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1. 发明授权

US10550059B2 Process for the production of acetic acid 有权
公开(公告)号：US10550059B2
公开(公告)日：2020-02-04
申请号：US16308332
申请日：2017-06-08
申请人： BP Chemicals Limited
发明人： Sean Anthony Hennigan
IPC分类号： C07C51/12 , C07C51/44 , C07C53/08
摘要： A process for the production of acetic acid which process comprises the steps of. (a) introducing methanol and/or a reactive derivative thereof and carbon monoxide into a first reaction zone containing a liquid reaction composition comprising a carbonylation catalyst, optionally a carbonylation catalyst promoter, methyl iodide, methyl acetate, acetic acid and water, (b) withdrawing at least a portion of the liquid reaction composition from the first reaction zone; (c) passing at least a portion of the withdrawn liquid reaction composition to a second reaction zone, wherein a gas feed comprising carbon monoxide is added to the liquid reaction composition withdrawn from the first reaction zone at one or more points upstream of the second reaction zone, one or more points within the second reaction zone, or a combination of one or more points upstream of the second reaction zone and one or more points within the second reaction zone; and (d) passing at least a portion of the liquid reaction composition from the second reaction zone into a flash separation zone to form: a vapour fraction, which comprises acetic acid, methyl iodide, methyl acetate and low pressure off-gas; and, a liquid fraction, which comprises carbonylation catalyst and optional carbonylation catalyst promoter; wherein the flow rate in kg of gas feed comprising carbon monoxide which is added to the second reaction zone per tonne of liquid reaction composition being passed to the flash separation zone (kg/te), is in the range of from 0.5FG to 1.2FG, wherein FG is defined according to equation 1: (1) FG=(0.296086962×tr)+(0.369636×RR)+(0.295878701×GP0.8134)−23.3448 wherein, tr is the residence time (seconds) of the liquid reaction composition within the second reaction zone which is calculated using equation 2: (2) tr=V2/Ff wherein, V2 is the volume of the second reaction zone (m3) and Ff is the volumetric flow rate of liquid reaction composition to the flash separation zone (m3/s), RR is the reaction rate of the liquid reaction composition passed to the second reaction zone at the temperature at which it is withdrawn from the first reaction zone (mol/litre/hour), and Gp is the purity of the gas feed comprising carbon monoxide which is added to the second reaction zone expressed as the mass fraction of carbon monoxide in the gas feed.

2. 发明授权

US10328420B2 Dehydration-hydrolysis processes and catalysts therefor 有权
公开(公告)号：US10328420B2
公开(公告)日：2019-06-25
申请号：US15730090
申请日：2017-10-11
申请人： BP CHEMICALS LIMITED
发明人： Thomas Edward Clark , Evert Jan Ditzel , David John Law , Bruce Leo Williams
IPC分类号： B01J29/65 , B01J37/08 , C01B39/44 , C07C41/09 , C07C43/04 , C07C51/09 , C07C53/08
摘要： Crystalline zeolites having a FER framework type wherein the crystallites have a dimension in the c-axis of about 500 nanometers (nm) or less, a method for their preparation and a process for the co-production of acetic acid and dimethyl ether comprising the step of contacting methyl acetate and methanol in the presence of catalysts comprising the crystalline zeolites.

3. 发明申请

US20180117526A1 METHOD AND APPARATUS FOR TREATING OFFGASES IN A ACETIC ACID PRODUCTION UNIT 审中-公开
公开(公告)号：US20180117526A1
公开(公告)日：2018-05-03
申请号：US15315154
申请日：2015-06-16
申请人： BP CHEMICALS LIMITED
发明人： Timothy Crispin Bristow , Paul David WILLIAMS
IPC分类号： B01D53/14 , C07C51/48 , C07C51/12 , B01D53/18
摘要： A method for scrubbing off-gas generated in production units for the manufacture of acetic acid and an apparatus therefor. The method comprises supplying off-gas and acetic acid solvent at a tick-over flow rate to an acetic acid scrubbing unit, withdrawing off-gas from the scrubbing unit, supplying withdrawn off-gas to a methanol scrubbing unit, scrubbing the off-gas therein with methanol solvent and withdrawing scrubbed off-gas from the methanol scrubbing unit.

