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    • 66. 发明授权
    • Production of oriented fibrillar products
    • 生产定向纤维制品
    • UST969008I4
    • 1978-04-04
    • US784630
    • 1977-04-04
    • Frederic Neil CogswellJiri George Tomka
    • Frederic Neil CogswellJiri George Tomka
    • D01D5/098B29C47/00B29C47/94C08G73/08D01D5/40
    • B29C47/94B29C47/0004B29C47/0021B29C47/0026B29C47/003B29K2079/00B29K2105/0079B29K2105/04B29K2995/0051C08G73/08Y10S264/47
    • the process for the production of an oriented fibrillar product from a polyarylene-oxadiazole which is heat-softenable without substantial degradation when in an air-free inert atmosphere comprises extruding contiguously disposed particles of the polymer, which particles are heat-softened but non-molten and are blanketed in an air-free atmosphere of an inert fluid, through a die to produce a substantially non-degraded oriented fibrillar product. Means are provided, if necessary, to substantially prevent relaxation of the orientation resulting from the extrusion.Particularly preferred polyarylene-oxadiazoles for use according to the process are the amorphous and non-crystallizable copolymeric polyphenylene-1,3,4-oxadiazoles having the characteristic repeating units ##STR1## where R.sub.1 is a p-phenylene radical, R.sub.2 is a m-phenylene radical, the ratio of R.sub.1 radicals to R.sub.2 radicals is within the range 60/40 to 10/90, and the R.sub.1 and/or R.sub.2 radicals are sufficiently substituted with bulky groups such as bromine atoms to inhibit crystallisation of the polymer.Preferably steam and/or water is the protective fluid and is derived from water associated with the polymer particles, the steam being formed by vaporization of the water during extrusion. The particles are usually in the form of a wet cake. The associated water may be present only as surface water (which has not significantly penetrated into the particles) or as water which has significantly penetrated into the polymer particles prior to extrusion. The use of liquid-interpenetrated particles is advantageous in that the vapor and/or compressed liquid provides a high pressure which provides a driving force for the extrusion and also the interpenetrated liquid flashes off from the extrudate leaving the die thereby rapidly cooling the extrudate throughout its thickness and freezing in the orientation.The extrusion product is an attractive paper-like tape, ribbon or sheet comprised of very stiff fibrils and is usually rather porous. The product can be used as such, or when coextruded with other stiff fiber-forming polymers to obtain a highly reinforced extrudate. The fibrous extrudate can also be used as a base within the interstices of which other monomers may be polymerized.
    • 67. 发明授权
    • Process for the production of polyolefin fibers
    • 生产聚烯烃纤维的方法
    • US4069287A
    • 1978-01-17
    • US708067
    • 1976-07-23
    • Joseph AboulafiaRichard Le FustecClaude Schranz
    • Joseph AboulafiaRichard Le FustecClaude Schranz
    • D01D5/40D21F11/00
    • D01D5/40D21H13/14D21H5/202
    • A process and apparatus for manufacturing polyolefin fibers from a composition of the said polyolefins dissolved in a diluent, by subjecting the composition to flow at a velocity above a critical value in a tube or bundle of tubes, the temperature of the composition being within the range of critical temperatures of the said composition over at least a portion of the length of the tube or bundle of tubes and separating the fibers from the liquid diluent. The critical temperature range is below the temperature of solution of the polyolefin in the molten state in a diluent and is more specifically the range of temperatures in which the polyolefin remains in dissolved condition when the solution mixture is maintained at rest but precipitates when the mixture is subjected to certain disturbances such as, for instance, shearing. This typically is between 70.degree. and 130.degree. C. The lower limits of the critical velocity and the critical temperature are determined by the appearance of undesired powder co-precipitating with the fibers.In a variation the composition contains fibrous material (e.g. cellulose) insoluble in the diluent, yielding an interlaced fiber mix (useful in paper making, among other things).In a further improvement to avoid formation of "nodules" (i.e. random agglomerations of fibers), said tube(s) is provided with at least one restriction decreasing the cross-section of the tube(s); e.g. by a diaphragm, conical nozzle, very short inner tube, etc.
    • 通过使组合物在管或管束中以高于临界值的速度流动,从溶解在稀释剂中的所述聚烯烃的组合物制造聚烯烃纤维的方法和装置,组合物的温度在该范围内 所述组合物在管或管束的至少一部分长度上的临界温度,并将纤维与液体稀释剂分离。 临界温度范围低于稀释剂中熔融状态下聚烯烃溶液的温度,更具体地说,当溶液混合物保持静止时聚烯烃保持溶解状态的温度范围,当混合物为 受到某些扰动,例如剪切。 这通常在70°和130°C之间。临界速度和临界温度的下限是由与纤维共沉淀的不需要的粉末的外观决定的。