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    • 71. 发明授权
    • Production of a film-like or fibrous structure of an aromatic polyester
    • 生产芳族聚酯的薄膜状或纤维结构体
    • US4517315A
    • 1985-05-14
    • US340036
    • 1982-01-18
    • Shunichi MatsumuraHiroo Inata
    • Shunichi MatsumuraHiroo Inata
    • C08J5/18C08K5/34D01F6/92B29D27/00C08G8/00
    • C08J5/18C08K5/34D01F6/92C08J2367/02Y10S264/13
    • A process for producing a film-like or fibrous structure of an aromatic polyester, which comprises(1) forming an unstretched film-like or fibrous structure by melt-shaping a blend comprising 100 parts by weight of (A) an aromatic polyester having a high degree of polymerization derived from an aromatic dicarboxylic acid as a main acid component and an aliphatic diol and/or an alicyclic diol as a main glycol component and (B) 3 to 300 parts by weight of a low-molecular-weight compound being substantially non-reactive with the aromatic polyester (A) and having a boiling point of at least about 200.degree. C. under atmospheric pressure and a molecular weight of not more than 1,000,(2) stretching the resulting film-like or fibrous structure,(3) extracting at least a major portion of the low-molecular-weight compound from the stretched film-like or fibrous structure by using an organic solvent which does not substantially dissolve the aromatic polyester under the extracting conditions, and(4) if desired, heat-setting the film-like or fibrous structure after the stretching step (2) and/or the extracting step (3).The film-like or fibrous structure of an aromatic polyester prepared by the process substantially contains no low-molecular-weight compound or contains the low-molecular-weight compound in an amount of up to about 1 part by weight at most per 100 parts by weight of the aromatic polyester.
    • 一种制备芳族聚酯的薄膜状或纤维结构体的方法,其包括:(1)通过熔融成型共混物形成未拉伸的薄膜状或纤维结构体,所述共混物包含100重量份的(A)具有 衍生自作为主要酸成分的芳族二羧酸和作为主要二醇成分的脂族二醇和/或脂环族二醇的高聚合度和(B)基于3〜300重量份的低分子量化合物 与芳族聚酯(A)不反应,并且在大气压下沸点至少为约200℃,分子量不大于1000,(2)拉伸所得膜状或纤维结构物( 3)通过使用在萃取条件下基本上不溶解芳香族聚酯的有机溶剂,从拉伸膜状或纤维结构体中提取至少一部分低分子量化合物,和( 4)如果需要,在拉伸步骤(2)和/或提取步骤(3)之后对膜状或纤维结构进行热定型。 通过该方法制备的芳族聚酯的薄膜状或纤维结构基本上不含低分子量化合物,或者含有最多约1重量份至100重量份的低分子量化合物 芳香族聚酯的重量。
    • 74. 发明授权
    • Process for manufacturing a polyester multifilament yarn
    • 聚酯复丝纱线的制造方法
    • US4410473A
    • 1983-10-18
    • US302952
    • 1981-09-16
    • Kohichi IoharaMichikage Matsui
    • Kohichi IoharaMichikage Matsui
    • D01F6/62C08L67/02D01F6/92D02G1/02D02G1/20
    • C08L67/02D01F6/92D02G1/0286Y10T428/2904Y10T428/2913Y10T428/2929Y10T428/2976
    • A polyester multifilament consisting essentially of filament groups (I) and (II). The filament group (I) is composed of a polyester selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate and polytetramethylene terephthalate, and/or a blend and/or copolymer comprising at least two members selected from the polyesters. The filament group (II) is composed of a substrate composed of a polyester selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate and polytetramethylene terephthalate, and/or a blend and/or a copolymer comprising at least two members selected from the polyesters and at least one polymer selected from the group consisting of styrene type polymers, methacrylate type polymers and acrylate type polymers, which is added to said substrate in an amount of 0.4 to 8% by weight based on the substrate.
    • 基本上由长丝组(I)和(II)组成的聚酯复丝。 长丝组(I)由选自聚对苯二甲酸乙二醇酯,聚对苯二甲酸丙二醇酯和聚四亚甲基对苯二甲酸酯的聚酯和/或包含选自聚酯中的至少两种成分的共混物和/或共聚物组成。 长丝群(II)由选自聚对苯二甲酸乙二醇酯,聚对苯二甲酸丙二醇酯和聚四亚甲基对苯二甲酸酯的聚酯组成的基材和/或共混物和/或共聚物组成,所述共混物和/或共聚物包含选自聚酯和 至少一种选自苯乙烯型聚合物,甲基丙烯酸酯型聚合物和丙烯酸酯类聚合物的聚合物,其以基于基材的0.4至8重量%的量加入到所述基材中。
    • 78. 发明授权
    • Production of polyester fibers of improved stability
    • 生产稳定性好的聚酯纤维
    • US4374960A
    • 1983-02-22
    • US302908
    • 1981-09-16
    • Ronald E. RothwellHugh H. RowanJames J. Dunbar
    • Ronald E. RothwellHugh H. RowanJames J. Dunbar
    • C08G63/91C08K5/00D01F6/92C08G69/48C08L77/06
    • D01F6/92C08G63/916C08K5/0008
    • There is provided by this invention a process for the production of high molecular weight linear polyethylene terephthalate condensation polyesters which are useful especially for preparing specialty fibers which have excellent resistance to degradation so that they can be used in such commercial articles as paper making machine fabric, industrial belting, etc. The improved high molecular weight linear polyethylene terephthalate condensation polyester specialty fibers are characterized by improved hydrolytic stability and by reduction in the free carboxyl content so as to have a carboxyl concentration of less than about 6 gram equivalents per 10.sup.6 grams of the polyester. These polyester specialty fibers are prepared by the steps of adding an end capping reagent to particles of the said feed polymer, heating to obtain a homogeneous mixture of the said polyester and end capping reagent, mechanically working the polyester melt, and forming filaments of the linear polyester having a reduced free carboxyl content.
    • 本发明提供一种生产高分子量线型聚对苯二甲酸乙二醇酯缩聚物的方法,其特别用于制备具有优异的耐劣化性能的特种纤维,因此可用于造纸机织物等商品中, 工业皮带等。改进的高分子量线性聚对苯二甲酸乙二醇酯缩聚物特种纤维的特征在于改进的水解稳定性和游离羧基含量的降低,使得羧基浓度小于约6克当量/ 106克 聚酯。 这些聚酯特种纤维通过以下步骤制备:将端封试剂加入到所述进料聚合物的颗粒中,加热以获得所述聚酯和封端剂的均匀混合物,机械加工聚酯熔体,并形成线性的长丝 具有降低的游离羧基含量的聚酯。