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11. 发明授权

US6121483A 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin 失效
公开(公告)号：US6121483A
公开(公告)日：2000-09-19
申请号：US499353
申请日：2000-02-08
申请人： Masaki Fushimi , Shintaro Inazawa
发明人： Masaki Fushimi , Shintaro Inazawa
IPC分类号： C07C69/708 , C07C69/74 , C08F4/58 , C08F4/658 , C08F10/00 , C07L69/66 , C07L47/02
CPC分类号： C08F10/00 , C07C69/708
摘要： A 3-alkoxypropionic ester derivative, an olefin polymerization solid catalyst component using the same, an olefin polymerization catalyst using the same, and a process for the preparation of a polyolefin using the same. The 3-alkoxypropionic ester derivative is represented by formula (I): ##STR1## wherein R.sup.1 represents a hydrocarbon group having from 1 to 10 carbon atoms; R.sup.2 represents a hydrocarbon group having from 1 to 20 carbon atoms; R.sup.3 represents a hydrocarbon group having from 1 to 20 carbon atoms; and R.sup.4 represents a branched hydrocarbon group having 3 or more carbon atoms.

12. 发明授权

US6103655A Carrier for olefin polymerization catalysts 失效
标题翻译：烯烃聚合催化剂载体
公开(公告)号：US6103655A
公开(公告)日：2000-08-15
申请号：US23802
申请日：1998-02-13
申请人： Luciano Luciani , Wolfgang Neissl , Norbert Hafner
发明人： Luciano Luciani , Wolfgang Neissl , Norbert Hafner
IPC分类号： C08F4/02 , C08F4/58 , C08F4/626 , C08F4/654 , C08F4/658 , C08F4/6592 , C08F10/00 , C08F110/06 , B01J31/00 , B01J20/10 , B01J27/138 , B01J37/00 , C08F4/44
CPC分类号： C08F10/00 , C08F110/06
摘要： Procedure for the preparation of a solid carrier for olefin polymerization catalysts, comprising the steps:a) impregnating a silica with Mg-chloride solubilized in ethylbenzoate, in the presence of further electron donors,b) optionally drying the impregnated silica obtained in (a) and impregnating it with a solution of Mg-alkyls in SiCl.sub.4 at a temperature from -10 to 20.degree. C. and subsequently treating the obtained slurry at a temperature from 40.degree. C. to reflux temperature, optionally adding a further amount of electron donors,c) drying the obtained carrier.The carrier which is obtained according to the above procedure is advantageously used for the preparation of supported catalysts for the polymerization of olefins.
摘要翻译：制备用于烯烃聚合催化剂的固体载体的方法，包括以下步骤：a）在另外的电子给体存在下，用溶解在苯甲酸乙酯中的氯化镁浸渍二氧化硅，b）任选地干燥（a）中获得的浸渍二氧化硅，并在-10℃至20℃的温度下将其与SiCl 4中的Mg-烷基溶液一起浸渍，随后在40℃至回流温度下将得到的浆料处理，任选地加入另外量的电子给体， c）干燥得到的载体。根据上述方法获得的载体有利地用于制备用于烯烃聚合的负载型催化剂。

13. 发明授权

US06090903A Propylene homopolymer 失效
标题翻译：丙烯均聚物
公开(公告)号：US06090903A
公开(公告)日：2000-07-18
申请号：US952962
申请日：1997-12-04
申请人： Takuo Kataoka , Masayoshi Saito
发明人： Takuo Kataoka , Masayoshi Saito
IPC分类号： C08F4/646 , C08F4/655 , C08F4/656 , C08F4/658 , C08F110/06
CPC分类号： C08F110/06 , C08F4/6465 , C08F4/6555 , C08F4/6567
摘要： A propylene homopolymer having a high stereo-regularity and an excellent processability during sheet or film formation, characterized in that it exhibits a melt flow rate (MFR) of from 0.1 to 20 g/10 min., a xylene-soluble component content of not more than 6% by weight and an isoblock content [IB] of at least 3 mol % as determined by the following equation (1) from Pmmmr, Pmmrr and Pmrrm, which are absorption intensities attributed to isoblock chain in xylene-insoluble component by .sup.13 C-NMR spectrum:[IB]=[Pmmmr]+[Pmmrr]+[Pmrrm] (1)wherein [Pmmmr], [Pmmrr] and [Pmrrm] are the relative intensity ratio (mol %) of Pmmmr, Pmmrr and Pmrrm, respectively, which are absorption intensities attributed to isoblock chain.
摘要翻译： PCT No.PCT / JP97 / 01097 Sec。 371 1997年12月4日第 102（e）日期1997年12月4日PCT 1997年3月31日PCT公布。公开号WO97 / 38030 日期1997年10月16日一种丙烯均聚物，其具有高的立体规整性，并且在片或膜形成过程中具有优异的加工性能，其特征在于其熔体流动速率（MFR）为0.1至20g / 10min，由Pmmmr，Pmmrr和Pmrrm的下列等式（1）确定的可溶组分含量不超过6重量％，并且具有至少3摩尔％的异丁烯含量[IB]为归因于二甲苯中的异链段的吸收强度通过13 C-NMR光谱分析不溶成分：[IB] = [Pmmmr] + [Pmmrr] + [Pmrrm]（1）其中[Pmmmr]，[Pmmrr]和[Pmrrm]是Pmmmr的相对强度比（mol％），Pmmrr和Pmrrm，分别是归因于异链段的吸收强度。

