbiimidazole (HABI) photoinitiator, and a leuco dye. These imaging media are useful in a variety of photopolymer products, including photoresists, proofing films, and holographic recording films.
    • 公开了新的光聚合物组合物,其包含在电磁光谱的近红外(近IR)区域强烈吸收的染料。 这些染料可用作光敏剂,用于引发各种光成像和光聚合反应。 本文公开了在电磁光谱的近红外(近IR)区域中敏感的成像介质,并且其可以引发负性光聚合物体系中的烯属不饱和单体组分的聚合和/或可以引发无色染料转化为其 相应的着色染料形式。 这些成像介质包括近IR染料光化学敏化剂,六芳基联咪唑(HABI)光引发剂,链转移剂和可光聚合材料或近IR染料光化学敏化剂,六芳基联咪唑(HABI)光引发剂和无色染料。 这些成像介质可用于各种光聚合物产品,包括光致抗蚀剂,防粘膜和全息记录膜。