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71. 发明授权

US4406818A Olefin polymerization 失效
标题翻译：烯烃聚合
公开(公告)号：US4406818A
公开(公告)日：1983-09-27
申请号：US343643
申请日：1982-01-28
申请人： Joel L. Martin , M. Bruce Welch , Richard E. Dietz , Charles E. Capshew
发明人： Joel L. Martin , M. Bruce Welch , Richard E. Dietz , Charles E. Capshew
IPC分类号： C08F4/00 , C08F4/60 , C08F4/62 , C08F4/64 , C08F4/658 , C08F10/00 , B01J31/26
CPC分类号： C08F10/00
摘要： Catalysts effective for the polymerization of olefins at high productivity formed upon mixing (1) a solution of titanium tetrahydrocarbyloxide or a zirconium tetrahydrocarbyloxide and an organoaluminum halide with (2) a dihydrocarbylmagnesium compound alone or admixed with a minor amount of a trialkylaluminum and (3) combining the product obtained in (2) with a metal halide selected from a silicon tetrahalide and a titanium tetrahalide. The catalyst component thus produced can be combined with an organoaluminum compound as a cocatalyst component.
摘要翻译：混合后有效生成烯烃聚合的催化剂（1）四氢氧化四氢化钛或四氢氧化镁锆与有机铝卤化物的溶液与（2）二烃基镁化合物单独或与少量三烷基铝混合，（3）将（2）中获得的产物与选自四卤化硅和四卤化钛的金属卤化物组合。由此生产的催化剂组分可以与作为助催化剂组分的有机铝化合物组合。

72. 发明授权

US4393182A Olefin polymerization process with novel supported titanium catalyst compositions 失效
标题翻译：烯烃聚合工艺与新型载体钛催化剂组合物
公开(公告)号：US4393182A
公开(公告)日：1983-07-12
申请号：US318649
申请日：1981-11-05
申请人： Brian L. Goodall , Adrianus A. van der Nat , Willem Sjardijn
发明人： Brian L. Goodall , Adrianus A. van der Nat , Willem Sjardijn
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F4/658 , C08F4/72 , C08F10/00 , C08F4/02
CPC分类号： C08F10/00
摘要： An olefin polymerization process comprises contacting the monomer to be polymerized with a catalyst composition comprising: an organoaluminum compound, a first electron donor, and a product obtained by contacting a solid component comprising a magnesium halide in which the atomic ratio of chlorine to magnesium is at least 1.2, a titanium halide and a second electron donor, with a halohydrocarbon and thereafter with a tetravalent titanium compound.
摘要翻译：烯烃聚合方法包括使待聚合的单体与催化剂组合物接触，所述催化剂组合物包含：有机铝化合物，第一电子给体和通过使包含氯与镁的原子比在其中的卤化镁的固体组分至少1.2，卤化钛和第二电子给体，与卤代烃，然后用四价钛化合物。

73. 发明授权

US11077434B2 Method of preparing metallocene catalyst for polyolefin preparation 有权
公开(公告)号：US11077434B2
公开(公告)日：2021-08-03
申请号：US15774448
申请日：2017-07-07
申请人： LG Chem, Ltd.
发明人： Hee Kwang Park , Hye Kyung Lee , Byung Seok Kim , Jae Youp Cheong , Sang Jin Jeon
IPC分类号： C08F4/76 , B01J31/22 , C08F110/06 , B01J37/03 , C08F4/658 , C08F4/6592 , C08F4/659 , C08F10/06
摘要： A method of preparing a high-purity metallocene catalyst capable of providing various selectivities and high activities for polyolefin copolymers, wherein a metallocene compound is formed by reacting a ligand compound with a zirconium compound, and then lithium chloride as a reaction by-product included in the metallocene compound is prepared in a form of a complex compound and effectively removed in a subsequent step of extracting the catalyst, thereby effectively preparing the high-purity metallocene catalyst, is provided.

74. 发明申请

US20200165422A1 SOLUTION POLYMERIZATION PROCESS 审中-公开
公开(公告)号：US20200165422A1
公开(公告)日：2020-05-28
申请号：US16751328
申请日：2020-01-24
申请人： NOVA Chemicals (International) S.A.
发明人： Fazle Sibtain , Christopher John Brooke Dobbin , Donald Gary Hartlen , Kenneth Edward Taylor , Hamidreza Khakdaman
IPC分类号： C08L23/08 , C08L23/14 , C08F4/659 , C08F4/658 , C08F4/655 , B32B27/34 , B32B27/08 , B32B7/12 , C08F210/16 , B29C41/04 , C08L23/20 , C08J5/18 , B32B27/32 , B32B3/26 , C08F4/6592 , C08F2/00 , C08J5/00
摘要： This disclosure relates to a continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a single site catalyst formulation are injected into a first reactor forming a first ethylene interpolymer. Process solvent, ethylene, optional comonomers, optional hydrogen and a heterogeneous catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in an optional third reactor, wherein an optional heterogeneous catalyst formulation may be employed. In a solution phase, the first, second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is passivated and following a phase separation process an ethylene interpolymer product is recovered.

