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    • 7. 发明授权
    • Process for producing paintable polymeric articles
    • 生产可涂覆聚合物品的方法
    • US6077913A
    • 2000-06-20
    • US48609
    • 1998-03-26
    • Lars Guenter Beholz
    • Lars Guenter Beholz
    • C08F8/06
    • B29C47/92C08F8/06B29C2947/92704B29C47/0004B29C47/38B29C47/805C08F2810/10
    • A method for improving surface adhesion characteristics of a polymer substrate in which the portion of the surface of the polymeric substrate to be treated is contacted with a fluid material containing at least one oxidizing agent. The oxidizing agent in the fluid material is present in a kinetically degrading state capable of producing at least one chemical intermediate which is reactive with the polymeric substrate. Contact between the fluid containing the oxidizing agent and the polymeric substrate is maintained for an interval sufficient to produce or modify functional groups in the polymeric substrate proximate to its surface. The oxidizing agent of choice is a bivalent oxygen compound. The oxidizing agent is activated by an activator agent containing at least one carboxylic acid group or derivative thereof. The activator agent may be present in the fluid upon initial contact with the polymeric substrate or may be added to the fluid subsequent to initial contact with the polymeric substrate.
    • 一种用于改善聚合物基材的表面粘附特性的方法,其中待处理的聚合物基材的表面的一部分与含有至少一种氧化剂的流体材料接触。 流体材料中的氧化剂以能够产生至少一种与聚合物基质反应的化学中间体的动力学降解状态存在。 含有氧化剂和聚合物基质的流体之间的接触保持足够的间隔以在聚合物基底中靠近其表面产生或改变官能团。 所选择的氧化剂是二价氧化合物。 氧化剂由含有至少一个羧酸基团或其衍生物的活化剂活化。 活化剂可以在与聚合物基材初始接触时存在于流体中,或者可以在与聚合物基材初始接触之后添加到流体中。
    • 8. 发明授权
    • Propylene resin composition and molded article thereof
    • 丙烯树脂组合物及其模制品
    • US5824759A
    • 1998-10-20
    • US716405
    • 1996-11-01
    • Kazuyuki WatanabeSakuyoshi NakagamiMeiko Saihata
    • Kazuyuki WatanabeSakuyoshi NakagamiMeiko Saihata
    • C08F8/50C08K5/14C08F210/00
    • C08K5/14B29C47/92C08F8/50B29C2947/92704B29C47/0004B29C47/38B29C47/805
    • A propylene resin composition obtained by dynamic heat treatment of a blend of (A) 100 parts by weight of a propylene-.alpha.-olefin block copolymer wherein a ratio (.eta..sub.1 /.eta..sub.2) of melt viscosity .eta..sub.1 at a shear rate of 10.sup.1 sec.sup.-1 to melt viscosity .eta..sub.2 at a shear rate of 10.sup.2 sec.sup.-1 is 3.5 to 8 as measured by a slit die method and (B)0.005 to 2 parts by weight of an organic peroxide, and having a melt flow rate (measured according to JIS K7210, at a temperature of 230.degree. C. under a load of 2.16 kg) adjusted to 50 to 300 g/10 minutes, a main endothermic peak temperature Tmp of 120.degree. to 150.degree. C. for melting temperature and a main exothermic peak temperature Tcp of 85.degree. to 105.degree. C. for crystallization temperature, as measured with a Differential Scanning Calorimetry, and a Tcp half-value width of 5.degree. C. or above, and a molded article obtained by using the same.
    • PCT No.PCT / JP96 / 00063 Sec。 371日期:1996年11月1日 102(e)1996年11月1日PCT PCT 1996年1月18日PCT公布。 公开号WO96 / 23029 日本1996年8月1日通过动态热处理(A)100重量份丙烯-α-烯烃嵌段共聚物的共混物获得的丙烯树脂组合物,其中熔体粘度等于1的(η1 /η2) 剪切速率为101秒-1,剪切速度为102秒-1的熔融粘度ηa为3.5至8,通过狭缝模压法测定为(B)0.005至2重量份的有机过氧化物,并且具有 熔体流动速率(根据JIS K7210,在2.16kg的负荷下在230℃的温度下测量)调节至50-300g / 10分钟,主吸热峰温度Tmp为120-150℃。 对于结晶温度为85〜105℃的主要放热峰温度Tcp,使用差示扫描量热法测定,Tcp半值宽度为5℃以上,得到的成型体 通过使用相同。
    • 9. 发明授权
    • Water-injection foaming devolatilizing method
    • 注水发泡脱挥发分法
    • US5630968A
    • 1997-05-20
    • US474724
    • 1995-06-07
    • Ning-He WangNoriaki Hashimoto
    • Ning-He WangNoriaki Hashimoto
    • B29C47/76B29C47/80B29C44/00
    • B29C47/762B29C47/805B29C47/0009Y10S425/812
    • A water-injection foaming devolatilizing method includes the steps of: melting and kneading a polymer in a water-injection dispersing zone of an extruder having a screw; injecting water into a polymer melt so as to be dispersed into the polymer melt which is being kneaded; and vaporizing volatile components contained in the polymer melt together with water in a devolatilizing zone having a vent port and located on a downstream side of the water-injection dispersing zone, so that the volatile components are removed and discharged through the vent port. A pressure-reducing expansion zone is provided between the water-injection dispersing zone and the devolatilizing zone so as to be upstream of the vent port. The method further includes gradually reducing a pressure in the pressure-reducing expansion zone so that not only bubbles in the water which is dispersed into the polymer melt are made to grow up, but also the bubbles are broken down at a downstream end portion of the pressure-reducing expansion zone.
    • 注水发泡脱挥发分法包括以下步骤:在具有螺杆的挤出机的注水分散区中熔融和捏合聚合物; 将水注入聚合物熔体中以分散在正在捏合的聚合物熔体中; 并且包含在聚合物中的挥发性成分的蒸发与具有通气口并位于注水分散区的下游侧的脱挥发区一起与水一起熔化,从而通过排气口除去挥发性成分并排出。 在注水分散区和脱挥发区之间设有减压膨胀区,以便在通气口的上游。 该方法还包括逐渐降低减压膨胀区的压力,使得不仅使分散在聚合物熔体中的水中的气泡长大,而且气泡在下游端部分分解 减压膨胀区。