14. 发明授权

US6080828A Polymerization catalyst and process for preparing an ethylene polymer 失效
标题翻译：聚合催化剂和制备乙烯聚合物的方法
公开(公告)号：US6080828A
公开(公告)日：2000-06-27
申请号：US310918
申请日：1999-05-13
申请人： Shin-ichi Kojoh , Mamoru Kioka
发明人： Shin-ichi Kojoh , Mamoru Kioka
IPC分类号： C08F4/658 , C08F4/651 , C08F4/655 , C08F8/00 , C08F10/02 , C08F110/02
CPC分类号： C08F10/02 , C08F110/02 , Y10S526/904
摘要： An ethylene polymer having small values of Mw/Mn and Mz/Mw, a small proportion of long-chain branches, a high melt tension and a high swell ratio, and a process for preparing the ethylene polymer are disclosed. A solid titanium catalyst component obtained by initially bringing a solid titanium composite which is obtained by the contact of a solid magnesium aluminum composite containing magnesium, halogen, aluminum, and an alkoxy group of 6 or more carbon atoms and/or alcohol of 6 or more carbon atoms with a tetravalent titanium compound into contact with an organometallic compound, and then bringing the resulting product into contact with oxygen is further disclosed. An ethylene polymerization catalyst comprising the above catalyst component and an organometallic compound catalyst component is furthermore disclosed. Therefore, the ethylene polymer is excellent in moldability, and a molded article obtained therefrom is excellent in rigidity and impact resistance and free from poor appearance.
摘要翻译：公开了具有小的Mw / Mn值和Mz / Mw值，小分支长支链，高熔体张力和高溶胀比的乙烯聚合物，以及制备乙烯聚合物的方法。一种固体钛催化剂组分，其通过首先将含有6个或更多个碳原子和/或6个或更多个碳原子的烷基的固体镁铝复合物与含有镁，卤素，铝的固体镁铝复合物接触而获得的固体钛复合物碳原子与四价钛化合物与有机金属化合物接触，然后使所得产物与氧接触。还公开了包含上述催化剂组分和有机金属化合物催化剂组分的乙烯聚合催化剂。因此，乙烯聚合物的成型性优异，其得到的成型体的刚性和耐冲击性优异，外观不良。

15. 发明授权

US6037296A Comonomer pretreated bimetallic catalyst for blow molding and film applications 失效
标题翻译：共聚单体预处理双金属催化剂用于吹塑和薄膜应用
公开(公告)号：US6037296A
公开(公告)日：2000-03-14
申请号：US066216
申请日：1998-04-24
申请人： John T. T. Hsieh , Sandra D. Schregenberger
发明人： John T. T. Hsieh , Sandra D. Schregenberger
IPC分类号： B01J31/22 , B01J31/26 , B01J31/32 , B01J37/02 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/658 , C08F10/00 , C08F210/16
CPC分类号： B01J31/143 , B01J31/1616 , B01J31/2295 , B01J31/38 , B01J37/0203 , C08F10/00 , B01J21/08 , B01J2531/48 , B01J31/0212 , C08F210/16 , C08F4/61912 , C08F4/61927
摘要： The invention relates to a catalyst component which is a tract product of reagents comprising silica which has a pore volume which exceeds 2.9 cc/gram and an average pore diameter which exceed 400 Angstroms;a metallocene of a first transition metal, activated by an alumoxane,a contact product of dialkylmagnesium and trialkylsilanol,a second transition metal source which exhibits a hydrogen response which is different from that of the metallocenean olefin of 4 to 20 carbon atoms. This catalyst component is activated by an aluminum alkyl activator.
摘要翻译：本发明涉及一种催化剂组分，其是包含二氧化硅的试剂的管道产物，其孔体积超过2.9cc / g，平均孔径超过400埃; 由铝氧烷活化的第一过渡金属的茂金属，二烷基镁和三烷基硅烷醇的接触产物，表现出与茂金属与4-20个碳原子的烯烃不同的氢响应的第二过渡金属源。该催化剂组分由烷基铝活化剂活化。