75. 发明授权

US07351678B2 Catalyst systems for Ziegler-Natta propene polymerisation 失效
标题翻译：用于齐格勒 - 纳塔丙烯聚合的催化剂体系
公开(公告)号：US07351678B2
公开(公告)日：2008-04-01
申请号：US10491917
申请日：2002-09-11
申请人： Kartin Köhler , Herbert Schumann , Birgit Corinna Wassermann , Wilfried Wassermann , Katharina Lange , Sebastian Dechert , Markus Hummert , Stefan Schutte , Walter Kaminsky , Andrea Eisenhardt , Björn Heuer , Andre Laban
发明人： Kartin Köhler , Herbert Schumann , Birgit Corinna Wassermann , Wilfried Wassermann , Katharina Lange , Sebastian Dechert , Markus Hummert , Stefan Schutte , Walter Kaminsky , Andrea Eisenhardt , Björn Heuer , Andre Laban
IPC分类号： B01J31/14 , B01J31/00 , B01J31/18 , C07F5/00 , C07F5/06 , C08F4/52 , C08F4/658 , C08F10/00 , C08F10/06
CPC分类号： C07F5/066
摘要： The invention relates to the use of nitrogenous aluminium organyl complexes of general formula (I) as co-catalysts in heterogeneous polymerisation reactions of propene. In said formula: R, R′, R1 and R1′ independently of one another represent branched or unbranched C1-C7 alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl or alkynyl; R2 represents unsubstituted, monoalkylated or polyalkylated and/or monofluorinated or polyfluorinated aromatic hydrocarbons from group (II); R3 and R4 independently of one another represent CH2, CF2 oder C(R1)2; m stands for 0, 1 or 2; n stands for 0, 1 or 2; o stands for 0 or 1, all independently of one another. Said systems exhibit improved characteristics in terms of activity and stereoselectivity in comparison to conventional co-catalysts such as AlEt3 and can act simultaneously as co-catalysts and stereoselectivity promoters
摘要翻译：本发明涉及在丙烯的非均相聚合反应中使用通式（I）的含氮有机络合物作为助催化剂。在所述式中：R 1，R 2，R 1和R 1彼此独立地表示支链或非支链C 1 -C 3 烷基，环烷基，烯基，环烯基，芳基或炔基; R 2表示来自（II）组的未取代的单烷基化或多烷基化和/或单氟化或多氟化芳族烃; R 3和R 4彼此独立地表示CH 2，CF 2，C（R 0） 2＆lt; 2＆gt;; m代表0,1或2; n代表0,1或2; o代表0或1，彼此独立。与常规助催化剂如AlE 3 3 3相比，所述体系在活性和立体选择性方面表现出改善的特性，并且可以同时作为助催化剂和立体选择性促进剂

76. 发明申请

US20070219326A1 Magnesium Compound, Solid Catalyst Component, Olefin Polymerization Catalyst, and Method for Producing Olefin Polymer 审中-公开
标题翻译：镁化合物，固体催化剂组分，烯烃聚合催化剂和生产烯烃聚合物的方法
公开(公告)号：US20070219326A1
公开(公告)日：2007-09-20
申请号：US11573045
申请日：2005-08-03
申请人： Shojiro Tanase , Nobuhiro Yabunouchi , Takehito Konakazawa , Takanori Sadashima , Kiyokazu Katayama
发明人： Shojiro Tanase , Nobuhiro Yabunouchi , Takehito Konakazawa , Takanori Sadashima , Kiyokazu Katayama
IPC分类号： C08F4/02 , C07C31/28 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00 , C07F3/003 , C08F10/06 , C08F110/06 , C08F4/6148 , C08F4/6145 , C08F4/6574 , C08F4/6578 , C08F4/70 , C08F4/6588 , C08F4/6565 , C08F2500/15 , C08F2500/17 , C08F2500/24
摘要： A magnesium compound obtained by reacting the following components (i) (ii) and (iii): (i) metal magnesium (ii) an alcohol (iii) a metal dihalide compound represented by the general formula (I) containing at least 0.001 mole of M relative to one mole of magnesium of the metal magnesium (i) MX2 (I) where X is a halogen atom and M is Mn, Fe, Co or Zn.
摘要翻译：通过使以下组分（i）（ii）和（iii）反应获得的镁化合物：（i）金属镁（ii）醇（iii）由通式（I）表示的金属二卤化物化合物，其含有至少0.001摩尔相对于1摩尔镁的金属镁（i）<？在线公式描述=“在线公式”end =“lead”？> MX 2（I）？in-line-formula description =“In-line Formulas”end =“tail”？>其中X是卤素原子，M是Mn，Fe，Co或Zn。

