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11. 发明授权

US07446154B2 Carboxylic acid-modified biphenyl epoxy diacrylate 有权
公开(公告)号：US07446154B2
公开(公告)日：2008-11-04
申请号：US12068925
申请日：2008-02-13
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
IPC分类号： C08G65/44 , C08G65/48 , C08L71/12
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), HO—YaO—X—OY—ObH (1) HO—X—OH (2) Y—OH (3) wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.

12. 发明申请

US20080032154A1 Epoxy Resin, Epoxy Resin Composition and Cured Product Thereof 审中-公开
标题翻译：环氧树脂，环氧树脂组合物及其固化产品
公开(公告)号：US20080032154A1
公开(公告)日：2008-02-07
申请号：US11630813
申请日：2005-07-08
申请人： Yasumasa Akatsuka , Katsuhiko Oshimi , Masataka Nakanishi
发明人： Yasumasa Akatsuka , Katsuhiko Oshimi , Masataka Nakanishi
IPC分类号： C08G65/38 , B05D3/00 , B32B15/092 , B32B25/08
CPC分类号： C08G59/621 , C08G59/063 , C08G59/5033 , C08G59/688 , C08J5/24 , C08J7/047 , C08J2363/02 , C08J2367/02 , C08J2379/08 , C08J2463/00 , C09D163/00 , Y10T428/12569 , Y10T428/31511 , C08L2666/04
摘要： An epoxy resin represented by formula (1) below: wherein the ratio of the component having two nuclei accounting for 25% or less in terms of the area corresponding to the component in a gel permeation chromatogram.
摘要翻译：由下式（1）表示的环氧树脂：其中具有两个核的组分的比例占凝胶渗透色谱图中对应于组分的面积的25％或更小。

13. 发明申请

US20050069715A1 Epoxy compound, preparation method thereof, and use thereof 有权
标题翻译：环氧化合物及其制备方法及其用途
公开(公告)号：US20050069715A1
公开(公告)日：2005-03-31
申请号：US10927617
申请日：2004-08-27
申请人： Atsuhito Hayakawa , Akihiro Itou
发明人： Atsuhito Hayakawa , Akihiro Itou
IPC分类号： C07D407/12 , C07D303/24 , C08G59/06 , C08G59/24 , C08L63/00 , H01L23/29 , B32B27/38 , H01L21/56
CPC分类号： C07D303/24 , C08G59/063 , C08G59/245 , C08L63/00 , H01L23/293 , H01L2924/0002 , Y10T428/31511 , C08L2666/16 , H01L2924/00
摘要： The present invention relates to an epoxy compound, represented by a general formula (I), which is solid at ordinary temperature, has extremely low melt viscosity and has excellent curing property and which can provide a cured product which is excellent in mechanical strength, heat resistance, and moisture resistance. It also relates to a preparation method of the epoxy compound, an epoxy resin composition, and a cured product thereof. The epoxy compound is represented by the following general formula (I): (wherein R1-R10 each represent hydrogen atom or alkyl group having 1-6 carbon atoms, and n represents an integer of 0 or more).
摘要翻译：本发明涉及由通式（I）表示的环氧化合物，其在常温下为固体，熔体粘度极低，固化性优异，可提供机械强度，热性优异的固化物电阻和耐湿性。它还涉及环氧化合物的制备方法，环氧树脂组合物及其固化产物。环氧化合物由以下通式（I）表示：（其中R 1 -R 10各自表示氢原子或具有1-6个碳原子的烷基，n表示0以上的整数）。

14. 发明申请

US20040214004A1 Bifunctional phenylene ether oligomer, its derivatives, its use and process for the production thereof 有权
标题翻译：双官能亚苯基醚低聚物，其衍生物，其用途及其制备方法
公开(公告)号：US20040214004A1
公开(公告)日：2004-10-28
申请号：US10851290
申请日：2004-05-24
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
IPC分类号： B32B027/38
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), 1 (wherein nullXnull is represented by the formula (2null), 2 and YnullOnull is represented by the formula (3), 3 R2, R3, R4, R8, R9, R10 and R11 in the formula (2null) and the formula (3null) being required not to be a hydrogen atom, and its use.
摘要翻译：通过式（2）的二价苯酚和式（3）的一价苯酚的氧化聚合获得的式（1）的双官能亚苯基醚低聚物（其中-X-由式（2'）表示，），YO-由式（3）表示，式（2'）和式（3'）中的R 2，R 3，R 4，R 8，R 9，R 10和R 11不需要为氢原子，及其用途。

