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1. 发明授权

US10072116B2 Modified propylene-(α-olefin) copolymer, method for producing same, coating material comprising same, resin composition for molding use, and hot-melt composition 有权
公开(公告)号：US10072116B2
公开(公告)日：2018-09-11
申请号：US15034136
申请日：2014-11-05
申请人： MITSUI CHEMICALS, INC.
发明人： Kuniaki Kawabe , Hirotaka Kanaya , Masakazu Tanaka , Toshiyuki Ito , Masako Yoshida
IPC分类号： C08F255/10 , C08F8/00 , C08F210/06 , C08F255/08 , C08L31/04 , C08L33/04 , C08L51/06 , C08L69/00 , C09D151/06 , C09J151/06 , C08F4/659 , C08F4/6592
CPC分类号： C08F255/10 , C08F4/65912 , C08F4/65927 , C08F8/00 , C08F8/50 , C08F210/06 , C08F255/023 , C08F255/08 , C08F2800/10 , C08F2810/30 , C08L31/04 , C08L33/04 , C08L51/06 , C08L69/00 , C09D151/06 , C09J151/06 , C08F222/06 , C08F210/08 , C08F2500/02 , C08F2500/20 , C08F212/08 , C08F2220/1858 , C08F220/06 , C08F210/16 , C08K7/14
摘要： The purpose of the present invention is to provide a polar-group-containing propylene-type wax having excellent properties including a low melting point. A modified propylene-(α-olefin) copolymer (A) according to the present invention is produced by grafting at least one compound selected from an unsaturated carboxylic acid, a derivative of the unsaturated carboxylic acid and an unsaturated sulfonic acid salt onto a propylene-(α-olefin) copolymer (A1) and has an acid value of 1 to 100 KOHmg/g, wherein the propylene-(α-olefin) copolymer (A1) comprises 60 to 95 mol % of a propylene-derived constituent unit (a) and 5 to 40 mol % of a constituent unit (b) derived from an α-olefin having 4 or more carbon atoms, and satisfies the specific requirements (i) to (iii).

2. 发明申请

US20180198012A1 ENCAPSULANT FOR PV MODULE, METHOD OF MANUFACTURING THE SAME AND PV MODULE COMPRISING THE SAME (AS AMENDED) 审中-公开
公开(公告)号：US20180198012A1
公开(公告)日：2018-07-12
申请号：US15106645
申请日：2015-02-26
申请人： LG CHEM, LTD.
发明人： Je Sik JUNG , Hyun Cheol KIM , Jung Youn LEE
IPC分类号： H01L31/048 , H01L31/049 , C08J5/18 , C08F255/08 , C08L23/08 , C09J7/30 , C09J123/08
CPC分类号： H01L31/0481 , C08F255/02 , C08F255/08 , C08F2500/11 , C08F2500/12 , C08F2500/26 , C08F2810/30 , C08F2810/40 , C08J5/18 , C08J2323/08 , C08J2323/20 , C08J2423/06 , C08J2423/08 , C08J2451/06 , C08L23/06 , C08L23/0815 , C08L23/16 , C08L23/20 , C08L51/06 , C08L2201/08 , C08L2203/162 , C08L2203/204 , C08L2203/206 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L2207/066 , C08L2310/00 , C09D123/0815 , C09D123/16 , C09J7/30 , C09J123/0815 , C09J123/20 , C09J2203/322 , C09J2205/114 , H01L31/049 , Y02E10/50 , C08F230/08
摘要： The present application relates to an encapsulant for a PV module, a method of manufacturing the same, and a PV module. The encapsulant according to an embodiment of the present application has excellent heat resistance or the like and improved creep properties, exhibits a haze with a certain level or less and excellent optical properties such as transparency or the like, when the encapsulant is applied to a PV module, physical properties such as durability, transparency, or the like are improved, and thus excellent generating efficiency of the PV module may be obtained.