16. 发明授权

US6028140A Process for the (co)polymerization of olefins 失效
标题翻译：烯烃（共）聚合方法
公开(公告)号：US6028140A
公开(公告)日：2000-02-22
申请号：US865079
申请日：1997-05-29
申请人： Gianni Collina , Tiziano Dall'occo , Maurizio Galimberti , Enrico Albizzati , Luciano Noristi
发明人： Gianni Collina , Tiziano Dall'occo , Maurizio Galimberti , Enrico Albizzati , Luciano Noristi
IPC分类号： C08F4/658 , C08F2/42 , C08F2/48 , C08F4/642 , C08F4/654 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F297/08 , C08G63/48
CPC分类号： C08F297/08 , C08F10/00 , C08F10/06 , C08F110/06 , C08F2410/05 , C08F4/65912
摘要： Homopolymers or copolymers obtained by a multistage process of olefins having the formula CH.sub.2 .dbd.CHR, in which R is hydrogen or R has from 1 to 10 carbon atoms and is an alkyl, cycloalkyl or aryl group, the process comprising:(A) a first stage of polymerization in which one or more of the olefins are polymerized in the presence of a titanium or vanadium catalyst;(B) a treatment stage in which the product obtained in the first stage of polymerization (A) is brought into contact with a compound capable of deactivating the catalyst present in the stage (A); and also brought into contact with a compound of a transition metal M selected from the group consisting of Ti, Zr, V, or Hf containing at least one M-.pi. bond and optionally with an alkyl-Al compound; and(C) a second stage of polymerization in which one or more of the olefins are polymerized, in one or more reactors, in the presence of the product obtained in treatment stage (B).
摘要翻译：通过具有式CH 2 = CHR的烯烃的多阶段方法获得的均聚物或共聚物，其中R是氢或R具有1至10个碳原子并且是烷基，环烷基或芳基，所述方法包括：（A）第一其中一种或多种烯烃在钛或钒催化剂存在下聚合的聚合阶段; （B）使在第一阶段（A）中获得的产物与能够使阶段（A）中存在的催化剂失活的化合物接触的处理阶段; 并且还与选自含有至少一个M-π键和任选与烷基-Al化合物的Ti，Zr，V或Hf组成的组中的过渡金属M的化合物接触; 和（C）在一个或多个反应器中，在处理阶段（B）中获得的产物存在下，使一种或多种烯烃聚合的第二阶段聚合。

17. 发明授权

US6018006A Process for preparing an ethylene polymerization catalyst and ethylene polymerization process 失效
公开(公告)号：US6018006A
公开(公告)日：2000-01-25
申请号：US358607
申请日：1994-12-14
申请人： Juan Raul Quijada Abarca , Dellyo Ricardo dos Santos Alvares
发明人： Juan Raul Quijada Abarca , Dellyo Ricardo dos Santos Alvares
IPC分类号： B01J31/38 , C08F4/02 , C08F4/10 , C08F4/12 , C08F4/16 , C08F4/60 , C08F4/64 , C08F4/646 , C08F4/654 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： C08F4/022 , C08F10/00 , C08F110/02
摘要： A preparation process for a catalytic support, based on a special alumina modified with varying quantities of magnesium chloride is described, a higher rate of MgCl.sub.2 leading to a lesser quantity of heavy molecular chains in the final polymer. The support, prepared by milling the special alumina together with the MgCl.sub.2 previously treated with ethyl benzoate, is impregnated with TiCl.sub.4 in order to create the catalyst. The resulting catalysts show high activity, which enables the metallic residue and chloride eliminating stage to be avoided in the resin so created. Furthermore the types of molecular weight distribution and of mechanical properties are different for the polymers produced.

18. 发明授权

US6015867A 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin 失效
标题翻译： 3-烷氧基丙酸酯衍生物，烯烃聚合催化剂和聚烯烃的制备方法
公开(公告)号：US6015867A
公开(公告)日：2000-01-18
申请号：US535514
申请日：1995-09-28
申请人： Masaki Fushimi , Shintaro Inazawa
发明人： Masaki Fushimi , Shintaro Inazawa
IPC分类号： C07C69/708 , C07C69/74 , C08F4/58 , C08F4/658 , C08F10/00 , C08F4/649
CPC分类号： C08F10/00 , C07C69/708
摘要： A 3-alkoxypropionic ester derivative, an olefin polymerization solid catalyst component using the same, an olefin polymerization catalyst using the same, and a process for the preparation of a polyolefin using the same. The 3-alkoxypropionic ester derivative is represented by formula (I): ##STR1## wherein R.sup.1 represents a hydrocarbon group having from 1 to 10 carbon atoms; R.sup.2 represents a hydrocarbon group having from 1 to 20 carbon atoms; R.sup.3 represents a hydrocarbon group having from 1 to 20 carbon atoms; and R.sup.4 represents a branched hydrocarbon group having 3 or more carbon atoms.
摘要翻译： 3-烷氧基丙酸酯衍生物，使用其的烯烃聚合固体催化剂组分，使用该烯烃聚合固体催化剂组分的烯烃聚合催化剂，以及使用其制备聚烯烃的方法。 3-烷氧基丙酸酯衍生物由式（I）表示：其中R 1表示具有1至10个碳原子的烃基; R2表示碳原子数为1〜20的烃基; R3表示碳原子数为1〜20的烃基; R 4表示碳原子数3以上的支链状烃基。

