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1. 发明授权

US10954365B2 Dilution index 有权
公开(公告)号：US10954365B2
公开(公告)日：2021-03-23
申请号：US16385211
申请日：2019-04-16
申请人： NOVA Chemicals (International) S.A.
发明人： Brian Molloy , Shivendra Goyal , Stephen Salomons , Fazle Sibtain
IPC分类号： C08J5/00 , C08L23/08 , C08F2/00 , C08F4/6592 , B29C41/22 , C08F2/06 , B32B3/26 , B32B27/32 , C08J5/18 , C08L23/20 , B29C41/04 , C08F210/16 , B32B7/12 , B32B27/08 , B32B27/34 , C08F4/655 , C08F4/658 , C08F4/659 , C08L23/14 , B29K23/00 , B29K105/00 , C08F210/14
摘要： This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Yd) greater than 0; total catalytic metal ≥3.0 ppm; ≥0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

2. 发明申请

US20170267822A1 ROTOMOLDED ARTICLES 有权
公开(公告)号：US20170267822A1
公开(公告)日：2017-09-21
申请号：US15609051
申请日：2017-05-31
申请人： NOVA Chemicals (International) S.A.
发明人： Celine Bellehumeur , Brian Molloy , Hamidreza Khakdaman , XiaoChuan Wang , Tieqi Li , Christopher Dobbin , Fazle Sibtain , Kenneth Taylor
IPC分类号： C08J5/18 , B29C41/04 , B32B27/08 , B32B27/32 , B32B27/34 , B32B3/26 , B32B7/12 , C08F2/00 , C08F2/06 , C08F210/16 , C08F4/655 , C08F4/658 , C08F4/659 , C08F4/6592 , C08J5/00 , C08L23/08 , C08L23/20 , B29K105/00 , B29K23/00 , C08F210/14
CPC分类号： C08L23/0815 , B29C41/04 , B29C41/22 , B29K2023/08 , B29K2105/0058 , B29K2105/0085 , B29K2105/0094 , B29K2905/02 , B29K2995/0063 , B29K2995/0088 , B32B3/266 , B32B7/12 , B32B27/08 , B32B27/327 , B32B27/34 , B32B2307/7265 , B32B2439/40 , C08F2/001 , C08F2/06 , C08F4/6555 , C08F4/6583 , C08F4/6585 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F210/14 , C08F210/16 , C08F2420/01 , C08F2420/04 , C08F2500/03 , C08F2500/09 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/17 , C08F2500/18 , C08F2500/26 , C08J5/00 , C08J5/18 , C08J2323/06 , C08J2323/08 , C08J2323/20 , C08J2323/24 , C08J2423/08 , C08J2423/20 , C08J2423/24 , C08L23/08 , C08L23/14 , C08L23/20 , C08L2203/16 , C08L2205/025 , C08L2205/03 , C08L2205/06 , C08L2314/02 , C08L2314/06
摘要： This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product and an ethylene polymer, where the ethylene interpolymer product has a Dilution Index (Yd) greater than 0 and improved Environmental Stress Crack Resistance (ESCR). The ethylene interpolymer product has a melt index from about 0.5 to about 15 dg/minute, a density from about 0.930 to about 0.955 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 6 and a CDBI50 from about 50% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