3. 发明授权

US09574040B2 Disentangled ultra high molecular weight polyethylene graft co-polymers and a process for preparation thereof 有权
标题翻译：分离的超高分子量聚乙烯接枝共聚物及其制备方法
公开(公告)号：US09574040B2
公开(公告)日：2017-02-21
申请号：US14427263
申请日：2013-09-10
申请人： RELIANCE INDUSTRIES LIMITED
发明人： Satya Srinivasa Rao Gandham , Ajit Behari Mathur , Uma Sankar Satpathy , Krishna Renganath Sarma , Raksh Vir Jasra
IPC分类号： C08F255/02 , C08F255/10 , C08F255/08
CPC分类号： C08F255/10 , C08F255/02 , C08F255/08 , C08F10/02 , C08F2/36
摘要： In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117° C. to 121° C. and improved decomposition temperature (T100) that ranges between 460° C. to 480° C.
摘要翻译：根据本公开内容，提供了一种用于制备解缠结的超高分子量聚乙烯接枝共聚物的固态接枝共聚方法，其中将解开的超高分子量聚乙烯与至少一种官能单体和自由基引发剂混合以获得混合物; 将由此获得的混合物进行固态聚合，得到解开的超高分子量聚乙烯的接枝共聚物。分离的超高分子量聚乙烯的接枝共聚物显示出在117℃至121℃之间更好的结晶温度和在460℃至480℃之间改进的分解温度（T100）。

4. 发明申请

US20170021535A1 ELECTRON BEAM CURABLE RESIN COMPOSITION, RESIN FRAME FOR REFLECTORS, REFLECTOR, SEMICONDUCTOR LIGHT EMITTING DEVICE, AND METHOD FOR PRODUCING MOLDED BODY 审中-公开
标题翻译：电子束固化树脂组合物，用于反射器的树脂框架，反射器，半导体发光装置和用于制造模制体的方法
公开(公告)号：US20170021535A1
公开(公告)日：2017-01-26
申请号：US15288449
申请日：2016-10-07
申请人： Toshiyuki SAKAI
发明人： Toshiyuki SAKAI
IPC分类号： B29C45/00 , B29C35/08 , C08K3/36 , C08K7/14 , C08F255/08 , C08K3/22
CPC分类号： B29C45/0001 , B29B13/08 , B29C35/0866 , B29C71/04 , B29C2035/0877 , B29K2035/00 , B29K2039/00 , B29K2105/0032 , B29K2105/16 , B29K2509/02 , B29K2509/08 , B29L2012/00 , C08F255/08 , C08K3/22 , C08K3/36 , C08K5/34924 , C08K7/14 , C08K2003/2241 , C08L23/20 , H01L23/296 , H01L31/02167 , H01L33/46 , H01L33/48 , H01L33/501 , H01L33/56 , H01L33/60 , H01L2224/48091 , Y10T428/24273 , H01L2924/00014 , C08L9/00
摘要： Provided are an electron beam curable resin composition including polymethylpentene, and a crosslinking agent, in which the crosslinking agent has a saturated or unsaturated ring structure, at least one atom among atoms forming at least one ring is bonded to any allylic substituent of an allyl group, a methallyl group, an allyl group through a linking group, and a methallyl group through a linking group, and a molecular weight is 1,000 or less, a resin frame for reflectors using the resin composition, a reflector, and a molding method using the resin composition.
摘要翻译：提供一种电子束固化树脂组合物，其包含聚甲基戊烯和交联剂，其中交联剂具有饱和或不饱和环结构，至少一个形成至少一个环的原子中的至少一个原子与烯丙基的任何烯丙基取代基键合，通过连接基团的甲代烯丙基，烯丙基和通过连接基的甲代烯丙基，分子量为1,000以下，使用该树脂组合物的反射体用树脂框，反射体和使用树脂组合物。

