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71. 发明申请

US20040152815A1 High speed spinning procedures for the manufacture of low denier polypropylene fibers and yarns 审中-公开
标题翻译：用于制造低旦尼尔聚丙烯纤维和纱线的高速纺丝方法
公开(公告)号：US20040152815A1
公开(公告)日：2004-08-05
申请号：US10295697
申请日：2002-11-17
发明人： Brian G. Morin , Martin E. Cowan
IPC分类号： C08K005/06
CPC分类号： D01F6/06 , D01F1/10
摘要： Improvements in permitting greater efficiency for low denier polypropylene fiber and yarn production are provided. Generally, spinning speeds are limited for polypropylene fibers and yarns as such materials tend to break easily upon exposure to excessively high tensions associated with low- to medium-spinning speeds. Low production speeds negatively impact the economics of producing such low denier fibers which prevents the widespread utilization of such fibers and yarns in various end-use applications, particularly applications for which low denier provides desirable hand characteristics. Thus, it has surprisingly been determined that such low denier manufactured fibers and yarns can be produced with certain nucleating additives that permit high tension levels in the quench stack as required for high-speed spinning procedures to be followed. Additionally, low-shrink and/or better resiliency properties are also available with the addition of such nucleating compounds within the target low denier polypropylene resins.
摘要翻译：提供了提高低旦尼尔聚丙烯纤维和纱线生产效率的改进措施。通常，纺丝速度对于聚丙烯纤维和纱线是有限的，因为这样的材料在暴露于与低至中等纺丝速度相关的过高的张力时容易破裂。低生产速度对生产这种低旦尼尔纤维的经济性产生负面影响，这阻止了各种最终用途应用中的这种纤维和纱线的广泛利用，特别是低旦尼尔提供了所需的手部特性的应用。因此，令人惊讶地确定，这种低旦尼尔制造的纤维和纱线可以用特定的成核添加剂生产，这些成核添加剂允许淬火堆叠中的高张力水平，以便遵循高速纺丝方法的要求。此外，在目标低旦尼尔聚丙烯树脂中加入这种成核化合物，也可获得低收缩和/或更好的弹性性能。

72. 发明申请

US20040096639A1 Uniform production methods for colored and non-colored polypropylene fibers 审中-公开
标题翻译：彩色和无色聚丙烯纤维的均匀生产方法
公开(公告)号：US20040096639A1
公开(公告)日：2004-05-20
申请号：US10295441
申请日：2002-11-16
发明人： Brian G. Morin , Martin E. Cowan , Joseph R. Royer
IPC分类号： B32B005/12 , D03D015/00 , D03D025/00 , B32B027/02 , B32B027/04 , B32B027/12 , D04H001/00 , D04H003/00 , D04H005/00 , D04H013/00
CPC分类号： D01F6/06 , D01F1/04 , D01F1/06 , D01F1/10 , Y10T428/24058 , Y10T428/249947 , Y10T442/3171 , Y10T442/60 , Y10T442/607 , Y10T442/629
摘要： Improvements in color management for polypropylene fiber production in terms of permitting similar if not identical processing conditions for both colored and uncolored fiber production are provided. Generally, either separate polypropylene fiber manufacturing lines or different processing conditions on the same manufacturing line are required for the production of colored and non-colored polypropylene fibers. This coloring is, for example, done by using pigments that may have a nucleation effect on the PP polymer which affects fiber properties. Such an inefficient situation exists due to the physical properties of drawn polypropylene fibers during manufacture, particularly the different properties exhibited between fibers including color and fibers that are colorless. Thus, it has been determined that specific additives can permit substantially identical fiber processing conditions (such as temperature and draw ratios, as examples) for colored and non-colored polypropylene fibers, providing greater efficiency to the manufacturer when switching between such fiber types is elected and/or necessary.
摘要翻译：提供了对于聚丙烯纤维生产的色彩管理方面的改进，对于有色和未着色的纤维生产而言，允许类似的，即使不相同的加工条件。通常，在生产有色和无色聚丙烯纤维时，需要在同一生产线上分开的聚丙烯纤维生产线或不同的加工条件。例如，这种着色是通过使用可能对影响纤维性能的PP聚合物具有成核作用的颜料来完成的。由于制造过程中拉伸的聚丙烯纤维的物理特性，特别是包括颜色的纤维和无色纤维之间的不同性能，存在这种低效率的情况。因此，已经确定，特定的添加剂可以允许用于着色和无色聚丙烯纤维的基本上相同的纤维加工条件（例如温度和拉伸比，作为实例），当选择这种纤维类型之间切换时，为制造商提供更高的效率和/或必要。

