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41. 发明授权

US6136923A Thermoplastic compositions of interpolymers of ethylene with styrene blended with poly vinyl chloride 失效
公开(公告)号：US6136923A
公开(公告)日：2000-10-24
申请号：US950983
申请日：1997-10-15
申请人： Yunwa W. Cheung , Martin J. Guest
发明人： Yunwa W. Cheung , Martin J. Guest
IPC分类号： C08J5/18 , C08L23/02 , C08L23/08 , C08L25/02 , C08L25/06 , C08L27/02 , C08L27/06 , C09D123/08 , C08K5/10 , C08K5/521 , C08L25/08
CPC分类号： C08J5/18 , C08L23/0838 , C08L25/06 , C08L27/06 , C09D123/0838 , C08J2323/08 , C08L2314/06
摘要： The present invention relates to blend compositions comprising;(A) of from about 1 to about 99 weight percent based on the combined weights of Components A, B and C of at least one substantially random interpolymer; and wherein said interpolymer;(1) contains of from about 0.5 to about 65 mole percent of polymer units derived from;(a) at least one vinylidene aromatic monomer, or(b) at least one hindered aliphatic vinylidene monomer, or(c) a combination of at least one vinylidene aromatic monomer and at least one hindered aliphatic vinylidene monomer;(2) contains of from about 35 to about 99.5 mole percent of polymer units derived from at least one aliphatic .alpha.-olefin having from 2 to 20 carbon atoms;(3) has a molecular weight (Mn) greater than about 1,000;(4) has a melt index (I.sub.2) of from about 0.01 to about 1,000;(5) has a molecular weight distribution (M.sub.w /M.sub.n) of from about 1.5 to about 20; and(B) of from about 99 to about 1 weight percent based on the combined weights of Components A, B, and C of one or more vinyl halide homopolymer(s) or copolymer(s); and(C) of from about 0 to about 70 weight percent based on the combined weights of Components A, B, and C of one or more plasticizers. The novel blend compositions, provide materials with improved processing/property attributes over the unmodified polymers comprising the blends. The blend compositions can exhibit a unique balance of properties including enhanced modulus and barrier properties, improved tensile strength, radio frequency (rf) sealability, solvent bondability, thermal stability and heat resistance depending upon the selection of the individual blend components and their composition ratios. Additionally, the location and the breadth of the glass transition can be controlled by varying the blend composition and plasticizer level. Surprisingly blends including a plasticizer show a single phase material from glass transition temperature data analysis.

42. 发明授权

US6100337A Functionalized thermoplastic elastomer 失效
标题翻译：官能化热塑性弹性体
公开(公告)号：US6100337A
公开(公告)日：2000-08-08
申请号：US80822
申请日：1998-05-18
申请人： Bridget Ann Spence , Ronald James Hoxmeier , Robert Charles Job
发明人： Bridget Ann Spence , Ronald James Hoxmeier , Robert Charles Job
IPC分类号： C08F255/00 , C08F255/02 , C08F255/08 , C08F283/12 , C08L27/22 , C08L25/02 , C08L25/18
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an .alpha.-olefin capable of producing an amorphous backbone with a comonomer which provides a "hook" for grafting to with a living polystyrene chain. Another method is to copolymerize an .alpha.-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an .alpha.-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译：使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。基础聚合物可以通过使能够制备无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。在较不优选的实施方案中，常规EPDM聚合物可以被金属化，并且由主链生长的单烯基芳族化合物阴离子可聚合单体。

