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    • 7. 发明授权
    • Stimulation of biogenic gas generation in deposits of carbonaceous material
    • 刺激碳质材料沉积物中生物气产生
    • US08656992B2
    • 2014-02-25
    • US13913731
    • 2013-06-10
    • Ciris Energy, Inc.
    • Robert Downey
    • E21B43/22E21B43/16
    • C12P5/023E21B43/006Y02E50/343
    • The invention relates to treating of subterranean formations to increase the susceptibility (by way of chemical break down or solubilization, but not necessarily limited by these or any other theories) of large carbonaceous molecules therein, such as comprise coal, to bioconversion into methane and other useful hydrocarbon products by indigenous and/or non-indigenous microbial consortia, by introducing into the subterranean formations: (a) a solution containing at least one of an oxoacid ester of phosphorus or a thioacid ester of phosphorus; and (b) one or more other chemical compounds/chemical entities selected from the group consisting of: hydrogen, carboxylic acids, esters of carboxylic acids, salts of carboxylic acids, oxoacids of phosphorus, salts of oxoacids of phosphorus, vitamins, minerals, mineral salts, metals, and yeast extracts. In an additional embodiment the treating of the subterranean formation further comprises introducing into the subterranean formation a microbial consortia (preferably comprised of methanogens).
    • 本发明涉及地下地层的处理,以增加其中大量含碳分子(如煤)的化学敏感性(通过化学分解或溶解,但不一定受这些或任何其他理论的限制),以生物转化为甲烷和其他 土壤和/或非土着微生物联合体的有用的烃产品通过引入到地层中:(a)含有磷的含氧酸酯或磷的硫代酸酯中的至少一种的溶液; 和(b)一种或多种其它选自以下的化合物/化学实体:氢,羧酸,羧酸的酯,羧酸的盐,磷的含氧,磷的含氧盐,维生素,矿物质,矿物质 盐,金属和酵母提取物。 在另外的实施方案中,地下地层的处理还包括向地下地层引入微生物菌群(优选由产甲烷菌组成)。
    • 9. 发明申请
    • Stimulation of Biogenic Gas Generation in Deposits of Carbonaceous Material
    • 刺激碳质材料沉积物中生物气体的产生
    • US20130264052A1
    • 2013-10-10
    • US13913731
    • 2013-06-10
    • Robert Downey
    • Robert Downey
    • C12P5/02E21B43/00
    • C12P5/023E21B43/006Y02E50/343
    • The invention relates to treating of subterranean formations to increase the susceptibility (by way of chemical break down or solubilization, but not necessarily limited by these or any other theories) of large carbonaceous molecules therein, such as comprise coal, to bioconversion into methane and other useful hydrocarbon products by indigenous and/or non-indigenous microbial consortia, by introducing into the subterranean formations: (a) a solution containing at least one of an oxoacid ester of phosphorus or a thioacid ester of phosphorus; and (b) one or more other chemical compounds/chemical entities selected from the group consisting of: hydrogen, carboxylic acids, esters of carboxylic acids, salts of carboxylic acids, oxoacids of phosphorus, salts of oxoacids of phosphorus, vitamins, minerals, mineral salts, metals, and yeast extracts. In an additional embodiment the treating of the subterranean formation further comprises introducing into the subterranean formation a microbial consortia (preferably comprised of methanogens).
    • 本发明涉及地下地层的处理,以增加其中大量含碳分子(如煤)的化学敏感性(通过化学分解或溶解,但不一定受这些或任何其他理论的限制),以生物转化为甲烷和其他 土壤和/或非土着微生物联合体的有用的烃产品通过引入到地层中:(a)含有磷的含氧酸酯或磷的硫代酸酯中的至少一种的溶液; 和(b)一种或多种其它选自以下的化合物/化学实体:氢,羧酸,羧酸的酯,羧酸的盐,磷的含氧,磷的含氧盐,维生素,矿物质,矿物质 盐,金属和酵母提取物。 在另外的实施方案中,地下地层的处理还包括向地下地层引入微生物菌群(优选由产甲烷菌组成)。
    • 10. 发明授权
    • Stimulation of biogenic gas generation in deposits of carbonaceous material
    • 刺激碳质材料沉积物中生物气产生
    • US08459349B2
    • 2013-06-11
    • US12455431
    • 2009-06-02
    • Robert Downey
    • Robert Downey
    • E21B43/22E21B43/16
    • C12P5/023E21B43/006Y02E50/343
    • The invention relates to treating of subterranean formations to increase the susceptibility (by way of chemical break down or solubilization, but not necessarily limited by these or any other theories) of large carbonaceous molecules therein, such as comprise coal, to bioconversion into methane and other useful hydrocarbon products by indigenous and/or non-indigenous microbial consortia, by introducing into the subterranean formations: (a) a solution containing at least one of an oxoacid ester of phosphorus or a thioacid ester of phosphorus; and (b) one or more other chemical compounds/chemical entities selected from the group consisting of: hydrogen, carboxylic acids, esters of carboxylic acids, salts of carboxylic acids, oxoacids of phosphorus, salts of oxoacids of phosphorus, vitamins, minerals, mineral salts, metals, and yeast extracts. In an additional embodiment the treating of the subterranean formation further comprises introducing into the subterranean formation a microbial consortia (preferably comprised of methanogens).
    • 本发明涉及地下地层的处理,以增加其中大量含碳分子(如煤)的化学敏感性(通过化学分解或溶解,但不一定受这些或任何其他理论的限制),以生物转化为甲烷和其他 土壤和/或非土着微生物联合体的有用的烃产品通过引入到地层中:(a)含有磷的含氧酸酯或磷的硫代酸酯中的至少一种的溶液; 和(b)一种或多种其它选自以下的化合物/化学实体:氢,羧酸,羧酸的酯,羧酸的盐,磷的含氧,磷的含氧盐,维生素,矿物质,矿物质 盐,金属和酵母提取物。 在另外的实施方案中,地下地层的处理还包括向地下地层引入微生物菌群(优选由产甲烷菌组成)。