73. 发明申请

US20040096621A1 High denier textured polypropylene fibers and yarns 审中-公开
标题翻译：高旦尼尔织构的聚丙烯纤维和纱线
公开(公告)号：US20040096621A1
公开(公告)日：2004-05-20
申请号：US10295747
申请日：2002-11-17
发明人： Weihua Sonya Dai , Brian G. Morin
IPC分类号： B32B033/00 , D01D005/22 , D02G003/02
CPC分类号： D01F1/10 , D01F6/06 , D02G3/445 , Y10T428/23993 , Y10T428/2922 , Y10T428/2967
摘要： Improvements in creating resilient high denier polypropylene yarns are provided. Generally, high denier polypropylene yarns exhibit poor resiliency (such as crush resistance, for example, when utilized as carpet face yarns) that effectively prevents widespread use in articles that require high degrees of resiliency. As a result, higher cost, but more resilient, yarns, such as polyesters or polyamides, have found greater acceptance in such end-use articles. Furthermore, previous attempts at texturing high denier polypropylene fibers have failed to attain suitable resilience levels therein is insufficient to permit proper return to initial shape and/or length after impact. It has now surprisingly been determined that such high denier polypropylene yarns can be produced with certain nucleating additives that permit requisite degrees of shape and length retention, and thus acceptable resilience levels to permit cost-effective replacement of more expensive polyester or polyamide yarns in certain end-use applications.
摘要翻译：提供了创造弹性高旦尼尔聚丙烯纱线的改进。通常，高旦尼尔聚丙烯纱线具有较差的弹性（例如抗碎性，例如当用作地毯面纱时），其有效地防止需要高度弹性的制品中广泛使用。因此，更高的成本，但更具弹性的纱线，例如聚酯或聚酰胺，已经在这种最终用途制品中得到更多的接受。此外，先前对高旦尼尔聚丙烯纤维进行纹理化的尝试未能达到合适的回弹水平不足以允许在冲击后适当地恢复初始形状和/或长度。现在令人惊讶地确定，这种高旦尼尔聚丙烯纱线可以用某些成核添加剂生产，这些成核添加剂允许形状和长度保持必需的程度，因此可以获得可接受的回弹水平，以允许在某些方面成本有效地更换更昂贵的聚酯或聚酰胺纱线 - 使用应用程序。