5. 发明授权

US09127110B2 Resin composition, and wire and cable using the same 有权
标题翻译：树脂组成，使用电线电缆
公开(公告)号：US09127110B2
公开(公告)日：2015-09-08
申请号：US13474692
申请日：2012-05-17
申请人： Keisuke Sugita , Ryutaro Kikuchi
发明人： Keisuke Sugita , Ryutaro Kikuchi
IPC分类号： C08F255/02 , C08C19/25 , C08F255/08 , C08J3/24 , C08K5/5415 , C08C19/28 , C09D123/08 , C08L51/06 , H01B3/44 , C08K5/5425
CPC分类号： C08F255/02 , C08C19/25 , C08C19/28 , C08F255/08 , C08J3/24 , C08K5/5415 , C08K5/5425 , C08L51/06 , C08L2312/08 , C09D123/0815 , H01B3/441 , C08F230/08
摘要： A resin composition includes a silane-crosslinked polyethylene as a main component provided by crosslinking a polyethylene in the presence of a silanol condensation catalyst and water, the polyethylene being graft-copolymerized with a silane compound by a free radical generating agent. The polyethylene has a density of 0.87 to 0.91 g/cm3. The silane compound is included not less than 2 parts by mass relative to 100 parts by mass of the polyethylene. The resin composition includes silicon detected by a fluorescence X-ray at a rate of not less than 0.3 mass % and has a gel fraction of not less than 70%. A mass ratio of the silane compound to the free radical generating agent is not less than 35 and not more than 150.
摘要翻译：树脂组合物包括硅烷交联聚乙烯作为主要组分，其通过在硅烷醇缩合催化剂和水的存在下交联聚乙烯，所述聚乙烯通过自由基生成剂与硅烷化合物接枝共聚。聚乙烯的密度为0.87〜0.91g / cm 3。相对于100质量份的聚乙烯，硅烷化合物的含量不得少于2质量份。树脂组合物包含通过荧光X射线以不小于0.3质量％的速率检测并具有不小于70％的凝胶分数的硅。硅烷化合物与自由基发生剂的质量比不小于35且不大于150。

6. 发明申请

US20140370316A1 ADHESIVE COMPOSITION AND IMAGE DISPLAY DEVICE USING SAME 有权
标题翻译：胶粘组合物和图像显示装置使用相同
公开(公告)号：US20140370316A1
公开(公告)日：2014-12-18
申请号：US14344382
申请日：2012-09-27
申请人： Mitsui Chemicals, Inc.
发明人： Yasushi Mizuta , Toshikazu Gomi
IPC分类号： C09J133/08 , C09J5/00 , G02F1/1333
CPC分类号： C09J133/08 , C08F220/18 , C08F222/1006 , C08F255/08 , C08F257/02 , C08K5/0025 , C09J4/06 , C09J5/00 , C09J11/06 , C09J11/08 , C09J151/003 , C09J2433/00 , G02F1/1333 , G02F2202/28 , Y10T428/31935 , C08F2220/1883
摘要： The present invention provides an adhesive composition which has a cured product exhibiting high transparency and a high refractive index, and which has high adhesive strength and experiences little reduction in the adhesive strength, even when exposed to high temperatures. In order to achieve the above the adhesive composition includes: (1) a hydrocarbon polymer having a total light transmittance of visible light, as measured according to JIS K7361-1, of at least 80%; (2) at least one kind of (meth)acrylic monomer selected from a mono(meth)acrylic monomer having one (meth)acrylic group in a molecule and a di(meth)acrylic monomer having two (meth)acrylic groups in a molecule; and (3) a photoinitiator; wherein 30-190 parts by weight of component (2) are included relative to 100 parts by weight of component (1).
摘要翻译：本发明提供一种具有高透明度，高折射率的固化物的粘合剂组合物，即使暴露在高温下，也具有高的粘合强度和几乎不降低粘合强度的粘合剂组合物。为了实现上述目的，粘合剂组合物包括：（1）根据JIS K7361-1测量的具有总可见光透射率的烃聚合物为至少80％; （2）至少一种选自分子中具有一个（甲基）丙烯酸基的单（甲基）丙烯酸单体和分子中具有两个（甲基）丙烯酸基的二（甲基）丙烯酸单体）的（甲基）丙烯酸单体 ; 和（3）光引发剂; 相对于100重量份组分（1），包含30-190重量份的组分（2）。