3. 发明申请

US20050215736A1 Olefin polymerization catalyst and olefin polymerization method using the same 失效
公开(公告)号：US20050215736A1
公开(公告)日：2005-09-29
申请号：US10998837
申请日：2004-11-30
申请人： Toshifumi Takemori , Minoru Iijima , Yoshihisa Hayashida , Masashi Iida
发明人： Toshifumi Takemori , Minoru Iijima , Yoshihisa Hayashida , Masashi Iida
IPC分类号： C08F4/02 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/44 , B01J31/00
CPC分类号： C08F210/02 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , C08F4/65922 , C08F4/65912 , C08F2500/18 , C08F2500/24 , C08F2500/03 , C08F210/14
摘要： An olefin polymerization solid catalyst which comprises having a reaction product of (C) a transition metal compound of the following formula (1) or (2) and (D) an organoaluminum compound carried on a support having (A) silica treated with (B) an organoaluminum-oxy compound; (R1aCp)m(R2bCp)nM-(-X-Ar-Yc)4-(m+n) (1) wherein M is titanium, zirconium or hafnium, Cp is a group having a cyclopentadienyl structure, R1 and R2 are a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an alkylaryl group, an arylalkyl group or an alkylsilyl group, X is an oxygen atom or a sulfur atom, Ar is an aromatic ring, Y may be the same or different and is a hydrogen atom or a substituent selected from the group consisting of a hydrocarbon group, an alkylsilyl group, a halogen atom, a halogenated hydrocarbon group, a nitrogen-containing organic group, an oxygen-containing organic group or a sulfur-containing organic group, a and b are an integer of from 0 to 5, m and n are an integer of from 0 to 3, m+n is an integer of from 1 to 3, and c is an integer of from 1 to 5, provided that Y is not hydrogen when Ar is a benzene ring, R3(R1dCp)(R2eCp)M-(-X-Ar-Yc)2 (2) wherein M is titanium, zirconium or hafnium, Cp is a group having a cyclopentadienyl structure, R1 and R2 are a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an alkylaryl group, an arylalkyl group or an alkylsilyl group, R3 is a divalent group selected from the group consisting of an alkylene group, an arylalkylene group, a dialkylsilylene group, a dialkylgermylene group, an alkylphosphinediyl group or an alkylimino group, which crosslinks (R1dCp) and (R2eCp), X is an oxygen atom or a sulfur atom, Ar is an aromatic ring, Y may be the same or different and is a hydrogen atom or a substituent selected from the group consisting of a hydrocarbon group, an alkylsilyl group, a halogen atom, a halogenated hydrocarbon group, a nitrogen-containing organic group, an oxygen-containing organic group and a sulfur-containing organic group, d and e are an integer of from 0 to 4, and c is an integer of from 1 to 5, provided that Y is not hydrogen when Ar is a benzene ring.

4. 发明申请

US20050202959A1 Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerisation of alk-1-enes 失效
标题翻译：齐格勒 - 纳塔型固体催化组分和催化体系，其制备方法及其在烷-1-烯的聚合中的应用
公开(公告)号：US20050202959A1
公开(公告)日：2005-09-15
申请号：US10504702
申请日：2003-01-28
申请人： Wolf Spaether , John Lynch , Joachim Rosch , Rainer Hemmerich
发明人： Wolf Spaether , John Lynch , Joachim Rosch , Rainer Hemmerich
IPC分类号： C08F10/00 , C08F4/64 , C08F4/658 , C08F10/06 , C08F110/06 , B01J31/00 , C08F4/44
CPC分类号： C08F110/06 , C08F4/651 , C08F4/025 , C08F4/6546 , C08F2500/12 , C08F2500/15 , C08F2500/24
摘要： The present invention relates to a new solid catalytic component, which can be used in combination with an aluminum compound as co-catalyst and optionally an external electron donor as additional co-catalyst to form a catalytic system of the Ziegler-Natta-catalyst-type. The solid catalytic system comprises titanium or vanadium compound, a compound of magnesium containing at least one halogen, a particulate porous support, and optionally an internal electron donor.
摘要翻译：本发明涉及一种新的固体催化组分，其可以与作为助催化剂的铝化合物和任选的外部电子给体一起用作另外的助催化剂以形成齐格勒 - 纳塔催化剂型催化体系。固体催化体系包括钛或钒化合物，含有至少一个卤素的镁的化合物，颗粒状多孔载体和任选的内部电子给体。