74. 发明申请

US20040082750A1 Films comprising isotactic propylene copolymers 有权
标题翻译：包含全同立构丙烯共聚物的膜
公开(公告)号：US20040082750A1
公开(公告)日：2004-04-29
申请号：US10641978
申请日：2003-08-15
发明人： Li-Min Tau , Pak-Wing S. Chum , Seema Karande , Clive Bosnyak
IPC分类号： C08F110/00
CPC分类号： C08J5/18 , B32B27/32 , C07B2200/11 , C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08J2323/12 , C08J2323/14 , C08J2367/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/147 , C08L23/16 , C08L101/00 , C08L2205/02 , C08L2314/06 , C09K3/10 , C09K2200/0617 , C09K2200/062 , D01F6/06 , D01F6/30 , D01F6/46 , Y10T428/31909 , C08F4/659 , C08F4/65904 , C08F4/64144 , C08L2666/04 , C08L2666/06 , C08F2500/12 , C08F2500/20 , C08F2500/15 , C08F2500/24 , C08F2500/26 , C08F2500/03 , C08F2500/08 , C08F2/001
摘要： Films with excellent machine direction (MD) tear properties comprise at least one layer made from a polymer comprising: (A) at least 50 weight percent (wt %) propylene; and (B) at least 5 wt % ethylene and/or one or more unsaturated comonomers. Representative of component (B) unsatuarated comonomers are the C4-20 null-olefins, C4-20 dienes, styrenic compounds, and the like. Preferably, the film has at least one of a (i) haze value of less than about 10, (ii) 45 degree gloss of greater than about 65, and (iii) dart value of greater than about 100 g/mil. In one preferred embodiment, the layer comprises a compolymer characterized as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about null1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译：具有良好机器方向（MD）撕裂性能的膜包括由聚合物制成的至少一层，包括：（A）至少50重量％（wt％）丙烯; 和（B）至少5重量％的乙烯和/或一种或多种不饱和共聚单体。组分（B）不饱和共聚单体的代表是C4-20α-烯烃，C4-20二烯，苯乙烯类化合物等。优选地，膜具有小于约10的（i）雾度值，（ii）大于约65的45度光泽度和（iii）大于约100g / mil的飞镖值中的至少一种。在一个优选的实施方案中，该层包含特征在于具有以下特性中的至少一个的共聚物：（i）对应于在约14.6和约15.7ppm的区域误差的13 C NMR峰，约等于强度的峰，（ii）当共聚单体含量（即源自乙烯和/或不饱和共聚单体的单元）的共聚物的单元为至少约3重量％时，大于约1.4的B值，（iii）偏度指数，6，大于约-1.20，（iv）具有保持基本相同的Tme的DSC曲线和随着共聚单体的量（即，衍生自乙烯和/或不饱和共聚单体的单元），并且（v）比用齐格勒 - 纳塔（ZN）催化剂制备的可比共聚物报告更多的γ型晶体的X射线衍射图。

75. 发明申请

US20040063117A1 Paper including bodies carrying at least one biochemical marker 失效
标题翻译：纸包括携带至少一种生物化学标记的物质
公开(公告)号：US20040063117A1
公开(公告)日：2004-04-01
申请号：US10466627
申请日：2003-07-18
发明人： Sandrine Rancien , Sebastien De Lamberterie
IPC分类号： C12Q001/68
CPC分类号： D01F6/06 , D01F1/10 , D01F2/10 , D21H21/46 , Y10T428/249933 , Y10T428/249936 , Y10T428/249937 , Y10T428/249944 , Y10T428/249948
摘要： Paper (1) characterized by the fact that it includes bodies (3) carrying at least one biochemical marker and of sufficient size to be capable of being taken individually.
摘要翻译：纸（1）的特征在于它包括携带至少一个生物化学标记并具有足够尺寸以能够单独摄取的体（3）的物质。

