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81. 发明申请

US20040013926A1 Proton conductive solid polymer electrolyte and method for producing the same 失效
标题翻译：质子导电固体聚合物电解质及其制备方法
公开(公告)号：US20040013926A1
公开(公告)日：2004-01-22
申请号：US10623064
申请日：2003-07-18
申请人： Honda Giken Kogyo Kabushiki Kaisha
发明人： Hiroshi Akita , Teruaki Komiya
IPC分类号： H01M008/10
CPC分类号： C08J5/20 , C08G73/18 , C08J5/2275 , C08J2379/06 , H01B1/122 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1044 , H01M8/1048 , H01M8/1081 , H01M2300/0082 , Y02P70/56
摘要： A monomer to produce polybenzimidazole is dissolved in polyphosphoric acid. For example, polysulfated phenylene sulfonic acid (acidic group-possessing polymer) is further dissolved in this solution. In this procedure, the acidic group-possessing polymer and the monomer are adsorbed to one another in accordance with the acid-base interaction. When the monomer is polymerized, for example, by means of dehydration polymerization in this state, then polybenzimidazole is synthesized, and the polybenzimidazole and the acidic group-possessing polymer are compatibilized with each other to produce a compatibilized polymer. When the compatibilized polymer is deposited as a solid, and the solid is separated from polyphosphoric acid, then the compatibilized polymer is obtained. A proton conductive solid polymer electrolyte as a final product is manufactured by forming the compatibilized polymer to have a predetermined shape.
摘要翻译：将产生聚苯并咪唑的单体溶解在多磷酸中。例如，多硫酸化亚苯基磺酸（含酸性基团的聚合物）进一步溶解在该溶液中。在该方法中，具有酸性基团的聚合物和单体根据酸碱相互作用彼此吸附。当在该状态下，例如通过脱水聚合使单体聚合时，合成聚苯并咪唑，使聚苯并咪唑和含酸性基团的聚合物相互增容，生成相容化的聚合物。当相容的聚合物作为固体沉积，并且将固体与多磷酸分离时，获得相容的聚合物。作为最终产品的质子传导性固体聚合物电解质通过将相容化的聚合物形成为具有预定形状来制造。

82. 发明授权

US06548621B1 Synthesis of poly (imide-benzoxazole) copolymer 失效
标题翻译：聚（酰亚胺 - 苯并恶唑）共聚物的合成
公开(公告)号：US06548621B1
公开(公告)日：2003-04-15
申请号：US09986407
申请日：2001-11-08
申请人： Shih-Jung Tsai , Steve Lien-Chung Hsu , Yuan-Pin Huang
发明人： Shih-Jung Tsai , Steve Lien-Chung Hsu , Yuan-Pin Huang
IPC分类号： C08G7300
CPC分类号： C08G73/16 , C08G73/18 , C08G73/22 , Y10T428/29 , Y10T428/31721
摘要： The invention provides a poly(imide-benzoxazole) (PIBO) copolymer prepared from a trimellitic anhydride halide monomer and a bis(o-diaminophenol) monomer. The PIBO copolymer is characterized by the following recurring unit: wherein X is —O—, —S—, —C(CF3)2—, —C(CH3)2—, —CO—, —CH2—, —SO2—, —SO—, or deleted; and n is an integer. The PIBO copolymers of this invention are particularly useful as dielectric layers in semiconductor devices because they possess hydroxyl groups which create better adhesion to semiconductor substrates.
摘要翻译：本发明提供由偏苯三酸酐卤化物单体和双（邻 - 二氨基苯酚）单体制备的聚（酰亚胺 - 苯并恶唑）（PIBO）共聚物。 PIBO共聚物的特征在于以下重复单元：其中X是-O - ， - S - ， - C（CF 3）2 - ， - C（CH 3）2 - ， - CO - ， - CH 2 - -SO-或删除; 并且n是整数。本发明的PIBO共聚物特别可用作半导体器件中的介电层，因为它们具有产生对半导体衬底的更好粘附性的羟基。

