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    • 71. 发明授权
    • Heat sensitive recording sheet
    • 热敏记录纸
    • US4839334A
    • 1989-06-13
    • US2235
    • 1987-01-12
    • Toshiyuki AbeKatsumasa KikkawaMichihiro GondaHideyuki SensuiMikiko Kanasugi
    • Toshiyuki AbeKatsumasa KikkawaMichihiro GondaHideyuki SensuiMikiko Kanasugi
    • B41M5/327
    • B41M5/3275Y10S428/913Y10T428/24876Y10T428/31866
    • A heat sensitive recording sheet having a heat sensitive color forming layer wherein a mixture of fluoran compounds of the following formulas I and II is used as a color former; ##STR1## wherein R.sub.1 is a hydrogen atom, an alkyl group having from 1 to 8 carbon atoms, a tetrahydrofurfuryl group, a substituted or unsubstituted phenyl group or a cycloalkyl group, R.sub.2 is a hydrogen atom, a chlorine atom, a fluorine atom, a lower alkyl group, a lower alkoxy group, a lower alkoxyalkyl group, a phenyl group or a benzyl group, and R.sub.3 is a hydrogen atom, a chlorine atom, a fluorine atom, a bromine atom, a lower alkyl group or an acyl group; and ##STR2## wherein each of R.sub.4 and R.sub.5 is a hydrogen atom, an alkyl group having from 1 to 8 carbon atoms, a substituted or unsubstituted phenyl group or a cycloalkyl group, or R.sup.4 and R.sub.5 may, together with the adjacent nitrogen atom, form a ring of the formula ##STR3## each of R.sub.6 and R.sub.7 is a hydrogen atom, a chlorine atom, a fluorine atom, a bromine atom, a lower alkyl group, a lower alkoxy group, a lower alkoxyalkyl group, a phenyl group or a benzyl group, and R.sub.8 is a hydrogen atom, a chlorine atom, a fluorine atom, a bromine atom, a lower alkyl group or an acyl group.
    • 一种具有热敏颜色形成层的热敏记录片,其中使用下列通式I和II的荧烷化合物的混合物作为着色剂; (I)其中R1是氢原子,具有1至8个碳原子的烷基,四氢糠基,取代或未取代的苯基或环烷基,R2是氢原子,氯原子, 氟原子,低级烷基,低级烷氧基,低级烷氧基烷基,苯基或苄基,R3为氢原子,氯原子,氟原子,溴原子,低级烷基或 酰基; 和其中R 4和R 5各自为氢原子,具有1至8个碳原子的烷基,取代或未取代的苯基或环烷基,或R 4和R 5可以与相邻的 氮原子形成下式的环,其中R6和R7各自为氢原子,氯原子,氟原子,溴原子,低级烷基,低级烷氧基,低级烷氧基烷基,低级烷氧基 苯基或苄基,R 8为氢原子,氯原子,氟原子,溴原子,低级烷基或酰基。
    • 73. 发明授权
    • Xanthene derivative and a production process of the same
    • 呫吨衍生物及其制备方法相同
    • US4749796A
    • 1988-06-07
    • US805699
    • 1985-12-06
    • Hideyuki SensuiMichihiro GondaToshio Obara
    • Hideyuki SensuiMichihiro GondaToshio Obara
    • C07B61/00C07D311/82G03C1/00G03C1/675G03F7/004G03F7/105
    • G03F7/105C07D311/82
    • This invention relates to a xanthene derivative that develops color on oxidation, so that it is favorably used for a photoresist, a PS plate or a proofing agent. The xanthene derivative, which has the following structural formula (I), is produced by putting a fluoran derivative represented by the following structural formula (II) to an esterification reaction and then to a reduction reaction. ##STR1## In the above formulae R.sub.1 and R.sub.2 independently stand for hydrogen, an alkyl radical with 1 to 8 carbon atoms, a tetrahydrofurfuryl radical, a substitued or an unsubstituted phenyl radical, a substituted or an unsubstituted benzyl radical or a cyclic alkyl radical; in addition, R.sub.1 and R.sub.2 are able to form a ring in pairs. R.sub.3 and R.sub.6 independently stand for hydrogen, chlorine, fluorine, a lower alkyl radical or a lower alkoxy radical. R.sub.4 and R.sub.5 independently stand for hydrogen, chlorine, fluorine, a lower alkyl radical, a lower alkoxy radical, a lower alkoxyalkyl radical, a substituted or an unsubstituted phenyl radical, a substituted or an unsubstituted benzyl radical, an amino radical, a N-substituted or N,N-substituted amino radical or a cyclic alkyl radical; in addition, R.sub.3 and R.sub.4, R.sub.4 and R.sub.5, and R.sub.5 and R.sub.6 are able to form a ring in pairs respectively. R.sub.7 stands for an alkyl radical, a substituted or an unsubstituted phenyl radical or a substituted or an unsubstituted benzyl radical. X stands for hydrogen, chlorine, fluorine, bromine, a nitro radical, a lower alkyl radical or a lower alkylamino radical; and n stands for an integer from 1 to 4 inclusive.
    • 本发明涉及在氧化时显色的呫吨衍生物,因此有利地用于光致抗蚀剂,PS板或校样剂。 具有以下结构式(I)的呫吨衍生物通过将由下列结构式(II)表示的荧烷衍生物置于酯化反应中进行还原反应来制备。 (II)在上述式中,R 1和R 2分别代表氢,具有1至8个碳原子的烷基,四氢糠基,取代或未取代的苯基,取代或 未取代的苄基或环状烷基; 此外,R1和R2能够成对形成环。 R3和R6独立地代表氢,氯,氟,低级烷基或低级烷氧基。 R4和R5独立地代表氢,氯,氟,低级烷基,低级烷氧基,低级烷氧基烷基,取代或未取代的苯基,取代或未取代的苄基,氨基, 取代或N,N-取代的氨基或环状烷基; 另外,R 3和R 4,R 4和R 5以及R 5和R 6可以分别成对形成环。 R7代表烷基,取代或未取代的苯基或取代或未取代的苄基。 X代表氢,氯,氟,溴,硝基,低级烷基或低级烷基氨基; n表示1〜4的整数。