5. 发明授权

US06924343B2 Olefin polymerization catalyst component, its preparation and use 有权
公开(公告)号：US06924343B2
公开(公告)日：2005-08-02
申请号：US10868509
申请日：2004-06-14
申请人： Jarmo Lindroos , Solveig Johansson , Päivi Waldvogel
发明人： Jarmo Lindroos , Solveig Johansson , Päivi Waldvogel
IPC分类号： C08J5/18 , C08F4/654 , C08F4/655 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02 , C08L23/04 , C08F4/60 , C08F4/602
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08L23/04 , C08L2205/02 , C08L2314/02 , C08F4/025 , C08F4/6555 , C08L2666/04 , C08F2500/12 , C08F2500/17
摘要： A process for polymerizing olefins using a high activity catalyst. The catalyst utilize in the present process has a good balance in activity and can be used to carry out ethylene polymerization at high and low melt flow rates to produce low gel or gel free product.

6. 发明授权

US06897274B2 Prepolymerization method of α-olefin 失效
标题翻译： α-烯烃的预聚方法
公开(公告)号：US06897274B2
公开(公告)日：2005-05-24
申请号：US10416399
申请日：2001-10-18
申请人： Yoo-Kyoung Kim , Kun Lo , Il-Seop Kim
发明人： Yoo-Kyoung Kim , Kun Lo , Il-Seop Kim
IPC分类号： C08F4/658 , C08F4/616 , C08F4/649 , C08F4/651 , C08F4/656 , C08F10/00 , C08F110/02 , C08F4/42
CPC分类号： C08F110/02 , C08F4/6565 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： The present invention relates to a method for the prepolymerization of α-olefin in the presence of a catalyst system which comprises (a) a magnesium supported solid complex titanium catalyst and (b) an organometallic compound of metal of Group I or III of the Periodic Table, characterized in that an inert solvent having high viscosity with molecular weight of 300 g/mole or more is used as a reaction medium.
摘要翻译：本发明涉及一种在催化剂体系存在下预聚合α-烯烃的方法，该催化剂体系包括（a）镁负载的固体络合物钛催化剂和（b）元素周期表I或III族金属的有机金属化合物表格，其特征在于使用分子量为300g / mol以上的高粘度的惰性溶剂作为反应介质。

7. 发明申请

US20050003953A1 Olefin polymerization catalyst compositions and method of preparation 有权
标题翻译：烯烃聚合催化剂组合物及其制备方法
公开(公告)号：US20050003953A1
公开(公告)日：2005-01-06
申请号：US10903309
申请日：2004-07-30
申请人： Linfeng Chen , Richard Kemp , Thomas Nemzek
发明人： Linfeng Chen , Richard Kemp , Thomas Nemzek
IPC分类号： C08F4/654 , C08F4/658 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00 , C08F4/6574 , C08F4/6548 , C08F4/685 , C08F4/658 , C08F4/6565
摘要： A method of making a solid procatalyst composition for use in a Ziegler-Natta olefin polymerization catalyst composition, said method comprising: contacting a precursor composition comprising a magnesium compound with a titanium halide compound and an internal electron donor in any order, in a suitable reaction medium to prepare a solid procatalyst composition, separating the solid procatalyst from the reaction medium, extracting the solid procatalyst composition by contacting the same one or more times with a liquid diluent at an elevated temperature for a period of time sufficient to prepare a solid procatalyst composition having a decreased titanium content compared to the titanium content of the solid procatalyst composition before said extraction, and recovering the solid procatalyst composition.
摘要翻译：一种制备用于齐格勒 - 纳塔烯烃聚合催化剂组合物的固体前催化剂组合物的方法，所述方法包括：在合适的反应中以任何顺序将包含镁化合物的前体组合物与卤化钛化合物和内部电子给体接触培养基以制备固体前催化剂组合物，将固体前催化剂从反应介质中分离出来，通过在高温下将液体稀释剂与液体稀释剂接触一段或者多次，将其固体原料催化剂组合物提取一段时间足以制备固体前催化剂组合物在所述萃取之前，与固体前催化剂组合物的钛含量相比，钛含量降低，并且回收固体前催化剂组合物。