43. 发明授权

US6084031A TPV from hydrosilylation crosslinking of acrylic modified bromo XP-50 butyl rubber 失效
标题翻译： TPV由氢化硅烷化交联丙烯酸改性溴代XP-50丁基橡胶
公开(公告)号：US6084031A
公开(公告)日：2000-07-04
申请号：US201050
申请日：1998-11-30
申请人： Robert E. Medsker , Raman Patel , Donald Wang
发明人： Robert E. Medsker , Raman Patel , Donald Wang
IPC分类号： C08J3/24 , C08F8/00 , C08F8/18 , C08F8/42 , C08F210/10 , C08K3/02 , C08L23/06 , C08L23/10 , C08L23/12 , C08L23/22 , C08L51/06 , C08L83/05 , C08L101/00 , C08L25/02
CPC分类号： C08F8/42 , C08L51/06 , C08L23/10
摘要： An improved process for the preparation of thermoplastic vulcanizates from butyl rubbers by hydrosilylation crosslinking of acrylic or alkacrylic functionalized copolymers of isobutylene and paramethylstyrene is disclosed. The functionalization results in lower compression and tension set than when using conventional butyl rubbers. Other physical properties of the thermoplastic vulcanizate are improved consistent with more efficient crosslinking of the functionalized copolymer.
摘要翻译：公开了一种通过丙烯酸或异丁烯和对甲基苯乙烯的丙烯酸官能化共聚物的氢化硅烷化交联从丁基橡胶制备热塑性硫化橡胶的改进方法。与使用常规丁基橡胶相比，官能化导致较低的压缩和张力设定。与功能化共聚物的更有效的交联一致，改进了热塑性硫化橡胶的其它物理性能。

44. 发明授权

US5973037A Styrene ethylene butylene styrene (SEBS) copolymer rubber modified asphalt mixture 失效
标题翻译：苯乙烯乙烯丁烯苯乙烯（SEBS）共聚物橡胶改性沥青混合料
公开(公告)号：US5973037A
公开(公告)日：1999-10-26
申请号：US978243
申请日：1997-11-25
申请人： John R. Fields
发明人： John R. Fields
IPC分类号： C08L25/02 , C08L95/00
CPC分类号： C08L95/00 , C08L95/005 , C08L25/02
摘要： Process and composition for styrene-ethylene-butylene-styrene (SEBS) block copolymer modified asphalt mixtures for use in roofing, sealing, paving, and waterproofing membranes. Powdered and pelletized SEBS is added to oxidized or unoxidized asphalt flux in high-shear processes, and is applied in hot and ambient uses such as cutbacks and emulsions, with or without added fillers, fibers, or other additives.
摘要翻译：用于屋顶，密封，铺路和防水膜的苯乙烯 - 乙烯 - 丁烯 - 苯乙烯（SEBS）嵌段共聚物改性沥青混合物的工艺和组成。粉碎和造粒的SEBS在高剪切过程中被加入到氧化或未氧化的沥青助熔剂中，并且被加入到热和环境用途中，例如剪切和乳液，具有或不具有添加的填料，纤维或其它添加剂。

45. 发明授权

US5880183A Two-component polymer composition 失效
标题翻译：双组分聚合物组合物
公开(公告)号：US5880183A
公开(公告)日：1999-03-09
申请号：US952906
申请日：1997-11-24
申请人： Siew Puat Yeo
发明人： Siew Puat Yeo
IPC分类号： C08L25/02 , C08L29/04 , C09D129/04 , C09J129/04 , D21H19/58 , C08L1/02 , C08L31/04 , C09J131/04
CPC分类号： D21H19/58 , C08L29/04 , C09D129/04 , C09J129/04
摘要： A composition of a hydroxyl functional polymer, an acetate functional polymer and a carboxyl functional polymer, which are crosslinked by a polyfunctional aziridine. Preferably, PVOH, polyvinylacetate and a carboxylated styrene/butadiene are used as the polymers. The aziridine can be held separate from the polymers prior to crosslinking. The composition is useful as a wood adhesive or coating composition.
摘要翻译： PCT No.PCT / SG96 / 00002 Sec。 371日期：1997年11月24日 102（e）1997年11月24日PCT PCT 1996年4月9日PCT公布。第WO96 / 37551号公报日期：1996年11月28日由多官能氮丙啶交联的羟基官能聚合物，乙酸酯官能聚合物和羧基官能聚合物的组成。优选使用PVOH，聚乙酸乙烯酯和羧化苯乙烯/丁二烯作为聚合物。在交联之前，氮丙啶可以与聚合物分离。该组合物可用作木材粘合剂或涂料组合物。