76. 发明申请

US20040029469A1 Microporous composite sheet material 有权
标题翻译：微孔复合片材
公开(公告)号：US20040029469A1
公开(公告)日：2004-02-12
申请号：US10386004
申请日：2003-03-11
申请人： Reemay, Inc.
发明人： Gary W. Anderson , Susannah D. Gelotte
IPC分类号： B32B003/00 , B32B027/12 , D04H003/16 , B32B005/18
CPC分类号： D06C3/06 , B29C47/0057 , B29C47/025 , B29C55/04 , B29C55/06 , B29C55/08 , B29C55/12 , B29C55/18 , B32B3/00 , B32B3/26 , B32B5/00 , B32B5/02 , B32B5/022 , B32B5/12 , B32B7/00 , B32B7/02 , B32B7/04 , B32B7/12 , B32B27/00 , B32B27/06 , B32B27/12 , B32B27/32 , B32B37/153 , B32B2255/00 , B32B2255/02 , B32B2262/00 , B32B2262/02 , B32B2262/0253 , B32B2266/025 , B32B2307/54 , B32B2307/718 , B32B2307/724 , B32B2307/7265 , B32B2439/00 , B32B2571/00 , D01D5/088 , D01D5/098 , D01F6/04 , D01F6/06 , D04H3/005 , D04H3/08 , D04H13/001 , D04H13/003 , D04H13/007 , Y10T156/10 , Y10T428/24942 , Y10T428/249953 , Y10T428/249978 , Y10T442/2025 , Y10T442/2139 , Y10T442/2148 , Y10T442/2213 , Y10T442/2861 , Y10T442/674 , Y10T442/681
摘要： A moisture vapor permeable, water impermeable composite sheet material is provided which is suitable for use as a housewrap material, and is also useful for other applications such as tarpaulins, or as covers for automobile, boats, patio furniture or the like. The composite sheet material includes a nonwoven substrate and an extrusion-coated polyolefin film layer overlying one surface of the substrate. The nonwoven substrate is comprised of polymeric fibers randomly disposed and bonded to one another to form a high tenacity nonwoven web. The nonwoven substrate has a grab tensile strength of at least 178 Newtons (40 pounds) in at least one of the machine direction (MD) or the cross-machine direction (CD). The extrusion coated polyolefin film layer is intimately bonded to the nonwoven substrate. The film layer has micropores formed therein to impart to the composite sheet material a moisture vapor transmission rate (MVTR) of at least 35 g/m2/24 hr. at 50% relative humidity and 23null C. and a hydrostatic head of at least 55 cm. In one embodiment, the nonwoven substrate comprises a spunbonded nonwoven fabric formed of randomly disposed substantially continuous polypropylene filaments. The spunbonded nonwoven fabric is an area bonded fabric in which the filaments are bonded to one another throughout the fabric at locations where the randomly disposed filaments overlie or cross one another.
摘要翻译：提供了一种适合用作家庭用纸材料的水蒸气透过性不透水复合片材材料，并且还可用于其他应用如篷布，或作为汽车，船只，露台家具等的覆盖物。复合片材包括非织造基材和覆盖在基材的一个表面上的挤出涂覆的聚烯烃膜层。非织造基底由聚合物纤维组成，其随机设置并彼此结合以形成高强度非织造纤维网。非织造基材在机器方向（MD）或横向（CD）上的至少一个上具有至少178牛顿（40磅）的拉伸强度。挤压涂覆的聚烯烃膜层紧密地结合到非织造基材上。膜层具有形成在其中的微孔，以使复合片材具有至少35g / m 2 / 24hr的湿气透过率（MVTR）。在50％相对湿度和23℃下，静水压头至少为55厘米。在一个实施方案中，非织造基材包括由随机设置的基本上连续的聚丙烯长丝形成的纺粘非织造织物。纺粘无纺织物是区域粘合织物，其中长丝在随机布置的长丝叠置或交叉的位置处通过织物彼此粘合。