8. 发明授权

US6414102B2 Linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions, graft copolymers derived therefrom, and process for preparing same 失效
标题翻译：具有窄分子量和组成分布的α-烯烃和二乙烯基苯的线性共聚物，由其衍生的接枝共聚物及其制备方法
公开(公告)号：US6414102B2
公开(公告)日：2002-07-02
申请号：US81044001
申请日：2001-03-19
申请人： PENN STATE RES FOUND
发明人： CHUNG TZE-CHIANG , DONG JIN YONG
IPC分类号： C08F4/642 , C08F4/646 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/16 , C08F210/18 , C08F212/36 , C08F255/02 , C08F290/04 , C08F236/20 , C08F255/06
CPC分类号： C08F290/042 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F10/00 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/16 , C08F210/18 , C08F212/36 , C08F255/02 , Y02P20/582 , C08F4/6543 , C08F4/65927 , C08F212/08 , C08F236/20 , C08F2500/03 , C08F2500/06 , C08F2500/25 , C08F210/14
摘要： The invention relates to polyolefin copolymers (I)and to graft copolymers (II)which are prepared from the copolymers (I), wherein the copolymers (I) are linear copolymers containing divinylbenzene comonomer units selected from the group consisting of 1,4-divinylbenzene units, mixtures of 1,4- and 1,3-divinylbenzene units and mixtures of 1,4-, 1,3- and 1,2-divinylbenzene units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G', independently, are selected from -H, -OH, epoxy, -NH2, -COOH, anhydride, -Cl, -Br, -M, -COOM (M=metal) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. In the graft copolymer (II), the combined alpha-olefin mole % (x+y) is from about 50 and 99.9 mole %, the sum of x, y, m and n is 100%, n is at least 0.05%, and the backbone polymer chain has a number average molecular weight (Mn) of at least about 1,000.
摘要翻译：本发明涉及由共聚物（I）制备的聚烯烃共聚物（I）和接枝共聚物（II），其中共聚物（I）是含有二乙烯基苯共聚单体单元的线性共聚物，其选自1,4-二乙烯基苯单元，1,4-和1,3-二乙烯基苯单元的混合物以及1,4-，1,3-和1,2-二乙烯基苯单元的混合物，其中式I和II中的R 1是C1至C10直链或支链烷基或C6〜C10取代或未取代的芳基; 并且其中G和G'独立地选自-H，-OH，环氧基，-NH 2，-COOH，酸酐，-Cl，-Br，-M，-COOM（M =金属）或具有分子量至少约为500，其可以衍生自步骤和链式聚合反应。在接枝共聚物（II）中，组合的α-烯烃摩尔％（x + y）为约50和99.9摩尔％，x，y，m和n的和为100％，n为至少0.05％骨架聚合物链的数均分子量（Mn）为至少约1,000。