83. 发明申请

US20030013817A1 High temperature ionic polymers and membranes made therefrom 审中-公开
标题翻译：高温离子聚合物和由其制成的膜
公开(公告)号：US20030013817A1
公开(公告)日：2003-01-16
申请号：US09888843
申请日：2001-06-26
发明人： Kelly Lu
IPC分类号： C08F116/00
CPC分类号： C08J5/2256 , B01D69/141 , B01D71/34 , B01D71/56 , B01D71/62 , B01D71/64 , B01D71/66 , B01D71/82 , C08G69/12 , C08G69/32 , C08G73/10 , C08G73/1067 , C08G73/18 , C08J2379/00 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/106 , H01M8/1072 , H01M2300/0082 , H01M2300/0088 , Y02P70/56
摘要： A novel class of high temperature ion-containing poly(aromatic) polymers is disclosed. They are Poly(aryl amide(nullCONHnull), sulfonyl amide (nullSO2NHnull), imide((nullCOnull)2Nnull), imidazole ((nullNHnull)(nullNnull)Cnull), oxazoles ((nullNHnull)(nullOnull)Cnull), thiazoles ((nullNHnull)(nullSnull)Cnull), amino (nullNHnull) group, ether (nullOnull), sulfide (nullSnull), sulfone (nullSO2null), or some combination of them) and they contain at least one type of ionic functional group selected from the following: (a) pendent ionic group: -Q-SO3(M), or -Q-SO2nullN(M)nullSO2nullR, or nullSO2nullN(M)nullSO2nullR (b) linking ionic group: nullSO2nullN(M)nullSO2null-Q-SO2nullN(M)nullSO2null-Q-SO2nullN(M)nullSO2-Q-wherein Q is a fluorinated alkylene or fluorinated alkoxylene group with carbon number from 1 to 12, and R is a fluorinated alkyl or fluorinated alkoxy group with carbon number from 1 to 12. M can be hydrogen H, lithium Li, sodium, Na, potassium K, and other suitable metal ions or organic bases. The new polymers can be random or blocked copolymers and can be crosslinked. The polymer can be made into polymeric membranes or composite membranes suitable for fuel cell, electrochemical applications, or selective permeable applications.
摘要翻译：公开了一类新型高温离子聚（芳族）聚合物。它们是聚（芳基酰胺（-CONH-），磺酰基（-SO 2 NH-），酰亚胺（（ - CO - ）2 N - ），咪唑（（-NH - ）（ - N = -NH - ）（ - O - ） - ） - 噻唑（（ - NH - ）（ - S-）C-） - 氨基（-NH-）基团，醚（-O-），硫化物，砜（-SO 2 - ）或它们的某种组合），并且它们含有至少一种选自以下的离子官能团：（a）侧离子基团：-Q-SO 3（M）或-Q- SO 2 -N（M）-SO 2 -R或-SO 2 -N（M）-SO 2 -R（b）连接离子基团：-SO 2 -N（M）-SO 2 -Q-SO 2 -N（M）-SO 2 - Q-SO 2 -N（M）-SO 2 -Q-其中Q是碳数为1至12的氟化亚烷基或氟化烷氧基，R为碳数为1至12的氟化烷基或氟化烷氧基 M可以是H，Li，Li，Na，Na，K，和其他合适的金属离子或有机碱。新的聚合物可以是无规或嵌段共聚物，并且可以是交联的。聚合物可以制成适用于燃料电池，电化学应用或选择性可渗透应用的聚合物膜或复合膜。

84. 发明申请

US20020028347A1 Polymer matrix electroluminescent materials and devices 审中-公开
标题翻译：聚合物基质电致发光材料和器件
公开(公告)号：US20020028347A1
公开(公告)日：2002-03-07
申请号：US09879752
申请日：2001-06-12
发明人： Matthew L. Marrocco III , Farshad J. Motamedi
IPC分类号： H05B033/14 , C09K011/06 , C09K011/08
CPC分类号： H01L51/0039 , C08G61/10 , C08G61/12 , C08G61/122 , C08G61/124 , C08G61/125 , C08G61/126 , C08G73/18 , C08G73/22 , C08G2261/12 , C08G2261/1523 , C08G2261/312 , C08G2261/52 , C08G2261/95 , C08K3/24 , C08L65/00 , C08L79/04 , C09D5/22 , C09D5/24 , C09D165/00 , C09D165/02 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/145 , C09K2211/1466 , C09K2211/182 , H01L51/0004 , H01L51/0035 , H01L51/0038 , H01L51/0043 , H01L51/0089 , H01L51/5008 , H01L51/5012 , H01L51/5016 , H01L51/5036 , H01L51/5056 , H01L51/5072 , H01L51/5206 , H01L51/5234 , H01L51/56 , H01L2251/306 , H05B33/14 , Y10T428/25
摘要： Photoluminescent and electroluminescent compositions are provided which comprise a matrix comprising aromatic repeat units and a luminescent metal ion or luminescent metal ion complex. Methods for producing such compositions, and the electroluminescent devices formed therefrom, are disclosed.
摘要翻译：提供了包含芳族重复单元和发光金属离子或发光金属离子络合物的基质的光致发光和电致发光组合物。公开了制备这种组合物的方法以及由其形成的电致发光器件。