46. 发明授权

US5877258A Thermoplastic molding materials 失效
标题翻译：热塑性成型材料
公开(公告)号：US5877258A
公开(公告)日：1999-03-02
申请号：US740212
申请日：1996-10-25
申请人： Norbert Guntherberg , Martin Weber , Freddy Gruber , Gerhard Lindenschmidt
发明人： Norbert Guntherberg , Martin Weber , Freddy Gruber , Gerhard Lindenschmidt
IPC分类号： B29C47/00 , B29C45/00 , B29C47/14 , C08F265/06 , C08L9/06 , C08L21/00 , C08L25/02 , C08L25/04 , C08L51/00 , C08L51/04 , C08L51/06 , C08L53/02 , C08L71/02
CPC分类号： C08L51/003 , C08L51/06 , C08L53/02 , Y10S525/902
摘要： Thermoplastic molding materials compriseA) from 30 to 98% by weight of a graft polymer ofa.sub.K) from 30 to 90% by weight of an elastomeric graft core, obtainable by copolymerization ofa.sub.K /1) from 80 to 99.99% by weight of a C.sub.1 -C.sub.10 -alkyl ester of acrylic acid,a.sub.K /2) from 0.01 to 20% by weight of a crosslinking monomer anda.sub.K /3) from 0 to 40% by weight of one or more further monomers, anda.sub.S) from 10 to 70% by weight of a graft shell ofa.sub.S /1) from 50 to 100% by weight of a styrene compound of the general formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, and/or of a C.sub.1 -C.sub.8 -alkyl ester of acrylic acid or methacrylic acid, anda.sub.S /2) from 0 to 50% by weight of one or more further monomers,B) from 1 to 50% by weight of a thermoplastic polymer ofb.sub.1) from 50 to 100% by weight of styrene and/or .alpha.-methylstyrene,b.sub.2) from 0 to 50% by weight of acrylonitrile andb.sub.3) from 0 to 50% by weight of one or more further monomers, andC) from 1 to 70% by weight of a copolymer ofc.sub.1) from 30 to 90% by weight of styrene and/or .alpha.-methylstyrene,C.sub.2) from 10 to 70% by weight of butadiene andC.sub.3) from 0 to 30% by weight of one or more further monomers,in which all or virtually all of the olefinic double bonds have been hydrogenated.
摘要翻译：热塑性成型材料包括A）30至98重量％的aK的接枝聚合物，30重量％至90重量％的弹性体接枝核心，其通过aK / 1）的80至99.99重量％丙烯酸的C1-C10烷基酯，aK / 2）0.01至20重量％的交联单体和K / 3）0至40重量％的一种或多种另外的单体，aS）为10至 70重量％的aS / 1的接枝壳）50至100重量％的通式为“IMAGE”的苯乙烯化合物，其中R 1和R 2各自为氢或C 1 -C 8烷基，和/或丙烯酸或甲基丙烯酸的C 1 -C 8烷基酯和1/2）0-50％重量的一种或多种其它单体，B）1至50重量％的热塑性聚合物，b1）50 至100重量％的苯乙烯和/或α-甲基苯乙烯，b2）0至50重量％的丙烯腈和b3）0至50重量％的一种或多种其它单体，和C）1至70重量％的c1）共聚物 30至90重量％的苯乙烯和/或α-甲基苯乙烯，C2）10至70重量％的丁二烯和C3）0至30重量％的一种或多种其它单体，其中全部或几乎全部的烯属双键已被氢化。

