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    • 1. 发明授权
    • Thermoplastic molding materials comprising organic black pigments
    • 包含有机黑色颜料的热塑性成型材料
    • US08796365B2
    • 2014-08-05
    • US12666937
    • 2008-06-24
    • Christian MaletzkoRüdiger BluhmBernd TrotteGunter SchererArno Bohm
    • Christian MaletzkoRüdiger BluhmBernd TrotteGunter SchererArno Bohm
    • C08K5/09C08K5/20C08K5/101C08K5/3447
    • C08K5/0041C08K5/3447C09B5/62F21V7/22
    • The invention relates to thermoplastic molding compositions comprising (A) from 34 to 99.99% by weight of at least one thermoplastic polymer selected from (i) polyarylene ethers, (ii) polyetherimides, (iii) polyarylene sulfides, and (iv) polycarbonates with glass transition temperature of at least 145° C., or else copolymers of the abovementioned polymers (i) to (iv), (B) from 0.01 to 10% by weight of at least one organic black pigment which is transparent in the range from 1000 nm to 1600 nm and which has thermal stability up to at least 300° C. to DIN EN 12877-1, (C) from 0 to 6% by weight of at least one mold-release agent selected from fatty acids, or from esters and amides, (D) from 0 to 50% by weight of one or more additives, where the total of the % by weight figures from (A), (B), (C) and (D) gives 100% by weight. The invention further relates to a process for preparation of the thermoplastic molding compositions, and to the moldings obtainable therefrom. Finally, the invention relates to the use of the thermoplastic molding compositions for reducing heat accumulation in plastics components, moldings, foils, or membranes.
    • 本发明涉及热塑性模塑组合物,其包含(A)34至99.99重量%的至少一种热塑性聚合物,其选自(i)聚亚芳基醚,(ii)聚醚酰亚胺,(iii)聚亚芳基硫醚,和(iv)具有玻璃的聚碳酸酯 转化温度至少为145℃,或者上述聚合物(i)至(iv),(B)的共聚物为0.01至10重量%的至少一种有机黑色颜料,其透明度为1000 nm至1600nm,并且根据DIN EN 12877-1,(C)具有至多300℃的热稳定性,0至6重量%的至少一种选自脂肪酸的脱模剂或来自酯的脱模剂 和(A),(B),(C)和(D)的重量%的总重量为100重量%的(D)0〜50重量%的一种或多种添加剂。 本发明还涉及一种制备热塑性模塑组合物的方法以及由其获得的模制品。 最后,本发明涉及热塑性模塑组合物用于减少塑料部件,模制品,箔或膜中的热积聚的用途。
    • 8. 发明授权
    • Substituted quaterrylene tetracarboxylic acid diimides
    • 取代的四亚甲基四羧酸二酰亚胺
    • US5986099A
    • 1999-11-16
    • US860928
    • 1997-07-21
    • Klaus MullenHeribert QuanteArno Bohm
    • Klaus MullenHeribert QuanteArno Bohm
    • C07D221/18C07D471/06C09B5/62C09B57/08
    • C07D221/18C09B5/62
    • Quaterrylenetetracarboxylic diimides I ##STR1## where R is hydrogen;C.sub.1 -C.sub.30 -alkyl whose carbon chain may be interrupted by one or e of --O--, --S--, --NR.sup.1 --, --CO-- and/or --SO.sub.2 -- and which may be monosubstituted or polysubstituted by cyano, C.sub.1 -C.sub.6 -alkoxy or a 5-, 6- or 7-membered heterocyclic radical which is attached via a nitrogen atom and which may contain further heteroatoms and may be aromatic, whereR.sup.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl;C.sub.5 -C.sub.8 -cycloalkyl whose carbon skeleton may be interrupted by one or more of --O--, --S-- and/or --NR.sup.1 --;aryl or hetaryl, which may each be monosubstituted or poly-substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.6 -alkoxy, cyano, --CONHR.sup.2, --NHCOR.sup.2 and/or aryl- or hetaryl-azo, which may each be substituted by C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.6 -alkoxy or cyano, whereR.sup.2 is hydrogen; C.sub.1 -C.sub.18 -alkyl; aryl or hetaryl, which may each be substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen or cyano;X is halogen; C.sub.1 -C.sub.18 -alkyl; aryloxy, arylthio, hetaryloxy or hetarylthio, which may each be substituted by C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy;n is from 2 to 12,their preparation and use as pigments or fluorescent dyes.
    • PCT No.PCT / EP96 / 00118 Sec。 371日期1997年7月21日 102(e)日期1997年7月21日PCT 1996年1月12日PCT PCT。 公开号WO96 / 22332 日期:1996年7月25日四氢四羧酸二酰亚胺其中R为氢; 其碳链可以被-O - , - S - , - NR 1 - , - CO - 和/或-SO 2 - 中的一个或多个中断的C 1 -C 30 - 烷基,并且其可以被氰基,C 1 -C 6单取代或多取代 - 烷氧基或5-,6-或7-元杂环基,其通过氮原子连接并且可以含有另外的杂原子并且可以是芳族的,其中R 1是氢或C 1 -C 6 - 烷基; 碳骨架可被-O - , - S-和/或-NR1-中的一个或多个中断的C 5 -C 8 - 环烷基; 芳基或杂芳基,其可以各自被C1-C18-烷基,C1-C6-烷氧基,氰基,-CONHR2,-NHCOR2和/或芳基 - 或杂芳基 - 偶氮基单取代或多取代,其可以各自被C1 C 1-10 - 烷基,C 1 -C 6 - 烷氧基或氰基,其中R 2是氢; C1-C18-烷基; 芳基或杂芳基,其各自可被C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基,卤素或氰基取代; X是卤素; C1-C18-烷基; 芳氧基,芳硫基,杂芳氧基或杂芳硫基,其各自可被C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代; n为2至12,它们的制备和用作颜料或荧光染料。
    • 9. 发明申请
    • Substituted Rylene Derivatives
    • 取代的Rylene衍生物
    • US20080167467A1
    • 2008-07-10
    • US11994719
    • 2006-07-06
    • Martin KonemannArno BohmNeil Gregory PschirerJianqiang QuGabriele Mattern
    • Martin KonemannArno BohmNeil Gregory PschirerJianqiang QuGabriele Mattern
    • C07D221/18
    • C07D493/06C07D471/06C08K5/0041C08K5/3437
    • Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.
    • 通式I的亚芳基衍生物各自定义如下:Rylene是多环共轭环系,其包含至少一个苝单元可以包含杂原子作为环原子,可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团:任选取代的烷基,环烷基,芳基,杂芳基,-U-芳基,其中U是-O - , - S - , - NR 2 - , - CO-, - SO - 或-SO 2 - 部分,或C 1 -C 12 - 烷氧基,C 1 -C -C≡CR2,-CR 2 -CR 2,2 - , - 羟基,巯基,卤素,氰基,硝基,-NR 3,R 4,-NR 3,COR 4, SO 2,SO 2,SO 2,SO 2,SO 3,SO 4,SO 2, >,-COOR 3或-SO 3 R 3; R'是相同或不同的基团:氢或R基团之一; R 2是氢或烷基,其中R 2个基团当它们不止一次出现时可以相同或不同; R 3,R 4各自独立地为氢; 任选取代的烷基,芳基或杂芳基; n为1至8。