77. 发明申请

US20050239978A1 Method for producing a poly-1olefin in the presence of a ziegler catalyst 有权
标题翻译：在齐格勒催化剂存在下制备聚-1-烯烃的方法
公开(公告)号：US20050239978A1
公开(公告)日：2005-10-27
申请号：US10514095
申请日：2003-05-22
申请人： Ludwig Bohm , Joachim Berthold
发明人： Ludwig Bohm , Joachim Berthold
IPC分类号： C08F10/00 , C08F4/44 , C08F4/60 , C08F4/658 , C08F10/02 , C08F110/02
CPC分类号： C08F110/02 , C08F10/02 , C08F4/6555 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： The invention relates to a method for producing a poly-1-olefin by polymerization of a 1-olefin of the formula R4C═CH2, in which R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in the gas phase, at a temperature of from 20 to 200° C. and a pressure of from 0.5 to 50 bar, in the presence of a catalyst which consists of the product of the reaction of a magnesium alkoxide with a transition-metal compound (component a) and an organometallic compound (component b), whose component (a) has been produced by reacting a transitionmetal compound of titanium, zirconium, vanadium or chromium with a gelatinous dispersion of the magnesium alkoxide in an inert hydrocarbon. In accordance with the invention, the gelatinous dispersion is obtained by stirring, using a stirring element, or shearing, using a high-performance shearing tool, a suspension of a magnesium alkoxide powder having a mean particle size, expressed as the d50 value, in the range from 50 to 1000 um, in an aliphatic hydrocarbon in which the magnesium alkoxide particles are insoluble. The suspension has, before conversion into the dispersion, been subjected to heat treatment at a temperature in the range from 40 to 150° C. over a period of from 10 to 100 hours.
摘要翻译：本发明涉及通过聚合式R 4 C-CH 2 2-的1-烯烃制备聚-1-烯烃的方法，其中R 0 > 4是氢或具有1至10个碳原子的烷基，悬浮液，溶液或气相中，温度为20-200℃，压力为0.5至50 在由醇盐与过渡金属化合物（组分a）的反应产物和有机金属化合物（组分b）组成的催化剂的存在下，其组分（a）通过使钛，锆，钒或铬的过渡金属化合物与烷氧基镁在惰性烃中的凝胶状分散体。根据本发明，通过使用搅拌元件搅拌或使用高性能剪切工具剪切平均粒度的烷氧基镁粉末的悬浮液（表示为d＆lt; 在50〜1000μm的范围内，在烷氧基镁颗粒不溶的脂族烃中。悬浮液在转化成分散体之前，在10〜100小时的时间内，在40〜150℃的温度下进行热处理。

78. 发明授权

US06884746B2 Catalysts for olefin polymerization and method of olefin polymerization using the same 有权
标题翻译：用于烯烃聚合的催化剂和使用其的烯烃聚合方法
公开(公告)号：US06884746B2
公开(公告)日：2005-04-26
申请号：US10311416
申请日：2001-06-14
申请人： Young-Soo Ko , Ki-Su Ro , Young-Jun Lee , Yong Chun
发明人： Young-Soo Ko , Ki-Su Ro , Young-Jun Lee , Yong Chun
IPC分类号： C08F4/658 , C08F4/656 , C08F10/00 , C08F110/06 , B01J31/00 , B01J37/00 , C02F4/02 , C02F4/60
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6492 , C08F4/6567 , C08F4/6565 , C08F2500/11 , C08F2500/12
摘要： Described herein is a prepolymerized catalyst encapsulated with macromolecular monomers which is prepared by adding olefin mononers and diene compounds to a solid complex titanium catalyst for olefin polymerization and then polymerizing, and also relates to a method for polymerization or copolymerization capable of preparing polyolefins with high melt strength by polymerizing the olefin by using said catalyst.
摘要翻译：本文描述了用大分子单体包封的预聚合催化剂，其通过将烯烃单体和二烯化合物加入到用于烯烃聚合的固体复合钛催化剂中然后聚合而制备，并且还涉及能够制备具有高熔体的聚烯烃的聚合或共聚方法通过使用所述催化剂聚合烯烃的强度。

