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    • 71. 发明授权
    • Stabilizer formulation for thermoplastic polymers
    • 用于热塑性聚合物的稳定剂配方
    • US6077890A
    • 2000-06-20
    • US985336
    • 1997-12-04
    • Robert L. HudsonMary Lou Delucia
    • Robert L. HudsonMary Lou Delucia
    • C08K5/00C08K5/34C08K5/04C08K5/17C08K5/51
    • C08K5/005
    • A stabilizer formulation particularly well suited for improving the properties of thermoplastic polymers is disclosed. The stabilizer formulation contains a combination of stabilizers that improves the process stability of a polymer, prevents the polymer from yellowing, increases the thermal aging stability of the polymer and inhibits the polymer from generating smoke during melt processing. Of particular advantage, the stabilizer formulation improves the stability of a polymer without significantly adversely affecting any other properties of the polymer. In one embodiment, the stabilizer formulation includes a hindered amine, a hydroxyl amine, and one or more hydrolytically resistant phosphites. In one embodiment, the formulation can further contain an acid scavenger for preventing an acid contained within the polymer or produced during processing from harming the polymer.
    • 公开了一种特别适用于改善热塑性聚合物性能的稳定剂配方。 稳定剂配方含有改善聚合物工艺稳定性的稳定剂的组合,防止聚合物变黄,提高聚合物的热老化稳定性,并抑制聚合物在熔融加工过程中产生烟雾。 特别有利的是,稳定剂配方改善聚合物的稳定性,而不会显着地不利地影响聚合物的任何其它性能。 在一个实施方案中,稳定剂配方包括受阻胺,羟胺和一种或多种抗水解亚磷酸酯。 在一个实施方案中,制剂还可含有用于防止聚合物中所含的酸或在加工过程中产生的酸损害聚合物的酸清除剂。
    • 77. 发明授权
    • Fire retardent polyester resin composition and process for producing the
same
    • 阻燃聚酯树脂组合物及其制备方法
    • US5770644A
    • 1998-06-23
    • US806651
    • 1997-02-26
    • Masanori YamamotoShintarou Kishimoto
    • Masanori YamamotoShintarou Kishimoto
    • C08K5/3492C08K5/523C08K5/5399C08L67/02C08K5/49C08K5/51C08K5/52
    • C08K5/5399C08K5/34928C08K5/523C08L67/02
    • A fire retardant polyester resin composition comprising (A) 95 to 30 parts by weight of a polyester resin and (B) 5.0 to 70 parts by weight of a polyphenylene ether resin and/or polyphenylene sulfide resin, and, for 100 parts by weight in total of the components (A) and (B), (C) 0.05 to 10 parts by weight of a compatibilizing agent, (D) 2.0 to 45 parts by weight of a phosphoric ester compound or phosphonitrile compound, (E) 0 to 150 parts by weight of a reinforcing filler, (F) 0.001 to 15 parts by weight of an anti-dripping agent, (G) 0 to 45 parts by weight of a melamine cyanurate, and (H) 0 to 15 parts by weight of a polystyrene resin having epoxy group, provided that the amount of the component (G) is from 0.5 to 45 parts by weight for 100 parts by weight in total of the components (A) and (B) when the amount of the component (B) is less than 35 parts by weight. The polyester resin composition scarcely corrodes a metal mold when it is molded, and is excellent in fire retardancy.
    • 一种阻燃性聚酯树脂组合物,其包含(A)95〜30重量份的聚酯树脂和(B)5.0〜70重量份的聚苯醚树脂和/或聚苯硫醚树脂,并且对于100重量份 组分(A)和(B),(C)0.05〜10重量份相容剂,(D)2.0〜45重量份磷酸酯化合物或磷腈化合物,(E)0〜150 (F)0.001-15重量份抗滴落剂,(G)0至45重量份三聚氰胺氰尿酸酯,和(H)0至15重量份的增塑填料, 当组分(B)的量为100重量份时,组分(G)的用量相对于组分(A)和(B)为100重量份,为0.5〜45重量份, 小于35重量份。 聚酯树脂组合物在模塑时几乎不腐蚀金属模具,并且阻燃性优异。