7. 发明授权

US08569417B2 Modified polyolefins 有权
标题翻译：改性聚烯烃
公开(公告)号：US08569417B2
公开(公告)日：2013-10-29
申请号：US13001668
申请日：2009-07-02
申请人： Michael Backer , Francois De Buyl , Valerie Smits , Damien Deheunynck
发明人： Michael Backer , Francois De Buyl , Valerie Smits , Damien Deheunynck
IPC分类号： C08F255/00 , C08F255/02 , C08F8/12 , C08F8/42
CPC分类号： C08F255/00 , C08F255/02 , C08F255/08 , C08L51/06 , C08L2666/02 , C09D151/06 , C09J151/06
摘要： The invention relates to a process for grafting hydrolysable silane groups to a polyolefin in which ethylene units, if present, form less than 50% by weight of the total polyolefin. The polyolefin is reacted with an unsaturated silane, having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polyolefin. The unsaturated silane has the formula R″—CH═CH—Z (I) or R″—C≡C—Z (II) in which Z represents an electron-withdrawing moiety substituted by a —SiRaR′(3-a) group wherein R represents a hydrolysable group; R′ represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; and R″ represents hydrogen or a group having an electron withdrawing or any other activation effect with respect to the —CH═CH— or —C≡C— bond. The use of an unsaturated silane of the formula R″—CH═CH—Z (I) or R″—C≡C—Z (II) in carrying out the grafting reaction on the polyolefin may give enhanced grafting yield compared to grafting with an olefinically unsaturated silane such as vinyltrimethoxysilane not containing an electron withdrawing moiety Z. The invention permits to provide a silane-modified polyolefin having a high grafting efficiency while limiting/preventing polymer degradation by chain scission. The silane-modified polyolefin can be further reacted with a polar surface, a filler or a polar polymer or reacted on itself to crosslink the polyolefin and obtain enhanced physical properties of the composites made thereof.
摘要翻译：本发明涉及一种将可水解硅烷基接枝到聚烯烃上的方法，其中乙烯单元（如果存在的话）占总聚烯烃的小于50重量％。在能够在聚烯烃中产生自由基位点的手段的存在下，聚烯烃与不饱和硅烷反应，所述不饱和硅烷具有与Si结合的至少一个可水解基团或其水解产物。不饱和硅烷具有式R“-CH = CH-Z（I）或R”C = CZ（II），其中Z表示被-SiRaR'（3-a）基团取代的吸电子部分其中R表示可水解基团; R'表示碳原子数1〜6的烃基。 a的值在1到3的范围内; R“表示氢或相对于-CH = CH-或-C = C-键具有吸电子或任何其它活化作用的基团。在聚烯烃上进行接枝反应时，使用式R'-CH = CH-Z（I）或R“C = CZ（II）的不饱和硅烷可以提高接枝率，烯属不饱和硅烷如不含吸电子部分Z的乙烯基三甲氧基硅烷。本发明允许提供具有高接枝效率的硅烷改性聚烯烃，同时通过链断裂限制/防止聚合物降解。硅烷改性的聚烯烃可以进一步与极性表面，填料或极性聚合物反应，或者自身反应以使聚烯烃交联并获得由其制成的复合材料的增强的物理性能。

8. 发明申请

US20120292077A1 RESIN COMPOSITION, AND WIRE AND CABLE USING THE SAME 有权
标题翻译：树脂组合物，使用它的电线和电缆
公开(公告)号：US20120292077A1
公开(公告)日：2012-11-22
申请号：US13474692
申请日：2012-05-17
申请人： Keisuke SUGITA , Ryutaro KIKUCHI
发明人： Keisuke SUGITA , Ryutaro KIKUCHI
IPC分类号： C08F255/02 , H01B3/44
CPC分类号： C08F255/02 , C08C19/25 , C08C19/28 , C08F255/08 , C08J3/24 , C08K5/5415 , C08K5/5425 , C08L51/06 , C08L2312/08 , C09D123/0815 , H01B3/441 , C08F230/08
摘要： A resin composition includes a silane-crosslinked polyethylene as a main component provided by crosslinking a polyethylene in the presence of a silanol condensation catalyst and water, the polyethylene being graft-copolymerized with a silane compound by a free radical generating agent. The polyethylene has a density of 0.87 to 0.91 g/cm3. The silane compound is included not less than 2 parts by mass relative to 100 parts by mass of the polyethylene. The resin composition includes silicon detected by a fluorescence X-ray at a rate of not less than 0.3 mass % and has a gel fraction of not less than 70%. A mass ratio of the silane compound to the free radical generating agent is not less than 35 and not more than 150.
摘要翻译：树脂组合物包括硅烷交联聚乙烯作为主要组分，其通过在硅烷醇缩合催化剂和水的存在下交联聚乙烯，所述聚乙烯通过自由基生成剂与硅烷化合物接枝共聚。聚乙烯的密度为0.87〜0.91g / cm 3。相对于100质量份的聚乙烯，硅烷化合物的含量不得少于2质量份。树脂组合物包含通过荧光X射线以不小于0.3质量％的速率检测并具有不小于70％的凝胶分数的硅。硅烷化合物与自由基发生剂的质量比不小于35且不大于150。

