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81. 发明申请

US20090054703A1 Catalytic Conversion of Ethanol and Methanol to an Isobutanol-Containing Reaction Product Using a Thermally Decomposed Hydrotalcite/Metal 有权
标题翻译：使用热分解水滑石/金属将乙醇和甲醇催化转化为含异丁醇的反应产物
公开(公告)号：US20090054703A1
公开(公告)日：2009-02-26
申请号：US12196602
申请日：2008-08-22
申请人： Kostantinos Kourtakis , Michael B. D'Amore , Leo Ernest Manzer
发明人： Kostantinos Kourtakis , Michael B. D'Amore , Leo Ernest Manzer
IPC分类号： C07C29/00
CPC分类号： C07C29/34 , C07C31/12
摘要： Hydrotalcite/metal carbonate combinations are partially or fully thermally decomposed to provide catalysts useful for the conversion of ethanol and methanol to a reaction product comprising isobutanol.
摘要翻译：水滑石/金属碳酸盐组合部分或完全热分解以提供可用于将乙醇和甲醇转化为包含异丁醇的反应产物的催化剂。

82. 发明授权

US07453015B2 Process for the preparation of alkylene glycols 失效
标题翻译：亚烷基二醇的制备方法
公开(公告)号：US07453015B2
公开(公告)日：2008-11-18
申请号：US11461334
申请日：2006-07-31
申请人： Eugene Marie Godfried Andre Van Kruchten , Hendrik Stichter , Johannes Theodorus Gertruda Wijenberg
发明人： Eugene Marie Godfried Andre Van Kruchten , Hendrik Stichter , Johannes Theodorus Gertruda Wijenberg
IPC分类号： C07C29/00
CPC分类号： C07C29/106 , Y02P20/52 , C07C31/202
摘要： A process for the conversion of an alkylene oxide to the corresponding alkylene glycol in the presence of a catalytic composition, carbon dioxide and water, wherein the catalytic composition comprises a halide, a metalate and optionally a macrocyclic chelating compound.
摘要翻译：一种在催化组合物，二氧化碳和水的存在下将烯化氧转化成相应的亚烷基二醇的方法，其中催化组合物包含卤化物，金属盐和任选的大环螯合化合物。

83. 发明申请

US20080228014A1 Hydrogenolysis of Glycerol and Products Produced Therefrom 有权
标题翻译：甘油及其产生的产物的氢解
公开(公告)号：US20080228014A1
公开(公告)日：2008-09-18
申请号：US12130124
申请日：2008-05-30
申请人： Paul Bloom
发明人： Paul Bloom
IPC分类号： C07C29/00
CPC分类号： C07C29/60 , C07C31/205
摘要： Processes for the hydrogenolysis of glycerol, as well as products produced therefrom are disclosed.
摘要翻译：公开了甘油氢解方法以及由此产生的产物。