15. 发明授权

US06784228B2 Epoxy resin composition, cured article thereof, novel epoxy resin, novel phenol compound, and process for preparing the same 失效
标题翻译：环氧树脂组合物，其固化物，新型环氧树脂，新型酚化合物及其制备方法
公开(公告)号：US06784228B2
公开(公告)日：2004-08-31
申请号：US10190491
申请日：2002-07-09
申请人： Ichiro Ogura , Yoshiyuki Takahashi , Tomoyuki Imada
发明人： Ichiro Ogura , Yoshiyuki Takahashi , Tomoyuki Imada
IPC分类号： C08K336
CPC分类号： C07D407/14 , C07D311/78 , C07D311/82 , C08G59/063 , C08G59/245
摘要： The present invention relates to an epoxy resin composition a cure article thereof, a novel epoxy resin used therein, a polyhydric phenol compound suited for used as an intermediate thereof, and a process for preparing the same. One of the objects to be achieved by the present invention is to exert the heat resistance, the moisture resistance, the dielectric performances and the flame-resistant effect required of electric or electronic materials such as semiconductor encapsulating materials and varnishes for circuit boards in the epoxy resin composition.
摘要翻译：环氧树脂组合物及其制备方法技术领域本发明涉及环氧树脂组合物及其固化物，其中使用的新型环氧树脂，适合用作其中间体的多元酚化合物及其制备方法。本发明要实现的目的之一是发挥电子或电子材料如半导体封装材料和环氧树脂电路板清漆所需要的耐热性，耐湿性，介电性能和阻燃效果树脂组合物。

16. 发明授权

US06730402B2 Flame-retardant epoxy resin composition and laminate made with the same 失效
标题翻译：阻燃环氧树脂组合物和由其制成的层压材料
公开(公告)号：US06730402B2
公开(公告)日：2004-05-04
申请号：US10070827
申请日：2002-03-11
申请人： Yukihiro Kiuchi , Masatoshi Iji
发明人： Yukihiro Kiuchi , Masatoshi Iji
IPC分类号： B32B2738
CPC分类号： C08L63/00 , C08G59/063 , C08G59/621 , C08K3/22 , Y10T428/31511 , Y10T428/31515 , Y10T428/31663 , C08L61/04 , C08L2666/16
摘要： A flame-retardant epoxy resin composition includes an epoxy resin, a curing agent, and a metal hydroxide, wherein the curing agent as a phenolic resin (C) containing, in the molecular chain, structural units derived from a phenol (A) and structural units derived from an aromatic compound (B) other than the phenol (A), or the epoxy resin is a novolac epoxy resin CD) obtained by subjecting the phenolic hydroxyl groups of the phenolic resin (C) to etherification with glycidyl. The composition has a high degree of flame retardancy.
摘要翻译：阻燃性环氧树脂组合物包括环氧树脂，固化剂和金属氢氧化物，其中作为酚醛树脂（C）的固化剂在分子链中含有衍生自苯酚（A）的结构单元和结构式衍生自苯酚（A）以外的芳香族化合物（B）的单元，或环氧树脂是酚醛树脂（C）的酚性羟基与缩水甘油醚化而得到的酚醛清漆型环氧树脂CD。该组合物具有高度的阻燃性。

17. 发明申请

US20030065109A1 Epoxy resins, epoxy resin mixtures, epoxy resin compositions and products of curing of the same 失效
标题翻译：环氧树脂，环氧树脂混合物，环氧树脂组合物及其固化产物
公开(公告)号：US20030065109A1
公开(公告)日：2003-04-03
申请号：US10149164
申请日：2002-07-25
发明人： Yasumasa Akatsuka , Koji Nakayama , Katsuhiko Oshimi , Syouichi Tomida
IPC分类号： C08G059/14
CPC分类号： C08G59/063 , C07D301/26
摘要： The object of the present invention is to provide an epoxy resin and epoxy resin composition having a low viscosity which can afford a cured product having an excellent heat resistance. The present invention is characterized by using an epoxy resin which is obtained by reacting 5-methylresorcin with epihalohydrin in the presence of alkali metal hydroxide.
摘要翻译：本发明的目的是提供一种具有低粘度的环氧树脂和环氧树脂组合物，其可以提供具有优异耐热性的固化产物。本发明的特征在于使用在碱金属氢氧化物存在下使5-甲基间苯二酚与表卤代醇反应获得的环氧树脂。