9. 发明授权

US6156691A Ziegler-Natta catalyst systems modified during their preparation 失效
标题翻译：齐格勒 - 纳塔催化剂体系在制备过程中改进
公开(公告)号：US6156691A
公开(公告)日：2000-12-05
申请号：US928394
申请日：1997-09-12
申请人： Stephan Huffer , Ulrich Moll , Ian David McKenzie , Franz Langhauser , Peter Kolle , Roland Hingmann , Gunther Schweier , Rainer Hemmerich , Jurgen Kerth
发明人： Stephan Huffer , Ulrich Moll , Ian David McKenzie , Franz Langhauser , Peter Kolle , Roland Hingmann , Gunther Schweier , Rainer Hemmerich , Jurgen Kerth
IPC分类号： C08F4/02 , C08F4/642 , C08F4/646 , C08F4/654 , C08F4/658 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： In catalyst systems of the Ziegler-Natta type modified during their preparation and comprising as active constituentsa) a titanium-containing solid component which is obtained by reacting a compound of titanium with a compound of magnesium, a halogen, an inorganic oxide as support, a C.sub.1 -C.sub.8 -alkanol and a carboxylic ester as electron donor compound,and also as cocatalystb) an aluminum compound andc) if desired, a further electron donor compound,the titanium-containing solid component a) is prepared by first, in a first stage, admixing an inorganic oxide as support with a solution of a chlorine-free compound of magnesium in an inert solvent, stirring this mixture for from 0.5 to 5 hours at from 10 to 120.degree. C. and subsequently reacting it while stirring continually in an inert solvent with a C.sub.1 -C.sub.8 -alkanol in an at least 1.3-fold excess, based on the compound of magnesium, to give a chlorine-free intermediate, then, without purification or extraction of the intermediate, adding a compound of trivalent or tetravalent titanium and a carboxylic ester as electron donor compound to this intermediate, stirring the resulting mixture for at least 30 minutes at from 20 to 130.degree. C., subsequently filtering off and washing the solid thus obtained and subsequently, in a second stage, extracting the solid obtained from the first stage in an inert solvent comprising at least 5% by weight of titanium tetrachloride and washing it with a liquid alkane.
摘要翻译：在其制备过程中改性的齐格勒 - 纳塔型催化剂体系中，包含作为活性成分的含钛固体成分a）通过使钛化合物与镁，卤素，无机氧化物作为载体反应而得到的含钛固体成分，作为电子给体化合物的C1-C8-链烷醇和羧酸酯，以及作为助催化剂的b）铝化合物，和c）如果需要，另外的电子给体化合物，含钛固体组分a）首先在第一阶段，将无机氧化物作为载体与无氯化合物的镁在惰性溶剂中的溶液混合，在10至120℃下搅拌该混合物0.5至5小时，随后在持续搅拌下反应在基于镁化合物的至少1.3倍过量的C 1 -C 8烷醇的惰性溶剂中，得到无氯中间体，然后不经纯化或萃取中间体，加入一种磅三价或四价钛和羧酸酯作为电子给体化合物，在20至130℃下搅拌所得混合物至少30分钟，随后过滤并洗涤由此获得的固体，随后在第二阶段，在包含至少5重量％的四氯化钛的惰性溶剂中萃取从第一阶段获得的固体，并用液体烷烃洗涤。

10. 发明授权

US6124412A Alumoxane-enhanced, supported ziegler-natta polymerization catalysts, methods of making same, processes of using same and polymers produced therefrom 失效
标题翻译：氧化铝增强的负载齐格勒 - 纳塔聚合催化剂，其制备方法，使用方法和由其制备的聚合物
公开(公告)号：US6124412A
公开(公告)日：2000-09-26
申请号：US999049
申请日：1997-12-29
申请人： Abdulmalik Bin-Taleb , Raju Raghavan , Abdulwhab Al-Sadoon
发明人： Abdulmalik Bin-Taleb , Raju Raghavan , Abdulwhab Al-Sadoon
IPC分类号： C08F4/658 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： The present invention relates to a new olefin polymerization catalyst composition, and methods of preparing and methods of using the catalysts to polymerize various olefinic monomers in either gas or slurry phase reactions. The principal advance over the previous art of record involves using alumoxanes or combinations of alumoxanes as catalyst preactivators. Polymers prepared from these catalysts posses productivity increased as high as 40 percent. At the same time, the bulk density remains relatively constant. Additionally, the total amount of cocatalyst species needed to effectively practice the invention is relatively low.
摘要翻译：本发明涉及新的烯烃聚合催化剂组合物，以及制备方法和使用催化剂在气相或浆料相反应中聚合各种烯烃单体的方法。与先前技术记录相比的主要进展是使用铝氧烷或铝氧烷的组合作为催化剂预活化剂。从这些催化剂制备的聚合物的生产率提高高达40％。同时，体积密度保持相对恒定。另外，有效地实施本发明所需的助催化剂物质的总量相对较低。

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