84. 发明申请

US20080227118A1 Protein Immobilization Method and Quantification Method 审中-公开
标题翻译：蛋白质固定化方法和定量方法
公开(公告)号：US20080227118A1
公开(公告)日：2008-09-18
申请号：US10585985
申请日：2005-01-21
申请人： Naoyuki Kohno , Hitoshi Uemori , Takahiro Nishibu , Kazunari Hirayasu , Yoshiteru Kobayashi , Takashi Yokoyama
发明人： Naoyuki Kohno , Hitoshi Uemori , Takahiro Nishibu , Kazunari Hirayasu , Yoshiteru Kobayashi , Takashi Yokoyama
IPC分类号： G01N33/543 , C07K17/00 , G01N33/567 , C07C315/00 , C07C61/00 , C07C29/00 , G01N33/68
CPC分类号： C07K17/02 , G01N33/543 , G01N33/6896 , G01N2800/2828
摘要： The present invention relates to a method for immobilizing a protein in a sample, which could not easily be immobilized by the conventional immobilization method, to a solid-phase; a method for quantitative determination of protein wherein an effect of inhibitory substance coexisting in a sample prepared using the immobilization method can be reduced; and a rapid and highly precise method for detecting an abnormal PrP and a method for determining BSE using the immobilization method as compared with the conventional method. The present invention provides: “a method for immobilizing a protein to a solid-phase comprising contacting the protein with the solid-phase having hydrophobic surface in the presence of a lower alcohol, and a halogenocarboxylic acid and/or a long chain alkyl sulfate, and an immobilizing reagent solution to be used therefor; a method for quantitative determination of protein comprising contacting a protein-staining solution with the solid-phase immobilized with a protein by the immobilization method, and determining a degree of color development generated thereby; an immunoblotting method wherein the solid-phase immobilized with a protein by the immobilization method is used; and a method for detecting an abnormal PrP a method for determining BSE by using the immobilization method.”
摘要翻译：本发明涉及通过常规固定方法将样品中的蛋白质固定化为固相的方法，用于定量测定蛋白质的方法，其中可以减少使用固定化方法制备的样品中共存的抑制物质的作用; 以及用于检测异常PrP的快速且高精度的方法以及与常规方法相比使用固定方法确定BSE的方法。本发明提供：“将蛋白质固定在固相中的方法，包括在低级醇和卤代羧酸和/或长链烷基硫酸盐的存在下使蛋白质与具有疏水性表面的固相接触，和用于其的固定试剂溶液;一种用于定量测定蛋白质的方法，包括通过固定方法使蛋白质染色溶液与固定有蛋白质的固相接触，并确定由此产生的显色程度;免疫印迹使用通过固定化方法固定有蛋白质的固相的方法;以及通过使用固定化方法来检测异常PrP的方法来测定BSE的方法。

85. 发明申请

US20080207957A1 Method For The Production Of Isopulegol 有权
标题翻译：异丙醇的生产方法
公开(公告)号：US20080207957A1
公开(公告)日：2008-08-28
申请号：US11722395
申请日：2005-12-17
申请人： Marko Friedrich , Klaus Ebel , Norbert Gotz
发明人： Marko Friedrich , Klaus Ebel , Norbert Gotz
IPC分类号： C07C29/00 , C07C35/08
CPC分类号： C07C29/56 , C07B2200/07 , C07C2601/14 , C07C35/17
摘要： The present invention relates to a process for the preparation of isopulegol of formula (I): comprising the cyclization of citronellal of formula (II): in the presence of a tris(aryloxy)aluminum catalyst, wherein the cyclization is carried out in the presence of I. at least one acid and/or II. at least one compound selected from the group comprising carboxylic anhydrides, aldehydes, ketones and vinyl ethers.
摘要翻译：本发明涉及一种制备式（I）异丙醇的方法：包括式（II）的香茅醛的环化：在三（芳氧基）铝催化剂存在下，其中环化在存在下进行至少一种酸和/或II。至少一种选自羧酸酐，醛，酮和乙烯基醚的化合物。

86. 发明申请

US20080015397A1 Process for making isooctenes from aqueous 1-butanol 审中-公开
标题翻译：从1-丁醇水溶液中制备异辛烯的方法
公开(公告)号：US20080015397A1
公开(公告)日：2008-01-17
申请号：US11818445
申请日：2007-06-13
申请人： Michael D'Amore , Leo Ernest Manzer , Edward Miller , Jeffrey Knapp
发明人： Michael D'Amore , Leo Ernest Manzer , Edward Miller , Jeffrey Knapp
IPC分类号： C07C1/20 , C07C29/00 , C07C41/01
CPC分类号： C07C29/04 , C07C1/20 , C07C5/03 , C07C9/21 , C07C41/06 , C07C2521/08 , C07C2527/054 , C07C2529/18 , C07C2529/40 , C07C2531/08 , C07C2531/10 , C10G2300/4006 , C10G2300/4012 , C10G2300/805 , C10G2400/22 , Y02E50/343 , C07C11/02 , C07C31/12 , C07C31/125 , C07C43/04
摘要： The present invention relates to a catalytic process for making isooctenes using a reactant comprising 1-butanol and water. The isooctenes so produced are useful for the production of fuel additives.
摘要翻译：本发明涉及使用包含1-丁醇和水的反应物制备异辛烯的催化方法。所生产的异辛烯可用于生产燃料添加剂。

