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    • 15. 发明授权
    • Process for forming an aramid copolymer
    • 形成芳族聚酰胺共聚物的方法
    • US09102788B2
    • 2015-08-11
    • US14548499
    • 2014-11-20
    • E I DU PONT DE NEMOURS AND COMPANY
    • Frederick K Mallon
    • C08G73/00C08G69/00C08G69/26C08G69/28C08G69/32C08G73/18
    • C08G69/00C08G69/265C08G69/28C08G69/32C08G73/18
    • The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and wherein the sum of y+b is 100 and the product of b×c is 225 or greater.
    • 本发明涉及形成包含2-(4-氨基苯基)-5(6)氨基苯并咪唑(DAPBI),对苯二胺(PPD)和对苯二甲酰氯(TCl))残留物的聚合物碎屑的方法,包括以下步骤:i) 在包含有机溶剂和c重量百分数的无机盐的溶剂体系中形成b摩尔%DAPBI的浆料,其中无机盐以至少5重量%存在的有机溶剂的量存在; ii)使所述浆料与少于化学计量的对苯二甲酰氯接触以形成预聚物溶液; 和iii)使预聚物溶液与γ-摩尔%的PPD和另外的TCL接触以形成聚合物溶液; 其中步骤ii)和iii)中加入的TCL的总量是基于在步骤i)和iii)中添加的DAPBI和PPD的总量的化学计量的量; 加入DAPBI和PPD的量足以提供基于聚合物的重量百分比固体含量为12%或更高的聚合物溶液; 并且其中y + b的和为100,并且b×c的乘积为225或更大。
    • 18. 发明授权
    • Process for forming an aramid copolymer
    • 形成芳族聚酰胺共聚物的方法
    • US08921511B2
    • 2014-12-30
    • US13559655
    • 2012-07-27
    • Frederick K Mallon
    • Frederick K Mallon
    • C08G73/00C08G69/28C08G73/18C08G69/32C08G69/00C08G69/26
    • C08G69/00C08G69/265C08G69/28C08G69/32C08G73/18
    • The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and wherein the sum of y+b is 100 and the product of b×c is 225 or greater.
    • 本发明涉及形成包含2-(4-氨基苯基)-5(6)氨基苯并咪唑(DAPBI),对苯二胺(PPD)和对苯二甲酰氯(TCl))残留物的聚合物碎屑的方法,包括以下步骤:i) 在包含有机溶剂和c重量百分数的无机盐的溶剂体系中形成b摩尔%DAPBI的浆料,其中无机盐以至少5重量%存在的有机溶剂的量存在; ii)使所述浆料与少于化学计量的对苯二甲酰氯接触以形成预聚物溶液; 和iii)使预聚物溶液与γ-摩尔%的PPD和另外的TCL接触以形成聚合物溶液; 其中步骤ii)和iii)中加入的TCL的总量是基于在步骤i)和iii)中添加的DAPBI和PPD的总量的化学计量的量; 加入DAPBI和PPD的量足以提供基于聚合物的重量百分比固体含量为12%或更高的聚合物溶液; 并且其中y + b的和为100,并且b×c的乘积为225或更大。
    • 20. 发明授权
    • Process for forming an aramid copolymer
    • 形成芳族聚酰胺共聚物的方法
    • US08716432B2
    • 2014-05-06
    • US13559684
    • 2012-07-27
    • Kiu-Seung Lee
    • Kiu-Seung Lee
    • C08G64/00C08G63/02
    • C08G69/00C08G69/32C08G73/18
    • The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5(6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of DAPBI in a solvent system comprising an organic solvent and an inorganic salt; (b) adding terephthaloyl dichloride to the slurry terephthaloyl dichloride in the amount of up to one-half mole for every mole of DAPBI in the slurry; (c) agitating the slurry to react the DAPBI and terephthaloyl dichloride to form an oligomeric solution; (d) adding PPD to the oligomeric solution and agitating until substantially all of the PPD is dissolved, (e) adding terephthaloyl dichloride in an amount of greater than one mole for every mole of PPD in the solution to form a prepolymer solution; and (e) agitating the prepolymer solution to form a polymer.
    • 本发明涉及形成包含2-(4-氨基苯基)-5(6)氨基苯并咪唑(DAPBI),对苯二胺(PPD)和对苯二酰氯的残留物的聚合物的方法,包括以下步骤:(a) DAPBI的浆料在包含有机溶剂和无机盐的溶剂体系中; (b)将浆料中对苯二甲酰氯的对苯二甲酰氯加入到浆料中每摩尔DAPBI达二摩尔量; (c)搅拌浆料以使DAPBI和对苯二酰氯反应形成低聚溶液; (d)将PPD加入到低聚溶液中并搅拌直到基本上所有的PPD溶解,(e)在溶液中每摩尔PPD加入大于1摩尔的对苯二甲酰氯以形成预聚物溶液; 和(e)搅拌预聚物溶液以形成聚合物。