4. 发明授权

US09873112B2 Dehydration-hydrolysis processes and catalysts therefor 有权
公开(公告)号：US09873112B2
公开(公告)日：2018-01-23
申请号：US14767633
申请日：2014-02-13
申请人： BP CHEMICALS LIMITED , Thomas Edward Clark , Evert Jan Ditzel , David John Law , Bruce Leo Williams
发明人： Thomas Edward Clark , Evert Jan Ditzel , David John Law , Bruce Leo Williams
IPC分类号： B01J29/65 , B01J37/08 , C01B39/44 , C07C51/09 , C07C41/09
CPC分类号： B01J29/65 , B01J37/08 , C01B39/445 , C01P2002/60 , C07C41/09 , C07C51/09 , C07C53/08 , C07C43/043
摘要： Process for the co-production of acetic acid and dimethyl ether by contacting methyl acetate and methanol in the presence of a catalyst containing a crystalline zeolite having a FER framework type. The zeolite has crystallites having a dimension of about 500 nm or less in the c-axis.

5. 发明申请

US20170190649A1 PROCESS 有权
公开(公告)号：US20170190649A1
公开(公告)日：2017-07-06
申请号：US15315260
申请日：2015-08-04
申请人： Sean Anthony HENNIGAN , BP CHEMICALS LIMITED
发明人： Sean Anthony HENNIGAN
IPC分类号： C07C51/44 , C07C51/12
CPC分类号： C07C51/44 , C07C51/12 , C07C53/08 , C07C53/122
摘要： A method of operating a heavy ends column in an acetic acid production unit, said production unit comprising at least a reaction section, a light ends recovery section comprising a light ends distillation column, and a heavy ends column, wherein a stream comprising acetic acid and propionic acid obtained from the light ends recovery section is fed to the heavy ends column through a feed inlet positioned at an intermediate point in the heavy ends column, a product stream comprising essentially acetic acid is withdrawn from the heavy ends column through a sidedraw product outlet position above the feed inlet, and a product stream comprising the propionic acid is withdrawn from the heavy ends column through a heavy product outlet positioned below the feed inlet, wherein the heavy ends column is operated under conditions such that the pressure in the heavy ends column above the feed inlet is lower than the pressure of the stream comprising acetic acid and propionic acid that is fed to the heavy ends column, and wherein the head pressure of the heavy ends column is below 1.0 bara, the number of theoretical separation stages between the feed inlet and the sidedraw product outlet is at least 5, preferably at least 7, more preferably at least 10, and the pressure drop in the part of the heavy ends column between the feed inlet and the sidedraw product outlet is at most 10 mbar per theoretical separation stage.

6. 发明申请

US20170081271A1 PROCESS FOR PURIFYING METHYL ACETATE MIXTURES 有权
公开(公告)号：US20170081271A1
公开(公告)日：2017-03-23
申请号：US15311965
申请日：2015-06-12
申请人： BP CHEMICALS LIMITED
发明人： Timothy Crispin BRISTOW
IPC分类号： C07C67/54 , B01D3/14 , C07C41/16 , B01D3/42 , C07C41/42 , C07C51/09
CPC分类号： C07C67/54 , B01D3/143 , B01D3/4205 , C07C41/16 , C07C41/42 , C07C51/09 , C07C67/37 , C07C43/043 , C07C53/08 , C07C69/14
摘要： A process for removing acetaldehyde from a mixture of methyl acetate, dimethyl ether and acetaldehyde comprising distilling mixtures derived from carbonylating dimethyl ether in the presence of a zeolite catalyst to generate an overhead stream depleted in acetaldehyde as compared to the feed mixture, a base stream depleted in acetaldehyde as compared to the feed mixture and a sidedraw stream enriched in acetaldehyde as compared to the feed mixture and withdrawing from the column the sidedraw stream enriched in acetaldehyde at a point above the feed point of the feed mixture to the column. Purified mixtures may be utilised as feedstock to processes for the co-production of acetic acid and dimethyl ether.