87. 发明申请

US20070265360A1 Catalyst and Process for the Synthesis of C2-Oxygenates by the Hydrogenation of Carbon Monoxide 审中-公开
标题翻译：催化剂和通过一氧化碳氢化合成C2-氧化物的方法
公开(公告)号：US20070265360A1
公开(公告)日：2007-11-15
申请号：US11630361
申请日：2004-06-23
申请人： Hongyuan Luo , Yunjie Ding , Hongmei Yin
发明人： Hongyuan Luo , Yunjie Ding , Hongmei Yin
IPC分类号： B01J21/06 , B01D53/02 , C07C29/00
CPC分类号： B01J37/0201 , B01J21/08 , B01J23/8986 , C07C29/158 , C07C45/49 , C07C51/10 , C07C47/06 , C07C53/08 , C07C31/08
摘要： A catalyst is invented for the synthesis of C2-oxygenates by the hydrogenation of CO. The catalyst is composed of Rh—Mn—Fe-M1-M2/Si02, among them Mn, Fe, M1 and M2 and additives. M1 can be Li or Na while M2 can be Ru or Ir. The content of Rh is 0.1-3% by weight; the weight ratio of Mn/Rh is 0.5-12, the weight ratio of Fe/Rh is 0.01-0.5, the weight ratio of M1/Rh is 0.01-1 and the weight ratio of M2/Rh is 0.1-1.0. The catalyst is prepared by impregnation of the solution of corresponding compounds of each component in desired amount onto the carrier of Si02, which is followed by drying at 283-473 K. Before using, the catalyst is reduced by hydrogen or hydrogen-containing gas at 573-673 K for at least one hour after drying or after calcinations at 473-673 K for 2-20 h. These catalysts can convert CO and H2 into ethanol, acetaldehyde, acetic acid and other C2-oxygenates at a high conversion and a high selectivity under mild conditions.
摘要翻译：催化剂是通过CO的氢化来合成C 2 O - 氧化合物的。催化剂由Rh-Mn-Fe-M 1 -M 2 / MnO 2，其中Mn，Fe，M 1和M 2以及添加剂。 M 1可以是Li或Na，而M 2可以是Ru或Ir。 Rh的含量为0.1-3重量％ Mn / Rh的重量比为0.5-12，Fe / Rh的重量比为0.01-0.5，M 1 / Rh / Rh的重量比为0.01-1，M < SUB> 2 / Rh为0.1-1.0。通过将所需量的各组分的相应化合物溶液浸渍到SiO 2载体上制备催化剂，然后在283-473K下干燥。在使用之前，催化剂被还原通过氢气或含氢气体在573-673K下干燥至少1小时或在473-673K煅烧2-20小时后。这些催化剂可以在温和条件下以高转化率和高选择性将CO和H 2 H 2转化成乙醇，乙醛，乙酸和其它C 2 O 3 - 氧化合物。

88. 发明授权

US07250537B2 Method of hydrogenating phenol 失效
标题翻译：氢化苯酚的方法
公开(公告)号：US07250537B2
公开(公告)日：2007-07-31
申请号：US10553792
申请日：2004-03-30
申请人： Masayuki Shirai , Chandrashekhar Vasant Rode , Uday Dattopant Joshi , Kazuo Torii , Takafumi Sato
发明人： Masayuki Shirai , Chandrashekhar Vasant Rode , Uday Dattopant Joshi , Kazuo Torii , Takafumi Sato
IPC分类号： C07C45/00 , C07C27/00 , C07C29/00
CPC分类号： C07C29/20 , C07C29/145 , C07C45/006 , C07C2601/14 , C07C2602/10 , C07C2602/28 , Y02P20/52 , C07C49/403 , C07C49/67 , C07C35/08 , C07C35/36
摘要： The present invention provides a novel method of hydrogenating a phenol for hydrogenating a phenol industrially advantageously. The present invention relates, in the case of phenol hydrogenation in which carbon dioxide is made to participate in the reaction, to a method of hydrogenating a phenol characterized by using a supported rhodium and/or ruthenium catalyst, whereby the phenol is hydrogenated efficiently at a lower reaction temperature than with prior art; such a method characterized in that carbon dioxide having a temperature of 20 to 250° C. and a pressure of 0.1 to 50 MPa is used as the carbon dioxide; and such a method characterized in that hydrogen under conditions of a temperature of 20 to 250° C. and a pressure of 0.1 to 50 MPa is used.An environmentally friendly phenol hydrogenation process that uses no harmful organic solvents can be realized.
摘要翻译：本发明提供了一种氢化苯酚以在工业上有利地氢化酚的新方法。本发明涉及在其中使二氧化碳参与反应的苯酚氢化的情况下，以使用负载的铑和/或钌催化剂为特征的苯酚氢化方法，由此苯酚在比现有技术低的反应温度; 这种方法的特征在于使用温度为20〜250℃，压力为0.1〜50MPa的二氧化碳作为二氧化碳; 其特征在于，在温度为20〜250℃，压力为0.1〜50MPa的条件下使用氢。可以实现不使用有害有机溶剂的环保酚加氢方法。

