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    • 70. 发明授权
    • Metallizing of plastic substrata
    • 金属化塑料基材
    • US4590115A
    • 1986-05-20
    • US449183
    • 1982-12-13
    • Robert Cassat
    • Robert Cassat
    • C23C18/16C23C18/18C23C18/20C23C18/30C23C18/31C23C18/40C23C18/44C23C18/50C25D5/56H05K3/18
    • C25D5/56C23C18/1641C23C18/2013C23C18/206H05K3/188Y10T428/24628
    • Plastic substrata are metallized, preferably by direct electrolytic metallization, by (i) providing a plastic shaped article comprising intimate admixture of a polymeric resin and a plurality of small metallic filler particles of a non-conductive oxide of a non-noble metal uniformly dispersed therethrough, at least one of the face surfaces of said shaped article having exposed thereon such high density of said metallic filler particles as to provide in step (ii) metallization growth nuclei adapted for direct electrolytic metallization; (ii) next subjecting said at least one face surface of said plastic shaped article to the action of a reducing agent to essentially quantitatively convert the non-conductive metal oxide filler particles to conductive free metal, metallization growth nuclei; and (iii) thence electrochemically and/or electrolytically metallizing the at least one reduced face surface of said plastic shaped article with a free metal deposit.
    • 通过(i)提供塑料成型制品,其包括聚合物树脂和非均匀分散在其中的非贵金属的非导电氧化物的多个小的金属填料颗粒,包括聚合物树脂的密集混合物,塑性基质金属化,优选通过直接电解金属化 所述成形制品的至少一个表面在其上暴露有如此高密度的所述金属填料颗粒,以在步骤(ii)中提供适于直接电解金属化的金属化生长核; (ii)接下来经历所述塑料成型制品的所述至少一个表面表面的还原剂的作用以基本上定量地将非导电金属氧化物填料颗粒转化为导电的游离金属,金属化生长核; 和(iii)然后用游离金属沉积物电化学和/或电解金属化所述塑料成形制品的至少一个还原表面。