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    • 10. 再颁专利
    • Adhesive compositions and copper foils and copper clad laminates using same
    • 粘合剂组合物和使用其的铜箔和铜包层压板
    • USRE39615E1
    • 2007-05-08
    • US10617653
    • 2002-10-17
    • Charles A. Poutasse
    • Charles A. Poutasse
    • B23B3/00
    • H05K3/386C08G59/02C08G59/06C08G59/40C08L61/04C09J163/00H05K3/022H05K3/384H05K3/385H05K3/389H05K2201/0239H05K2201/0355H05K2201/0358H05K2203/0315H05K2203/0723Y10S428/901Y10T428/24917Y10T428/30Y10T428/31511Y10T428/31525Y10T428/31529Y10T428/31678
    • The invention relates to an adhesive composition, comprising: (A) at least one phenolic resole resin; and (B) the product made by reacting (B-1) at least one difunctional epoxy resin, with (B-2) at least one compound represented by the formula wherein in Formulae (I) and (II): G, T and Q are each independently functional groups selected from the group consisting of COOH, OH, SH, NH2, NHR1, (NHC(═NH))mNH2, R2COOH, NR12, C(O)NHR1, R2NR12, R2OH, R2SH, R2NH2 and R2NHR1, wherein R1 is a hydrocarbon group, R2 is an alkylene or alkylidene group and m is a number in the range of 1 to about 4; T can also be R1, OR1 or SO2C6H4—NH2; and Q can also be H. The invention also relates to copper foils having the foregoing adhesive composition adhered to at least one side thereof to enhance the adhesion between said foils and dielectric substrates. The invention also relates to laminates comprising copper foil, a dielectric substrate, and an adhesion-promoting layer comprising the foregoing adhesive composition disposed between and adhered to the foil and the substrate.
    • 本发明涉及粘合剂组合物,其包含:(A)至少一种酚醛树脂树脂; 和(B)通过使(B-1)至少一种双官能环氧树脂与(B-2)至少一种由下式表示的化合物反应制备的产物:其中在式(I)和(II)中:G,T和 Q独立地为选自COOH,OH,SH,NH 2,NHR 1,(NHC(-NH))m的官能团。 NH 2,NR 2 COOH,NR 1,SO 2,C(O)NHR 2, 1,R 2,R 2,R 2,R 2,OH,R 2, 其中R 1,R 2,R 2,R 2,R 2, / SUP>是烃基,R 2是亚烷基或亚烷基,m是1至约4的数; T也可以是R 1,或者1或2或更高的C 1 H 4 > -NH 2 2; 并且Q也可以是H.本发明还涉及具有粘附到其至少一个侧面的上述粘合剂组合物的铜箔,以增强所述箔和电介质基底之间的粘附。 本发明还涉及包含铜箔,电介质基底和包含上述粘合剂组合物的粘合促进层的层压体,所述粘合剂组合物设置在箔和衬底之间并粘附到箔和衬底上。