85. 发明授权

US06335419B2 Polybenzazole and fiber thereof 失效
标题翻译：聚吲唑及其纤维
公开(公告)号：US06335419B2
公开(公告)日：2002-01-01
申请号：US09731394
申请日：2000-12-05
申请人： Go Matsuoka , Fuyuhiko Kubota
发明人： Go Matsuoka , Fuyuhiko Kubota
IPC分类号： C08G6300
CPC分类号： C08G75/32 , C08G73/18 , C08G73/22 , D01F6/74
摘要： A polybenzazoleolybenzazole having a residual content of a BB-PBZ monomer of not more than 0.010 wt %, which is obtained by dehydration polymerization condensation of an AA-PBZ monomer of the formula (I) wherein Ar is a quadrivalent aromatic organic residue and X is O, S or NH, and a BB-PBZ monomer of the formula (II) W—Z—W (II) wherein Z is an optionally substituted divalent aromatic organic residue and W is a carboxyl group or a group derived from the carboxyl group, which is reactive with —XH in the AA-PBZ monomer. Because the residual content of the BB-PBZ monomer in polybenzazole is not more than 0.010 wt %, a polybenzazole fiber having a small filament denier can be produced stably at a high speed without suffering from thread breakage during the production.
摘要翻译：通过其中Ar是四价芳族有机残基的式（I）的AA-PBZ单体和X是通过其脱水聚合缩合获得的具有不大于0.010重量％的BB-PBZ单体的残留含量的聚苯并唑聚吲哚 O，S或NH，和式（II）的BB-PBZ单体，其中Z是任选取代的二价芳族有机残基，W是羧基或衍生自羧基的基团，其与-XH的反应性 AA-PBZ单体。由于聚吲哚中的BB-PBZ单体的残留量不大于0.010重量％，所以可以高速稳定地制造具有小丝旦数的聚吲哚纤维，而在生产过程中不会发生断线。

86. 发明授权

US5919890A Method for production of polybenzazole 失效
标题翻译：生产聚吲哚的方法
公开(公告)号：US5919890A
公开(公告)日：1999-07-06
申请号：US835850
申请日：1997-04-30
申请人： Kiyoshi Hotta , Fuyuhiko Kubota , Yoshio Araki , Masakatsu Ohguchi
发明人： Kiyoshi Hotta , Fuyuhiko Kubota , Yoshio Araki , Masakatsu Ohguchi
IPC分类号： C08G73/18 , C08G73/22 , C08G75/00 , C08G75/32 , C08G63/00
CPC分类号： C08G73/22 , C08G73/18 , C08G75/32
摘要： A method for producing polybenzazole, which comprises reacting a PBZ monomer salt with an AA-PBZ monomer or a BB-PBZ monomer in a non-oxidizing solvent having a dehydrating action to give an oligomer, and adding the AA-PBZ monomer or BB-PBZ monomer, which has not been subjected to the above reaction, to allow reaction with the oligomer, whereby to give a polymer having a desired polymerization degree. According to this method, the polymerization degree of the polymer to be obtained finally and of the polymer during production process can be easily controlled.
摘要翻译：一种生产聚吲哚的方法，其包括在具有脱水作用的非氧化性溶剂中使PBZ单体盐与AA-PBZ单体或BB-PBZ单体反应得到低聚物，并加入AA-PBZ单体或BB- 没有进行上述反应的PBZ单体，使其与低聚物反应，得到具有所需聚合度的聚合物。根据该方法，可以容易地控制最终得到的聚合物的聚合度和制备过程中聚合物的聚合度。

