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    • 67. 发明申请
    • Multilayer oriented antimicrobial and antifogging films
    • 多层定向抗菌防雾膜
    • US20050158537A1
    • 2005-07-21
    • US10512297
    • 2003-04-17
    • Oktay AralCumbur BuyukakinciZakir Rzaev
    • Oktay AralCumbur BuyukakinciZakir Rzaev
    • A01N25/34B32B27/08B32B27/16B32B27/18B32B27/32C08L23/10C08L23/14
    • B32B27/18A01N25/34B32B27/32B32B37/153B32B38/0008B32B2307/31B32B2307/518B32B2307/7145B32B2307/75B32B2310/14B32B2439/70C08L23/10C08L23/142Y10S428/91Y10T428/26Y10T428/265Y10T428/266Y10T428/2817Y10T428/2826Y10T428/31855Y10T428/31909Y10T428/31913C08L2666/06A01N59/16A01N25/10
    • Antimicrobial and antifogging polymeric films with preferable A/C/E structure useful for the food, medicine and agriculture applications as well as for other general packaging and non-traditional special applications. More preferably, animicrobial and antifogging films having a A/B/C/E structure. Most preferably, antimicrobial and antifogging films having a A/B/C/D/E structure. A multilayer structure (having at least an skin layer (A) having antifogging and antimicrobial properties/a core layer (C)/an outer layer (E) structure) for semi and biaxially oriented polyolefin based antifogging films having advantageous properties as compared with known and commercial films such as low values of haze, high values of sheen, lower longitudinal and transverse shrinkage, which provides high dimensional stability, and excellent antifogging and antimicrobial properties. Preferably the skin layer (A), having antifogging and antimicrobial properties, is electrical corona or flame treated. Electrical corona or flame treatment of the outer layer (E) may enhance ink anchorage and increase the printability of this layer. Preferably, the films comprise an inner (B) layer between the skin layer (A) and the core layer (C). Preferably, the films may comprise a second inner (D) layer between the outer (E) layer and the core layer (C).
    • 具有优选A / C / E结构的抗微生物和防雾聚合物膜,适用于食品,医药和农业应用以及其他一般包装和非传统特殊应用。 更优选具有A / B / C / E结构的抗微生物和防雾膜。 最优选具有A / B / C / D / E结构的抗微生物和防雾膜。 一种多层结构(至少具有防雾和抗菌性能的表层(A)/芯层(C)/外层(E)结构),其与已知的相比具有优势的半双轴取向聚烯烃防雾膜 和商业膜,例如雾度值低,光泽度高,纵向和横向收缩较低,提供高尺寸稳定性,以及优异的防雾和抗菌性能。 优选地,具有防雾和抗微生物性质的皮肤层(A)是电晕或火焰处理的。 外层(E)的电晕或火焰处理可以增强油墨的粘附力并增加该层的印刷性。 优选地,膜包括在表皮层(A)和芯层(C)之间的内层(B)层。 优选地,膜可以包括在外(E)层和芯层(C)之间的第二内(D)层。
    • 68. 发明授权
    • Encapsulated barrier for flexible films and a method of making the same
    • 柔性膜的封装屏障及其制造方法
    • US06911244B2
    • 2005-06-28
    • US10325002
    • 2002-12-20
    • Robert J. BlembergGregory L. PetkovsekChad M. Perre
    • Robert J. BlembergGregory L. PetkovsekChad M. Perre
    • B32B7/02B32B7/12B32B3/02
    • B32B7/02B32B7/12Y10S428/91Y10T428/1383Y10T428/239Y10T428/31743Y10T428/31928
    • The present invention relates to a film structure and a method of manufacturing the same. More specifically, the film structure may include a barrier material made from EVOH, nylon or other thermally sensitive barrier material encapsulated by a first adhesive material. The barrier material and the first adhesive material form a barrier layer and a first set of adhesive layers when coextruded. The barrier layer and the first set of adhesive layers may be coextruded at the same or a similar temperature to form a first extrudate. The extrudate may be encapsulated by or otherwise coextruded with a second adhesive material to form a second extrudate at a higher temperature than the first extrudate that then may be formed into a flat sheet via a die. The first set of adhesive layers protects the barrier layer from high temperatures and long residence times related to the coextrusion/lamination process that may degrade the barrier layer. In addition, acid terpolymer consisting of ethylene/methyl acrylate/acrylic acid adheres a barrier material of EVOH to outer layers of the film structure.
    • 膜结构及其制造方法技术领域本发明涉及膜结构及其制造方法。 更具体地,膜结构可以包括由EVOH,尼龙或由第一粘合剂材料包封的其它热敏阻挡材料制成的阻挡材料。 当共挤出时,阻挡材料和第一粘合材料形成阻挡层和第一组粘合剂层。 阻挡层和第一组粘合剂层可以在相同或相似的温度下共挤出以形成第一挤出物。 挤出物可以用第二粘合剂材料包封或以其它方式共挤出,以在比可以通过模具形成平板的第一挤出物更高的温度下形成第二挤出物。 第一组粘合剂层保护阻隔层不受高温和长时间停留时间的影响,共挤出/层压过程可能会降低阻挡层。 此外,由乙烯/丙烯酸甲酯/丙烯酸组成的酸性三元共聚物将EVOH的阻隔材料粘合到膜结构的外层。