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    • 98. 发明授权
    • Method and arrangement for producing an N-semiconductive indium sulfide thin layer
    • 用于生产N-半导体硫化铟薄层的方法和装置
    • US08143145B2
    • 2012-03-27
    • US12934329
    • 2009-03-14
    • Nicholas AllsopChristian-Herbert FischerSophie GledhillMartha Christina Lux-Steiner
    • Nicholas AllsopChristian-Herbert FischerSophie GledhillMartha Christina Lux-Steiner
    • H01L21/36H01L21/20H01L21/76H01L21/469
    • C23C16/305C23C16/45527
    • A method of producing, at atmospheric pressure, an n-type semiconductive indium sulfide thin film on a substrate using an indium-containing precursor, hydrogen sulfide as a reactive gaseous precursor, and an inert carrier gas stream includes cyclically repeating first and second steps so as to produce an indium sulfide thin film of a desired thickness. The first method phase includes converting the indium-containing precursor to at least one of a dissolved and a gaseous phase, heating the substrate to a temperature in a range of 100° C. to 275° C., directing the indium containing precursor onto the substrate and supplying hydrogen sulfide to the indium-containing precursor in a mixing zone in an amount so as to provide an absolute concentration of hydrogen sulfide that is greater than zero and no greater than 1% by volume. The indium concentration of the indium-containing precursor is set so as to produce a compact In(OHx,Xy,Sz)3 film, where X=halide and x+y+2z=1 with z≠0. The second step includes setting a temperature of the substrate in a range of 18° C. and 450° C. and directing hydrogen sulfide onto the substrate in an absolute concentration up to 100%.
    • 在大气压下使用含铟前体,硫化氢作为反应性气态前体和惰性载气流在基板上制造n型半导体硫化铟薄膜的方法包括循环重复第一和第二步骤 以产生所需厚度的硫化铟薄膜。 第一种方法阶段包括将含铟前体转化为溶解气相和气相中的至少一种,将基底加热至100℃至275℃的温度,将含铟前体引导到 底物并在混合区中向含铟前体提供硫化氢,其量使得硫化氢的绝对浓度大于零且不大于1体积%。 设定含铟前体的铟浓度,以便产生紧密的In(OH x,Xy,Sz)3膜,其中X =卤化物,x + y + 2z = 1,z≠0。 第二步包括将基板的温度设定在18℃和450℃的范围内,并以绝对浓度高达100%的方式将硫化氢引导到基板上。