87. 发明授权

US5856384A Polycyclic aromatic compounds having nonlinear optical properties 失效
标题翻译：具有非线性光学性质的多环芳族化合物
公开(公告)号：US5856384A
公开(公告)日：1999-01-05
申请号：US305426
申请日：1994-09-13
申请人： Anthony F. Garito , Shinji Yamada , Anna Panackal
发明人： Anthony F. Garito , Shinji Yamada , Anna Panackal
IPC分类号： G02B6/12 , B32B7/02 , B32B9/00 , C07D471/14 , C07D471/22 , C08G73/00 , C08G73/06 , C08G73/10 , C08G73/18 , C08G73/22 , C08K5/3447 , G02B6/122 , G02B6/125 , G02B6/28 , G02F1/01 , G02F1/065 , G02F1/313 , G02F1/35 , G02F1/355 , G02F1/361
CPC分类号： C08G73/22 , C08G73/0672 , C08G73/18 , C08K5/3447 , G02B6/1221 , G02B6/125 , G02F1/065 , G02F1/3132 , G02F1/3612 , G02F1/3613 , G02F1/3615 , G02F1/3616 , G02F1/3617 , G02B2006/12147 , G02B2006/2865 , Y10T428/31721
摘要： Devices and materials containing certain stable, polycyclic aromatic compounds exhibit sensible, second order nonlinear optical effects. In general, useful polycyclic aromatic compounds possess electron-donating and electron-withdrawing chemical functionality but no center of inversion symmetry on either the molecular or crystalline unit cell level.
摘要翻译：含有某些稳定的多环芳族化合物的装置和材料表现出明显的二阶非线性光学效应。通常，有用的多环芳族化合物具有给电子和吸电子化学官能团，但在分子或晶体单元电池水平上没有反转对称中心。

88. 发明授权

US5827927A Macromonomers having reactive end groups 失效
标题翻译：具有反应性端基的大分子单体
公开(公告)号：US5827927A
公开(公告)日：1998-10-27
申请号：US645914
申请日：1996-05-14
申请人： Robert R. Gagne , Matthew Louis Marrocco, III , Mark Steven Trimmer , Neil H. Hendricks
发明人： Robert R. Gagne , Matthew Louis Marrocco, III , Mark Steven Trimmer , Neil H. Hendricks
IPC分类号： C08F299/02 , C07C225/16 , C07C225/22 , C07C235/84 , C07C255/56 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/452 , C07D209/76 , C07D295/192 , C07D303/22 , C07D303/36 , C07D303/46 , C08F4/46 , C08F290/00 , C08F290/06 , C08F290/14 , C08G8/28 , C08G61/00 , C08G61/02 , C08G61/10 , C08G61/12 , C08G63/00 , C08G63/181 , C08G63/685 , C08G64/06 , C08G64/12 , C08G64/42 , C08G69/00 , C08G69/02 , C08G69/20 , C08G69/26 , C08G69/32 , C08G69/36 , C08G73/06 , C08G73/18 , C08G85/00 , C08L67/00 , C08L67/02 , C08L69/00 , C08L71/12 , C08L85/00 , C08F8/00
CPC分类号： C07D207/404 , C07C225/16 , C07C225/22 , C07C235/84 , C07C255/56 , C07D207/452 , C07D209/76 , C07D295/192 , C07D303/22 , C07D303/36 , C07D303/46 , C08F290/06 , C08F290/14 , C08F290/141 , C08G61/00 , C08G61/02 , C08G63/181 , C08G63/6856 , C08G64/06 , C08G64/12 , C08G69/02 , C08G69/20 , C08G69/26 , C08G69/32 , C08G69/36 , C08G73/0622 , C08G73/0627 , C08G73/0633 , C08G73/0638 , C08G73/18 , C08G8/28 , C08G85/00 , C08L67/00 , C08L67/02 , C08L69/00 , C08L71/126 , C08L85/00 , C07C2102/06 , C07C2103/18 , C08G2261/312
摘要： A soluble rigid-rod macromonomer is provided which has the following formula: ##STR1## wherein each A.sub.1, A.sub.2, A.sub.3, and A.sub.4, on each monomer unit, independently, is C or N, and each G.sub.1, G.sub.2, G.sub.3, and G.sub.4, on each monomer unit, independently, is H or a solubilizing side group, provided that at least one monomer unit has at least one solubilizing side group. The solubilizing side groups provide the macromonomers with a solubility of at least 0.5% by weight in the solvent system from which they are formed. E is a reactive end group, and the macromonomer has an average degree of polymerization, DP.sub.n, greater than 6. Such macromonomers are chemically incorporated into polymer systems to provide stronger stiffened polymers.
摘要翻译：提供了一种可溶性刚性棒状大分子单体，其具有下式：其中每个单体单元上的每个A1，A2，A3和A4各自独立地为C或N，每个G1，G2，G3和G4 在每个单体单元上，独立地是H或增溶侧基，条件是至少一个单体单元具有至少一个增溶侧基。增溶侧基为大分子单体在其形成的溶剂体系中提供至少0.5重量％的溶解度。 E是反应性端基，并且大分子单体的平均聚合度DPn大于6.这些大分子单体被化学地掺入到聚合物体系中以提供更强的加强聚合物。