89. 发明授权

US07176336B2 Process for the synthesis of unsaturated alcohols 有权
标题翻译：合成不饱和醇的方法
公开(公告)号：US07176336B2
公开(公告)日：2007-02-13
申请号：US10940403
申请日：2004-09-14
申请人： Bob R. Maughon , Kenneth A. Burdett , Zenon Lysenko
发明人： Bob R. Maughon , Kenneth A. Burdett , Zenon Lysenko
IPC分类号： C07C29/00 , C07C33/025 , C07C33/03
CPC分类号： C07C29/095 , C07C67/293 , C07C67/333 , C07C67/475 , C07C69/007 , C07C69/533 , C07C69/593 , C07C69/145 , C07C33/03 , C07C33/035
摘要： A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.
摘要翻译：一种制备不饱和醇（烯烃）的方法，例如均聚单醇或均烯基多元醇，包括保护羟基取代的不饱和脂肪酸或脂肪酸酯如蓖麻油酸甲酯，其衍生自种子油，形成羟基保护的不饱和脂肪酸或脂肪酸酯; 羟基保护的不饱和脂肪酸或脂肪酸酯的均匀化或交叉变性以产生含有羟基保护的非饱和复分解产物的产物混合物; 并在足以制备不饱和醇的条件下脱保护羟基保护的不饱和复分解产物。优选地，蓖麻油酸甲酯通过交叉复分解或均一复分解转化成均相烯醇1-癸烯-4-醇或均烯基多元醇9-十八碳烯-7,12-二醇。

90. 发明授权

US07173138B2 Ligands for pnicogen chelate complexes with a metal of subgroup VIII and use of the complexes as catalysts for hydroformylation, carbonylation, hydrocyanation or hydrogenation 有权
标题翻译：用于第VIII族金属的pnicogen螯合物的配体和该配合物用作加氢甲酰化，羰基化，氢氰化或氢化的催化剂
公开(公告)号：US07173138B2
公开(公告)日：2007-02-06
申请号：US10473216
申请日：2002-03-28
申请人： Wolfgang Ahlers , Rocco Paciello , Dieter Vogt , Peter Hofmann
发明人： Wolfgang Ahlers , Rocco Paciello , Dieter Vogt , Peter Hofmann
IPC分类号： C07F9/572 , C07C29/00 , C07C29/03 , B01J31/02
CPC分类号： C07F15/065 , B01J31/186 , B01J31/187 , B01J31/28 , B01J2231/321 , B01J2231/323 , B01J2231/645 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/505 , C07F9/572 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07F9/6596 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07C31/125 , C07C47/02
摘要： Pnicogen chelate compounds which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII which are useful as catalysts for the hydroformylation of olefins.
摘要翻译：具有两个含有气相的基团的Pnicogen螯合物通过呫吨样或类三环类似的分子骨架彼此连接，并且其中至少一个吡咯基团通过其氮原子与每个原子核原子共价结合形成与过渡金属的复合物可用作烯烃加氢甲酰化的催化剂的VIII族。

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