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    • 31. 发明授权
    • Phenylcarbodiimides, compositions containing them and their use in the
control of pests
    • 苯基碳二亚胺,含有它们的组合物及其在防治害虫中的应用
    • US4968720A
    • 1990-11-06
    • US231749
    • 1988-08-12
    • Josef Ehrenfreund
    • Josef Ehrenfreund
    • A01N47/30A01N47/32A01N47/40A01N47/42C07C67/00C07C241/00C07C267/00C07C325/00C07C331/28C07C335/16C07C335/32C07C335/36
    • A01N47/30A01N47/32A01N47/40A01N47/42C07C331/28C07C335/16C07C335/36C07C2101/08
    • Novel substituted phenyl-thioureas, -isothioureas and -carbodiimides of formula I ##STR1## in which R.sub.1 is C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkyl mono- or poly-substituted by halogen and/or by C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.8 cycloalkyl mono- or poly-substituted by C.sub.1 -C.sub.3 alkyl, or is C.sub.3 -C.sub.8 cycloalkyl-C.sub.1 -C.sub.4 alkyl; each of R.sub.2 and R.sub.3 is C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.6 cycloalkyl or C.sub.5 -C.sub.6 cycloalkenyl; each of R.sub.4 and R.sub.5 is hydrogen or C.sub.1 -C.sub.4 alkyl; each R.sub.6 is halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy or a --CH.dbd.CH.sub.2, --CH.sub.2 or --CH.sub.2 bridge in the 2,3- or 3,4-position; n is 0, 1 or 2; Z is --NH--CS--NH--, --N.dbd.C(SR.sub.7 --NH-- or --N.dbd.C.dbd.N--, and R.sub.7 is C.sub.1 -C.sub.10 alkyl or C.sub.3 -C.sub.5 alkenyl, and salts thereof with organic or inorganic acids, processes and intermediates for their manufacture, their use in the control of pests, and pesticidal compositions that contain at least one compound of formula I as active ingredient, are disclosed. The preferred field of use is the control of pests in and on animals and plants.
    • 式I的新型取代的苯基 - 硫脲, - 异硫脲和 - 碳二亚胺其中R 1是C 1 -C 8烷基,被卤素单取代或多取代的C 1 -C 8烷基和/或被C 1 -C 6烷氧基,C 3 -C 8环烷基 C 1 -C 3烷基单或多取代的C 3 -C 8环烷基,或者是C 3 -C 8环烷基-C 1 -C 4烷基; R 2和R 3各自为C 1 -C 6烷基,C 5 -C 6环烷基或C 5 -C 6环烯基; R 4和R 5各自为氢或C 1 -C 4烷基; 每个R 6是2,3或3,4位的卤素,C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基或-CH = CH 2,-CH 2或-CH 2桥; n为0,1或2; Z为-NH-CS-NH-,-N = C(SR7-NH-或-N = C = N-,R7为C1-C10烷基或C3-C5烯基,其盐与有机或无机酸, 公开了用于其制造的中间体,其用于控制​​害虫和含有至少一种式I化合物作为活性成分的杀虫组合物,优选的用途是控制动物和植物中的害虫。
    • 32. 发明授权
    • Substituted carbodiimides
    • 取代的碳二亚胺
    • US4921876A
    • 1990-05-01
    • US288396
    • 1988-12-22
    • Manfred BogerJosef Drabek
    • Manfred BogerJosef Drabek
    • C07C267/00A01N47/40C07D213/64C07D213/643
    • C07D213/643A01N47/40
    • The invention relates to novel substituted carbodiimides of the formula ##STR1## wherein R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 alkoxy which is substituted by 1 to 7 halogen atoms, or is C.sub.1 -C.sub.5 alkylthio;R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.10 alkyl or C.sub.1 -C.sub.5 alkoxy;R.sub.3 is hydrogen, C.sub.1 -C.sub.10 alkyl, halogen, phenoxy, phenylthio, or is phenoxy or phenylthio, each mono- or disubstituted by a member selected from the group consisting of halogen, methyl, ethyl, C.sub.1 -C.sub.3 haloalkyl containing 1 to 7 halogen atoms and cyano, or is pyridyloxy or pyridyloxy which is mono- or disubstituted by a member selected from the group consisting of halogen and C.sub.1 -C.sub.3 haloalkyl containing 1 to 7 halogen atoms;R.sub.4 is C.sub.1 -C.sub.12 alkyl, alkoxyalkyl containing a total of 2 to 10 carbon atoms, C.sub.3 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.10 cycloalkylmethyl, C.sub.3 -C.sub.10 cycloalkyl which is substituted by 1 to 3 C.sub.1 -C.sub.3 alkyl groups, or is C.sub.1 -C.sub.5 -alkyl which is substituted to 1 to 2 C.sub.3 -C.sub.10 cycloalkyl groups, or is a polycyclic alkyl group containing 7 to 10 carbon atoms, phenyl(C.sub.1 -C.sub.5)alkyl or phenyl(C.sub.1 -C.sub.5)alkyl which is mono- or disubstituted at the phenyl nucleus by halogen, trifluoromethyl, methoxy or ethoxy, to the preparation of these compounds and to compositions containing them for use in pest control, especially for controlling insects and representatives of the order Acarina that attack plants and animals, in particular plant-destructive sucking insects.