9. 发明授权

US07732547B2 Fluorinated cyclic olefinic graft polymer 有权
标题翻译：氟化环烯烃接枝聚合物
公开(公告)号：US07732547B2
公开(公告)日：2010-06-08
申请号：US11776554
申请日：2007-07-12
申请人： Jen-Luan Chen , Dar-Ming Chiang , Wen-Liang Liu
发明人： Jen-Luan Chen , Dar-Ming Chiang , Wen-Liang Liu
IPC分类号： C08F36/16
CPC分类号： C08F277/00 , C08F8/24 , C08F255/00 , C08F255/02 , C08F255/08 , C08F255/10 , C08L23/02 , C08L51/06 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： The present invention provides a graft polymer and compositions comprising a cyclic olefin polymer characterized by having a glass transition temperature of about 60° C. to 250° C. and a molecular weight of about 400 to 300000, and a fluorocarbon alkyl group grafted on the cyclic olefin polymer.
摘要翻译：本发明提供一种接枝聚合物和包含环状烯烃聚合物的组合物，其特征在于玻璃化转变温度为约60℃至250℃，分子量为约400至300000，并且接枝在环烯烃聚合物。

10. 发明申请

US20100063200A1 AQUEOUS ROMP-BASED MONOLITH MATERIALS AND METHODS FOR MAKING 有权
标题翻译：基于ROMP的单组分材料及其制备方法
公开(公告)号：US20100063200A1
公开(公告)日：2010-03-11
申请号：US12207055
申请日：2008-09-09
申请人： Su Lu , Liangliang Qiang , Yanrong Zhu , Zhida Pan
发明人： Su Lu , Liangliang Qiang , Yanrong Zhu , Zhida Pan
IPC分类号： C08L55/00 , B01J31/12
CPC分类号： C08F290/00 , B01J20/28042 , B01J20/286 , B01J20/288 , C08F255/00 , C08F255/08 , C08F277/00 , C08F290/06 , C08F291/00 , C08G61/08 , C08L51/003 , C08L51/06 , G01N2030/528 , C08L2666/02
摘要： A water soluble ROMP catalyst, which has high catalytic efficiency for ring opening metathesis is use in the preparation of polymeric blends for use in monolithic columns. In one embodiments a method for making a polymeric blend is discolosed comprising reaction of a water-soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor, and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support. In another embodiment a monolithic bed is disclosed comprising the water-soluble ROMP catalyst immobilized on a surface of a solid support. Also disclosed is a monolithic bed comprising: a polymer blend, the polymer blend produced from contacting a water soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor; and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support.
摘要翻译：对于开环复分解具有高催化效率的水溶性ROMP催化剂用于制备用于整体柱的聚合物共混物。在一个实施方案中，制造聚合物共混物的方法被解开，包括水溶性ROMP催化剂与降冰片烯取代的环烯烃聚合物或聚降冰片烯聚合物前体的反应，并且其中所述接触在水溶液或极性溶剂中，在坚实的支持。在另一个实施方案中，公开了一种整体床，其包含固定在固体载体表面上的水溶性ROMP催化剂。还公开了一种整体床，包括：聚合物共混物，通过使水溶性ROMP催化剂与降冰片烯取代的环烯烃聚合物或聚降冰片烯聚合物前体接触而制备的聚合物共混物; 并且其中所述接触在固体载体存在下在水性或极性溶剂中进行。

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