77. 发明授权

US06583076B1 Nonwoven fabrics prepared using visbroken single-site catalyzed polypropylene 失效
标题翻译：使用偏苯乙烯单点催化聚丙烯制备的无纺布
公开(公告)号：US06583076B1
公开(公告)日：2003-06-24
申请号：US09439257
申请日：1999-11-12
申请人： Robert Louis Pekrul , Peter Michailovich Kobylivker
发明人： Robert Louis Pekrul , Peter Michailovich Kobylivker
IPC分类号： D04H156
CPC分类号： D01F8/06 , B29C47/0004 , B29C47/38 , B29C47/805 , B29C47/92 , B29C2947/92704 , C08F8/50 , C08F2810/10 , D01F6/06 , D04H1/4291 , D04H1/4382 , Y10T442/60 , Y10T442/68 , Y10T442/681 , C08F8/06 , C08F110/06
摘要： Nonwoven filaments having improved melt spinning process characteristics and end use properties are prepared using a visbroken single-site catalyzed propylene polymer. The propylene polymer has a first melt flow rate (MFR) before visbreaking and a second MFR after visbreaking, such that the ratio of the second MFR to the first MFR is about 1:1 to about 3:1. The nonwoven filaments exhibit less filament tension during spinning, and permit higher line speeds before breaking, than similar filaments prepared using a single-site catalyzed propylene polymer having the second MFR straight out of the reactor, and which has not been visbroken.
摘要翻译：具有改进的熔融纺丝工艺特性和最终用途性能的非织造长丝使用减弱的单中心催化的丙烯聚合物制备。丙烯聚合物在减粘裂化前具有第一熔体流动速率（MFR）和减粘裂化后的第二MFR，使得第二MFR与第一MFR的比例为约1:1至约3:1。无纺丝在纺丝期间显示较少的丝张力，并且在断裂之前允许更高的线速度比使用具有直接从反应器中出来的第二个MFR的单中心催化的丙烯聚合物制备的并且没有减弱的类似长丝。

78. 发明申请

US20030087573A1 Process for producing continuous filament nonwoven fabric 审中-公开
标题翻译：生产连续长丝无纺布的方法
公开(公告)号：US20030087573A1
公开(公告)日：2003-05-08
申请号：US10062055
申请日：2002-02-01
申请人： Polymer Group, Inc.
发明人： Valeria Griep Erdos , Pierre D. Grondin , Paul A. Kamnikar
IPC分类号： D01D005/12 , B29C047/60
CPC分类号： D04H3/02 , D01F6/06 , D04H3/14 , Y10T442/60 , Y10T442/681 , Y10T442/696
摘要： The present invention is directed to a process for producing continuous filament nonwoven fabric which comprises the steps of providing a single polymeric resin having an MFR of between about 6 to 16, spinning said single polymeric resin using commercially available continuous filament spinning equipment, to yield a continuous filament nonwoven fabric exhibiting a tensile strength improvement of at least 30% when compared to similar resin of greater than 35 MFR.
摘要翻译：本发明涉及一种生产连续长丝无纺织物的方法，其包括以下步骤：提供具有约6-16之间的MFR的单一聚合物树脂，使用市售的连续长丝纺丝设备纺出所述单一聚合物树脂，得到连续长丝非织造布与大于35MFR的类似树脂相比显示出至少30％的抗拉强度改善。

79. 发明申请

US20030049989A1 Thermoplastic constructs with improved softness 有权
标题翻译：具有改善柔软度的热塑性构件
公开(公告)号：US20030049989A1
公开(公告)日：2003-03-13
申请号：US10214071
申请日：2002-08-07
发明人： Richard Ferencz , Robert Dale , Nick Carter
IPC分类号： D04H003/00 , C08K005/20 , C08L023/00 , B29C047/00 , D01F001/10
CPC分类号： D01F6/06 , B29C47/00 , B29C47/0014 , B29C47/0021 , C08K5/20 , C08L23/02 , D01F1/10 , D04H1/4382 , D04H3/02 , Y10T442/626 , Y10T442/637
摘要： The present invention is directed to the combined use of first and second fatty acid amides to improve the softness of a thermoplastic polymer construct. A combination of fatty acid amides is provided in the blend ratio of about 10 to 90 percent by weight of a first fatty acid amide and 90 to 10 percent by weight of a second fatty acid amide. The first and second fatty acid amides are compounded into a thermoplastic polymer carrier resin and, preferentially, produced as concentrate pellets containing 0.5 to 75 percent by weight total fatty acid amide loading. The concentrate pellets are introduced into a thermoplastic polymer base, to form a thermoplastic resin, at a letdown level in the range of about 1 to 15 percent, with the range of 2 to 10 percent being preferred, and the range of 3 to 6 percent being most preferred.
摘要翻译：本发明涉及第一和第二脂肪酸酰胺的组合使用以改善热塑性聚合物构造物的柔软性。脂肪酸酰胺的组合以约10至90重量％的第一脂肪酸酰胺和90至10重量％的第二脂肪酸酰胺的混合比提供。将第一和第二脂肪酸酰胺配合到热塑性聚合物载体树脂中，优选以含有0.5至75重量％总脂肪酸酰胺负载的浓缩颗粒生产。将浓缩物颗粒引入热塑性聚合物基质中以形成热塑性树脂，其浓度范围为约1至15％，范围为2至10％，优选为3至6％是最喜欢的。