47. 发明授权

US5756579A Rubber-reinforced vinyl aromatic (CO) polymer 失效
标题翻译：橡胶增强乙烯基芳族（CO）聚合物
公开(公告)号：US5756579A
公开(公告)日：1998-05-26
申请号：US785086
申请日：1997-01-21
申请人： Vilma Fornasari , Davide Preti , Anna Grazia Rossi , Roberto Nocci
发明人： Vilma Fornasari , Davide Preti , Anna Grazia Rossi , Roberto Nocci
IPC分类号： C08F279/00 , C08F279/02 , C08F287/00 , C08L9/00 , C08L25/02 , C08L25/12 , C08L53/02 , C08L51/04
CPC分类号： C08F287/00 , C08F279/02 , C08L25/02 , C08L25/12 , C08L53/02 , C08L9/00
摘要： A rubber-reinforced vinyl aromatic (co)polymer comprising a polymeric matrix and a rubber phase dispersed and/or grafted in the polymeric matrix and consisting of a mixture of(i) a diene rubber and(ii) a vinyl aromatic monomer/conjugated 1,3-diene linear block copolymer, said block copolymer having a diene content exceeding 80 wt % and, respectively, a vinyl aromatic monomer content of less than 20 wt %.
摘要翻译：橡胶增强的乙烯基芳族（共）聚合物，其包含分散和/或接枝在聚合物基质中的聚合物基质和橡胶相，并由（i）二烯橡胶和（ii）乙烯基芳族单体/共轭1 的3-二烯线性嵌段共聚物，所述嵌段共聚物的二烯含量超过80重量％，乙烯基芳族单体含量分别小于20重量％。

48. 发明授权

US5741857A Blends of elastomer block copolymer and aliphatic .alpha.-olefin/monovinylidene aromatic monomer and/or hindered aliphatic vinylidene monomer interpolymer 失效
标题翻译：弹性体嵌段共聚物和脂族α-烯烃/单亚乙烯基芳族单体和/或受阻脂族亚乙烯基单体互聚物的共混物
公开(公告)号：US5741857A
公开(公告)日：1998-04-21
申请号：US732108
申请日：1996-10-15
申请人： Calvin P. Esneault , Morris S. Edmondson
发明人： Calvin P. Esneault , Morris S. Edmondson
IPC分类号： C08L23/00 , C08L23/06 , C08L23/08 , C08L25/02 , C08L25/08 , C08L53/00 , C08L53/02 , C08L25/04
CPC分类号： C08L53/00 , C08L23/06 , C08L23/0838 , C08L25/02 , C08L53/02 , C08L53/025 , C08L23/0815
摘要： A thermoplastic elastomeric blend composition comprising: (A) from 99 to 1 weight percent of a styrenic block copolymer; and (B) from 1 to 99 weight percent of an interpolymer of .alpha.-olefin and (1) at least one aliphatic .alpha.-olefin and (2)at least one vinylidene aromatic monomer or (2) at least one hindered aliphatic vinylidene monomer or (3) a combination of at least one vinylidene aromatic monomer and at least one hindered aliphatic vinylidene monomer, and fabricated articles made from such composition.
摘要翻译：一种热塑性弹性体共混物组合物，其包含：（A）99至1重量％的苯乙烯嵌段共聚物; 和（B）1至99重量％的α-烯烃互聚物和（1）至少一种脂族α-烯烃和（2）至少一种亚乙烯基芳族单体或（2）至少一种受阻脂族亚乙烯基单体或（3）至少一种亚乙烯基芳族单体和至少一种受阻脂族亚乙烯基单体的组合，以及由该组合物制成的制品。