18. 发明申请

US20030036623A1 Lightfast epoxy resin 失效
标题翻译：耐光环氧树脂
公开(公告)号：US20030036623A1
公开(公告)日：2003-02-20
申请号：US10218817
申请日：2002-08-14
发明人： Ellis Breskman
IPC分类号： C08G059/40
CPC分类号： C08G59/063 , C08G59/06
摘要： A lightfast epoxy resin is formed by phosgenating Bisphenol A by reaction with phosgene to produce Bisphenol A bischloroformate. The Bisphenol A bischloroformate is then reacted with either epichlorohydrin, glycidol or pinacol and another chemical to produce a lightfast epoxy resin. By phosgenating the Bisphenol A prior to the reaction with either epichlorohydrin, glycidol or pinacol and another chemical, the resulting epoxy resin has improved lightfastness and is not degraded by sunlight. The epoxy resin of the present invention can be used in paints, coatings, and plastics for vehicles.
摘要翻译：通过与光气反应来对双酚A进行光气化以形成双酚A双氯甲酸酯形成耐光环氧树脂。然后将双酚A双氯甲酸酯与表氯醇，缩水甘油或频哪醇和另一种化学品反应以产生耐光环氧树脂。通过在与表氯醇，缩水甘油或频哪醇和另一种化学品反应之前使双酚A光气化，得到的环氧树脂具有改善的耐光性，并且不被阳光降解。本发明的环氧树脂可用于车辆的涂料，涂料和塑料。

19. 发明授权

US5792814A Method for preparing modified resins and their applications 失效
公开(公告)号：US5792814A
公开(公告)日：1998-08-11
申请号：US906316
申请日：1997-08-05
申请人： Tetsuya Oishi , Kazuo Sugazaki , Jin Suzuki
发明人： Tetsuya Oishi , Kazuo Sugazaki , Jin Suzuki
IPC分类号： C08F8/00 , C08F8/08 , C08F8/28 , C08F8/30 , C08G12/00 , C08G59/06 , C08G61/00 , C08G63/91 , C08G65/48 , C08G69/48 , C08K5/00 , C08L23/26 , C08L63/00 , C08L67/02 , C08L71/12 , H05K3/34
CPC分类号： C08L71/126 , C08F8/00 , C08F8/08 , C08F8/28 , C08F8/30 , C08F8/40 , C08G12/00 , C08G59/063 , C08G61/00 , C08G63/914 , C08G65/485 , C08G69/48 , C08K5/0066 , C08L23/26 , C08L63/00 , C08L67/02 , B23K2201/42 , H05K2201/10734 , H05K2203/081 , H05K2203/087 , H05K2203/1105 , H05K2203/176 , H05K3/3436 , H05K3/3494
摘要： There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin. According to the preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins. By the utilization of these techniques, there can be obtained a flame-retardant material having a good char formability, a thermally stable material whose molded articles can inhibit heat deterioration, a material excellent in miscibility between different kinds of resins, a surface-modified material which is excellent in adhesion and coating properties and the like.

20. 发明授权

US5654382A Epoxy resin high in ortho bisphenol F 失效
标题翻译：邻苯二酚F高环氧树脂
公开(公告)号：US5654382A
公开(公告)日：1997-08-05
申请号：US497494
申请日：1995-06-30
申请人： Robert A. Dubois , Hideyuki Ohnishi , Allyson J. Malzman
发明人： Robert A. Dubois , Hideyuki Ohnishi , Allyson J. Malzman
IPC分类号： C07D303/08 , C07D303/24 , C08G59/06 , C08G59/24 , C08G59/00 , C08G65/08 , C08G65/14
CPC分类号： C08G59/066 , C07D303/24 , C08G59/063 , C08G59/245
摘要： An epoxy resin prepared from a component comprising a bisphenol F having high ortho isomer content is claimed. Ortho isomer content is defined as follows:(A+2B)/2A: content of ortho-para isomer of a bisphenol FO: content of ortho-ortho isomer of a bisphenol FThe epoxy resin of the present invention has lower viscosity (e.g. melt viscosity, solution viscosity) and good physical properties (e.g. flexibility), and suitable for various applications such as coating materials, electrical laminates, adhesives, molding products, encapsulation materials, etc.
摘要翻译：要求保护由含有高正构异构体含量的双酚F的组分制备的环氧树脂。正交异构体含量定义如下：（A + 2B）/ 2A：双酚F的邻位对位异构体的含量：双酚F的邻位异构体的含量本发明的环氧树脂具有较低的粘度（例如熔融粘度，溶液粘度）和良好的物理性能（例如柔性），适用于各种应用，如涂料，电层压板，粘合剂，成型产品，包封材料等。

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