80. 发明申请

US20020169429A1 Wettable polyolefin fibers and fabrics 有权
标题翻译：可湿性聚烯烃纤维和织物
公开(公告)号：US20020169429A1
公开(公告)日：2002-11-14
申请号：US10045391
申请日：2001-11-09
发明人： Sheng-Shing Li , Andrew J. Leggio , George H. Menzie , David Devore , John J. McNamara , TaHau Yu , Douglas W. Horsey
IPC分类号： A61F013/15 , A61F013/20
CPC分类号： D04H3/16 , A61L15/225 , B29C47/0011 , B29C47/0014 , B29C47/8895 , C08K5/06 , C08L23/10 , C08L53/00 , C08L71/02 , C08L2203/12 , D01F1/10 , D01F6/04 , D01F6/06 , D01F8/06 , D04H1/4291 , D04H1/56 , D04H3/00 , Y10T428/2913 , Y10T428/2929 , Y10T442/2008 , Y10T442/2311 , Y10T442/2352 , Y10T442/2418 , Y10T442/2484 , Y10T442/3976 , Y10T442/696 , C08L23/06 , C08L23/02 , C08L2666/24 , C08L23/12 , C08L2666/22
摘要： Polyolefin woven and nonwoven fibers, filaments and fabrics made therefrom which comprise a melt blend which comprises (a) a polyolefin; and (b) at least one compound of the formula (I) R1null(hydrophilic oligomer)nullnull(I) wherein R1 is a straight or branched chain alkyl of 22 to 40 carbon atoms and the hydrophilic oligomer is a homo- or co-oligomer consisting of monomer units derived from monomers selected from the group consisting of ethylene oxide, propylene oxide, ethylene glycol, propylene glycol, epichlorhydrin, acrylic acid, methacrylic acid, ethylene imine, caprolactone, vinyl alcohol and vinyl acetate; and wherein the hydrophilic oligomer consists of between 2 and 10 monomer units, exhibit excellent durable wettability. The fabrics are useful in disposable diapers, training pants, feminine napkins, tampons, incontinence care products, wet and dry wipes, wound dressings, surgical capes, filter medial, battery separators and the like.
摘要翻译：聚烯烃织造和非织造纤维，长丝和由其制成的织物，其包含熔融共混物，其包含（a）聚烯烃; 和（b）至少一种式（I）的化合物，其中R1是一个或多个式（I）的化合物，其中R 1是 22至40个碳原子的直链或支链烷基，并且亲水性低聚物是由源自选自环氧乙烷，环氧丙烷，乙二醇，丙二醇，表氯醇的单体衍生的单体单元组成的均聚物或共聚物，丙烯酸，甲基丙烯酸，乙烯亚胺，己内酯，乙烯醇和乙酸乙烯酯; 并且其中所述亲水性低聚物由2和10个单体单元组成，表现出优异的耐久润湿性。织物在一次性尿布，训练裤，女性餐巾，棉塞，失禁护理产品，湿和干湿巾，伤口敷料，外科手术盖，过滤器内侧，电池分离器等中是有用的。

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