49. 发明授权

US5679759A Polycarbonate moulding materials with improved toughness 失效
标题翻译：聚碳酸酯成型材料具有改善的韧性
公开(公告)号：US5679759A
公开(公告)日：1997-10-21
申请号：US530629
申请日：1995-09-20
申请人： Dieter Wittmann , Thomas Eckel , Heinrich Alberts , Herbert Eichenauer , Ulrich Jansen
发明人： Dieter Wittmann , Thomas Eckel , Heinrich Alberts , Herbert Eichenauer , Ulrich Jansen
IPC分类号： C08L25/02 , C08L51/04 , C08L69/00 , C08G64/00
CPC分类号： C08L51/04 , C08L25/02 , C08L69/00 , C08L69/005
摘要： Thermoplastic moulding materials containing A. 15 to 80 parts by weight of a thermoplastic polycarbonate or polyester carbonate, and B. 4 to 40 parts by weight of a graft polymer of B.1 20 to 60 weight % of one or more monomers on B.2 40 to 80 weight % of one or more graft bases having glass transition temperatures
摘要翻译：含有A.15〜80重量份热塑性聚碳酸酯或聚酯碳酸酯的热塑性成型材料，以及B.4〜40重量份B.1的接枝聚合物20〜60重量％的B上的一种或多种单体。 2 40至80重量％的玻璃化转变温度<0℃的一个或多个接枝基质和C.16至45重量份热塑性芳族乙烯基（共）聚合物，其中接枝基底B.2具有平均粒径（d50值）为0.20〜0.35μm，成分B:C的重量比为2:1〜1:4。

50. 发明授权

US5612417A Thermoplastic molding materials having high transparency prepared from compatible polymer alloys 失效
标题翻译：由相容的聚合物合金制备的具有高透明度的热塑性成型材料
公开(公告)号：US5612417A
公开(公告)日：1997-03-18
申请号：US568487
申请日：1995-12-07
申请人： Thomas Rhein , Michael Wicker , Mona Rueppel , Gerald Dietrich , Ernst Mohr
发明人： Thomas Rhein , Michael Wicker , Mona Rueppel , Gerald Dietrich , Ernst Mohr
IPC分类号： C08L25/02 , C08L25/14 , C08L33/00 , C08L33/04 , C08L33/06 , C08L33/12 , C08L33/02 , C08L33/10
CPC分类号： C08L33/12 , C08L25/14 , C08L33/062
摘要： A thermoplastic polymethacrylate molding material with a high degree of thermal dimensional stability, a high degree of transparency, a high degree of flowability and a high degree of resistance against water, monomeric methylmethacrylate, mixtures consisting of ethanol and water, as well as fuel, wherein the molding material is a compatible mixture of1 to 99 wt % of a copolymer P, made from (p1) 30 to 70 wt % styrene and/or .alpha.-methylstyrene, (p2) 29 to 70 wt % (C.sub.1 -C.sub.6 -alkyl)methacrylate, and (p3) 1 to 20 wt % acrylic acid and/or methacrylic acid, the sum of (p1), (p2), and (p3) adding up to 100 wt %, and99 to 1 wt.-parts of a polymethylmethacrylate polymer PM, made of (pm1) 80 to 100 wt % methylmethacrylate, as well as (pm2) 0 to 20 wt % monomers which can be copolymerized with methylmethacrylate.
摘要翻译：一种热塑性聚甲基丙烯酸酯成型材料，具有高度的热尺寸稳定性，高透明度，高流动性和高耐水性，单体甲基丙烯酸甲酯，由乙醇和水组成的混合物以及燃料，其中成型材料是由（p1）30〜70重量％苯乙烯和/或α-甲基苯乙烯制成的1〜99重量％共聚物P，（p2）29〜70重量％（C1-C6烷基）和（p3）1〜20重量％的丙烯酸和/或甲基丙烯酸，（p1），（p2）和（p3）之和为100重量％，99〜1重量份的聚甲基丙烯酸甲酯聚合物PM，由（pm1）80-100重量％甲基丙烯酸甲酯制成，以及（pm2）0-20重量％的可与甲基丙烯酸甲酯共聚的单体。

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