89. 发明授权

US5770121A Solid state coagulation of optical quality polymer thin films 失效
标题翻译：固态凝聚光学优质聚合物薄膜
公开(公告)号：US5770121A
公开(公告)日：1998-06-23
申请号：US759819
申请日：1996-11-18
申请人： Chyi-Shan Wang , Jar-Wha Lee , D. Mark Husband
发明人： Chyi-Shan Wang , Jar-Wha Lee , D. Mark Husband
IPC分类号： B01D67/00 , B01D71/62 , B01D71/66 , B29C35/16 , B29C37/00 , B29D7/01 , C08G73/18 , C08G73/22 , C08G75/32 , B29D7/00
CPC分类号： C08G75/32 , B01D67/0013 , B01D67/0016 , B01D71/62 , B01D71/66 , B29C35/16 , B29C37/0092 , B29D7/01 , C08G73/18 , C08G73/22 , B01D2323/12 , B29K2105/0079
摘要： A method for preparing optical quality, thin films of polymers and co-polymers, as well as blends of such polymers or co-polymers with flexible polymers and co-polymers which comprises (a) preparing a solution of the polymer or co-polymer or blend in a suitable solvent; (b) forming a film from the solution; (c) cooling the thus-formed film to a temperature below the freezing point of the solvent; and (d) dissolving the solvent out of said film at a temperature below the melting point of the solvent. This method can be employed to prepare films of high optical clarity for electro-optical device applications. Because of their thermal stability, mechanical strength and chemical resistance, films prepared according to this method can also be used as filters and separation membranes.
摘要翻译：制备光学质量的方法，聚合物和共聚物的薄膜，以及这些聚合物或共聚物与柔性聚合物和共聚物的共混物，其包括（a）制备聚合物或共聚物的溶液或在合适的溶剂中混合; （b）从溶液中形成膜; （c）将如此形成的膜冷却至低于溶剂凝固点的温度; 和（d）在低于溶剂熔点的温度下将溶剂溶解在所述膜中。该方法可用于制备用于电光器件应用的高光学透明度的膜。由于其热稳定性，机械强度和耐化学性，根据该方法制备的膜也可用作过滤器和分离膜。

90. 发明授权

US5374706A Liquid crystalline polymer compositions process, and products 失效
标题翻译：液晶聚合物组合物工艺和产品
公开(公告)号：US5374706A
公开(公告)日：1994-12-20
申请号：US136430
申请日：1993-10-13
申请人： James F. Wolfe , Paul D. Sybert , Joanne R. Sybert
发明人： James F. Wolfe , Paul D. Sybert , Joanne R. Sybert
IPC分类号： C08G73/18 , C08G75/32 , C08G85/00 , C08L57/00 , C09K19/38 , C08G73/22
CPC分类号： C09K19/3823 , C08G73/18 , C08G75/32 , C08G85/00 , C08L57/00 , Y10S428/902
摘要： Novel compositions comprising a high concentration of one or more extended chain homopolymer, copolymer, or block polymer and certain polyphosphoric acids are prepared. Such compositions are optically anisotropic (liquid crystalline), capable of exhibiting excellent cohesive strength, and are especially suited to the production of high molecular weight ordered polymer fibers by dry-jet wet spinning. These liquid crystalline compositions are capable of being drawn through long air gap distances and spun at exceptionally high spin draw ratios. Fibers, films and other articles formed from these liquid crystalline compositions exhibit exceptionally high physical and heat resistant properties.
摘要翻译：制备包含高浓度一种或多种延伸链均聚物，共聚物或嵌段聚合物和某些多磷酸的新型组合物。这种组合物是光学各向异性（液晶），能够表现出优异的内聚强度，并且特别适用于通过干喷湿法纺丝生产高分子量有序聚合物纤维。这些液晶组合物能够通过长的气隙距离被拉伸并以非常高的旋转拉伸比旋转。由这些液晶组合物形成的纤维，薄膜和其它制品表现出极高的物理和耐热性能。

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