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    • 92. 发明授权
    • Microemulsion polymer blends
    • 微乳液聚合物共混物
    • US5238992A
    • 1993-08-24
    • US935645
    • 1992-08-26
    • Syed Outubuddin
    • Syed Outubuddin
    • B01D67/00C08F2/16C08F246/00
    • B01D67/0006C08F2/16C08F246/00B01D2323/18B01D2325/02
    • A process for preparing solid polymer blends and composites of controlled porosity in microemulsions containing both hydrophilic and hydrophobic phases. The microemulsions are prepared with surfactant systems that may include a cosolvent as a part thereof, together with a hydrophilic monomer, or monomers, dissolved in the hydrophilic phase of the microemulsion, and a hydrophobic monomer, or monomers, dissolved in the hydrophobic phase. Polymerization of the monomers thus present is carried out to provide highly uniform dispersions of the resulting polymers in each other. The invention allows for the control of the morphology of the blends, the improvement in compatability of otherwise incompatible polymers, and improvements in the processability of the polymers due to enhanced thermal and mechanical properties.
    • 一种在含有亲水和疏水相的微乳液中制备固体聚合物共混物和受控孔隙率的复合材料的方法。 微乳液用可以包括共溶剂作为其一部分的表面活性剂体系与溶解在微乳液的亲水相中的亲水单体或单体以及溶解在疏水相中的疏水性单体或单体一起制备。 进行如此存在的单体的聚合以提供所得聚合物彼此高度均匀的分散体。 本发明允许控制共混物的形态,改善其它不相容的聚合物的相容性,以及由于增加的热和机械性能而提高聚合物的加工性能。
    • 100. 发明授权
    • Preparation of aqueous polymer dispersions
    • 聚合物水分散体的制备
    • US4904724A
    • 1990-02-27
    • US285667
    • 1988-12-16
    • Gerhard AuchterGerhard Neubert
    • Gerhard AuchterGerhard Neubert
    • C08F2/20C08F2/16C08F2/18C08F2/22C08F285/00
    • C08F285/00
    • Aqueous polymer dispersions are prepared by free radical polymerization of(a) from 50 to 100%, based on the total weight of the monomers, of C.sub.1 -C.sub.20 -alkyl (meth)acrylates,(b) from 0 to 20%, based on the total weight of the monomers, of polyolefinically unsaturated monomers and(c) from 0 to 30%, based on the total weight of the monomers, of further monoolefinically unsaturated monomersin aqueous emulsion in the presence of a preformed solution copolymer (A) dispersed in water and obtained from(I) 1.5-15%, based on its weight, of monomers of 3 to 10 carbon atoms which contain a carboxyl or carboxylic anhydride group,(II) 30-98.5%, based on its weight, of C.sub.1 -C.sub.20 -alkyl acrylates or methacrylates,(III) 0-60%, based on its weight, of vinylaromatics,(IV) 0-20%, based on its weight, of monoolefinically unsaturated carbonyl compounds and(V) 0-20%, based on its weight, of further monomers not stated under (I) to (IV)and a solution copolymer (B) obtained from 40-100%, based on its weight, of monomers (II) and 0-60%, based on its weight, of monomers (III) to (V).
    • 聚合物水分散体是通过(a)基于单体总重量为50-100%的(甲基)丙烯酸C 1 -C 20烷基酯,(b)0至20%,基于 单体的总重量,聚烯烃不饱和单体的总重量,和(c)基于单体的总重量,0-30%的预聚物溶液共聚物(A)分散在水乳液中的另外的单烯属不饱和单体 在水中,从(I)的1.5重量%得到含有羧基或羧酸酐基团的3〜10个碳原子的单体,(II)30〜98.5%(重量)为C1〜 -C 20 - 丙烯酸烷基酯或甲基丙烯酸烷基酯,(III)基于其重量的0-60%的乙烯基芳族化合物,(IV)基于其重量的0-20%的单烯属不饱和羰基化合物和(V)0-20% (I)至(IV)中未提及的其它单体和基于其重量的40-100%获得的溶液共聚物(B),基于其重量, ,单体(II)和0-60%(基于其重量)单体(III)至(V)。