79. 发明授权

US06858685B2 Solid catalyst component for olefin polymerization, process for producing the same, process for producing catalyst for olefin polymerization, and process for producing olefin polymer 失效
标题翻译：用于烯烃聚合的固体催化剂组分，其制备方法，用于生产烯烃聚合催化剂的方法，和烯烃聚合物的制备方法
公开(公告)号：US06858685B2
公开(公告)日：2005-02-22
申请号：US10207762
申请日：2002-07-31
申请人： Ken Yoshimura , Shin-ichi Kumamoto , Makoto Satoh
发明人： Ken Yoshimura , Shin-ichi Kumamoto , Makoto Satoh
IPC分类号： C08F4/16 , C08F4/02 , C08F4/651 , C08F4/653 , C08F4/654 , C08F4/658 , C08F10/00 , C08F110/06 , C08F297/08 , C08F4/42
CPC分类号： C08F297/083 , C08F10/00 , C08F110/06 , C08F297/08 , C08F4/6565 , C08F2500/17 , C08F2500/18
摘要： There is provided a process for producing a catalyst for olefin polymerization, which comprises the step of contacting (1) an organ aluminum compound, (2) an external electron donor compound and (3) a solid catalyst component obtained by a process comprising the steps of; (i) reducing a titanium compound represented by the following formula [I] with an organomagnesium compound in the presence of a fine particle and an organosilicon compound having an Si—O bond to obtain a solid product, and (ii) contacting the solid product, a halogenocompound having halogenation ability and an internal electron donor compound to obtaining the solid catalyst component.
摘要翻译：提供了一种制备用于烯烃聚合的催化剂的方法，其包括使（1）有机铝化合物，（2）外部电子给体化合物和（3）通过包括以下步骤的方法获得的固体催化剂组分的步骤：（i）在微粒和具有Si-O键的有机硅化合物的存在下，用有机镁化合物还原由下式[I]表示的钛化合物，得到固体产物，和（ii）使固体产物，具有卤化能力的卤化合物和内部电子给体化合物以获得固体催化剂组分。

80. 发明授权

US6133385A Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins 失效
标题翻译：用于烯烃聚合中改进的立体选择性和较宽分子量分布的催化剂体系
公开(公告)号：US6133385A
公开(公告)日：2000-10-17
申请号：US223916
申请日：1994-04-06
申请人： Edwar S. Shamshoum , David John Rauscher , Douglas Alan Burmaster
发明人： Edwar S. Shamshoum , David John Rauscher , Douglas Alan Burmaster
IPC分类号： C08F4/646 , C08F4/649 , C08F4/658 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00 , Y02P20/52
摘要： The present invention provides a catalyst system and a process for the polymerization of olefin that exhibits improved selectivity and broader molecular weight distribution in the polymer product. The catalyst system includes a conventional supported Ziegler-Natta catalyst in combination with a mixture of at least two electron donors, both having the general formula SiR.sub.m (OR').sub.4-m where R is selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a vinyl group; R' is an alkyl group; and m is 0-3, wherein when R is an alkyl group, R may be identical with R'; when m is 0, 1 or 2, the R' groups may be identical or different; and when m is 1, 2 or 3, the R groups may be identical or different. Preferably, one electron donor is described by the formula: ##STR1## wherein R.sub.1 and R.sub.4 are both an alkyl or cycloalkyl group containing a secondary or tertiary carbon atom attached to the silicon atom, R.sub.1 and R.sub.4 being the same;; R.sub.2 and R.sub.3 are alkyl or aryl groups, R.sub.2 and R.sub.3 being the same or different;and the other electron is described by the formula: ##STR2## wherein R'.sub.1 is an alkyl or cycloalkyl group containing at least one primary, secondary or tertiary carbon atom attached to the silicon atom, R'.sub.2 and R'.sub.3 are an alkyl or aryl group, R'.sub.2 and R'.sub.3 being the same or different; and R'.sub.4 is an alkyl group with a primary carbon attached to the silicon atom, R'.sub.1 and R'.sub.4 being the same or different. This catalyst system produces polypropylene having xylene solubles of 1-7 to 5.1 wt % and a molecular weight distribution of about 10.
摘要翻译：本发明提供一种催化剂体系和烯烃聚合方法，其在聚合物产物中表现出改善的选择性和较宽的分子量分布。催化剂体系包括与至少两个电子给体的混合物组合的常规负载齐格勒 - 纳塔催化剂，两者都具有通式SiRm（OR'）4-m，其中R选自烷基，环烷基，芳基和乙烯基; R'是烷基; 并且m为0-3，其中当R为烷基时，R可以与R'相同; 当m为0,1或2时，R'可以相同或不同; 当m为1,2或3时，R基团可以相同或不同。优选地，一个电子给体由下式描述：其中R1和R4都是含有与硅原子连接的仲或叔碳原子的烷基或环烷基，R1和R4相同; R2和R3是烷基或芳基，R2和R3相同或不同; 而另一个电子由下式描述：其中R'1是含有至少一个连接到硅原子上的伯，仲或叔碳原子的烷基或环烷基，R'2和R'3是烷基或芳基 R'2和R'3相同或不同; 并且R'4是具有连接到硅原子上的伯碳的烷基，R'1和R'4相同或不同。该催化剂体系产生具有1-7至5.1wt％的二甲苯可溶物和约10的分子量分布的聚丙烯。

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