19. 发明授权

US6005049A Process for the production of polypropylene 失效
标题翻译：聚丙烯生产工艺
公开(公告)号：US6005049A
公开(公告)日：1999-12-21
申请号：US94477
申请日：1993-07-19
申请人： David Merrill Rebhan , David Albin Wibbenmeyer
发明人： David Merrill Rebhan , David Albin Wibbenmeyer
IPC分类号： C08F4/658 , C08F2/34 , C08F4/60 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F110/06
摘要： A process for the production of polypropylene comprising continuously contacting liquid propylene or a mixture comprising liquid propylene and one or more other alpha-olefins in one or more reaction zones, under gas phase polymerization conditions, with a catalyst system comprising (i) a solid particulate catalyst precursor, which includes magnesium; titanium; a halogen which is chlorine, bromine, or iodine, or mixtures thereof; and, as an inside electron donor, a carboxylic acid ester; (ii) a hydrocarbylaluminum cocatalyst; and (iii) as an outside electron donor, a silicon compound containing at least one silicon-oxygen-carbon linkage, the particles of precursor being carried into the reaction zone(s) via a portion of the liquid propylene, the flow rate of said portion having a Reynolds number greater than about 15,000.
摘要翻译：一种用于生产聚丙烯的方法，其包括在气相聚合条件下，在一个或多个反应区中将液体丙烯或包含液态丙烯和一种或多种其它α-烯烃的混合物与催化剂体系连续接触，所述催化剂体系包含（i）固体颗粒催化剂前体，其包括镁; 钛; 氯，溴或碘的卤素，或其混合物; 和作为内电子供体的羧酸酯; （ii）烃基铝助催化剂; 和（iii）作为外部电子供体，含有至少一个硅 - 氧 - 碳键的硅化合物，前体颗粒经由液体丙烯的一部分被运送到反应区中，所述的雷诺数大于约15,000的部分。

20. 发明授权

US5990034A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US5990034A
公开(公告)日：1999-11-23
申请号：US986183
申请日：1997-12-05
申请人： Takashi Nozaki
发明人： Takashi Nozaki
IPC分类号： C08F4/02 , C08F4/60 , C08F4/658 , C08F10/00 , C08F110/02 , C08F210/16 , B01J31/00 , B01J37/00
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16
摘要： An olefin polymerization catalyst comprising (A) a solid catalyst component and (B) an organometallic compound component. The solid catalyst component (A) is prepared by a process comprising the steps of:(I) obtaining a solid (A-1) by reacting:(i) an organomagnesium component soluble in a hydrocarbon solvent and represented by the formula (M.sup.1).sub..alpha. (Mg).sub..beta. (R.sup.1).sub.p (R.sup.2).sub.q (OR.sup.3).sub.r ; and(ii) an Si--H bond-containing chlorosilane compound represented by the formula: H.sub.a SiCl.sub.b R.sup.4.sub.4-(a+b), in a ratio of from 0.01 to 100 mol (ii) per mol (i);(II) reacting the solid (A-1) with an alcohol (A-2) in a ratio of from 0.05 to 20 mol of the alcohol per mol of C--Mg bonds contained in the solid (A-1), to form a reaction product; and(III) reacting the reaction product with a titanium compound (A-4). The solid catalyst component (A) is adjusted to have an alkoxy group/titanium molar ratio of 2.4 or lower and an alkoxy group/magnesium molar ratio of 0.15 or lower.
摘要翻译：一种烯烃聚合催化剂，其包含（A）固体催化剂组分和（B）有机金属化合物组分。固体催化剂组分（A）通过包括以下步骤的方法制备：（I）通过使以下物质反应获得固体（A-1）：（i）可溶于烃溶剂并由式（M1）表示的有机镁组分 α（Mg）β（R1）p（R2）q（OR3）r; 和（ii）由式IIaSiClbR44-（a + b）表示的含Si-H键的氯代硅烷化合物，其比例为0.01至100摩尔（ⅱ）/摩尔（i）; （II）使固体（A-1）与醇（A-2）按每摩尔固体（A-1）中所含的C-Mg键0.05至20摩尔醇的比例反应，形成反应产物; 和（III）使反应产物与钛化合物（A-4）反应。将固体催化剂组分（A）调节为烷氧基/钛摩尔比为2.4或更低，烷氧基/镁的摩尔比为0.15或更低。

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