7. 发明申请

US20150329466A1 INTEGRATED PROCESS FOR THE PRODUCTION OF METHANOL AND METHYL ACETATE 有权
标题翻译：用于生产甲醇和乙酸甲酯的综合方法
公开(公告)号：US20150329466A1
公开(公告)日：2015-11-19
申请号：US14652828
申请日：2013-12-19
申请人： BP CHEMICALS LIMITED
发明人： Timothy Crispin BRISTOW
IPC分类号： C07C67/37 , C07C51/09 , C07C29/151
CPC分类号： C07C51/09 , C07C29/1516 , C07C29/1518 , C07C67/37 , Y02P20/125 , C07C69/14 , C07C53/08 , C07C31/04
摘要： An integrated process for the production of methyl acetate and methanol by carbonylating dimethyl ether with synthesis gas, recovering methyl acetate and unreacted synthesis gas and supplying unreacted synthesis gas and fresh synthesis gas for methanol synthesis.
摘要翻译：通过用合成气羰基化二甲醚，回收乙酸甲酯和未反应的合成气并提供未反应的合成气和新鲜的合成气进行甲醇合成，生产乙酸甲酯和甲醇的综合方法。

8. 发明申请

US20040077489A1 Polymerisation catalysts 有权
标题翻译：聚合催化剂
公开(公告)号：US20040077489A1
公开(公告)日：2004-04-22
申请号：US10667859
申请日：2003-09-23
申请人： BP Chemicals Limited
发明人： Brian Stephen Kimberley , Peter James Maddox , Stephen Roy Partington
IPC分类号： B01J031/00 , C08F004/02
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerisation of 1-olefins is disclosed, which comprises (1) a compound of Formula B wherein M is FenullIInull, FenullIIInull, ConullInull, ConullIInull, ConullIIInull, MnnullInull, MnnullIInull, MnnullIIInull, MnnullIVnull, RunullIInull, RunullIIInull or RunullIVnull; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1-R7 are hydrocarbyl, substituted hydrocarbyl, htctrohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst. Copolymers made using the catalyst having specific physical properties are also disclosed. 1
摘要翻译：公开了用于1-烯烃聚合的催化剂，其包括（1）式B的化合物，其中M是Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III] Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 当R 1 -R 7中的任何两个或更多个是烃基，取代的烃基，氢原子或取代的杂烃基时，所述两个或多个可以连接形成一个或多个环状取代基; 和（2）另外的催化剂。还公开了使用具有特定物理性质的催化剂制备的共聚物。

9. 发明申请

US20030144544A1 Catalyst composition and process for making same 有权
标题翻译：催化剂组成及其制备方法
公开(公告)号：US20030144544A1
公开(公告)日：2003-07-31
申请号：US10338673
申请日：2003-01-09
申请人： BP Chemicals Limited & Johnson Matthey Public Limited Company
发明人： Michael James Baker , John William Couves , Kenneth George Griffin , Peter Johnston , James Colin McNicol , George Frederick Salem
IPC分类号： C07C067/05 , B01J023/02
CPC分类号： B01J37/0201 , B01J35/0006 , B01J35/08 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A composition and process for making same in which the composition comprises support particles having at least one catalytically active metal or precursor thereof distributed therein in a layer below the surface of said particle, said layer being between an inner and an outer region of said support particle) and each of said inner and outer regions having a lower concentration of said metal or precursor thereof than said layer.
摘要翻译：一种组合物及其制备方法，其中组合物包含其中分布有至少一种催化活性金属或其前体的载体颗粒在所述颗粒表面下方的层中，所述层位于所述载体颗粒的内部和外部区域之间），并且所述内部和外部区域中的每一个具有比所述层更低浓度的所述金属或其前体。

10. 发明申请

US20020143220A1 Process for the preparation of mono-olefins from paraffinic hydrocarbons 失效
标题翻译：从链烷烃制备单烯烃的方法
公开(公告)号：US20020143220A1
公开(公告)日：2002-10-03
申请号：US10093725
申请日：2002-03-11
申请人： BP Chemicals Limited
发明人： David Charles Griffiths , Barry Martin Maunders , William Terence Woodfin
IPC分类号： C07C001/00 , C07C001/04
CPC分类号： C07C5/48 , C07C1/0485 , C07C29/1518 , C10G2/30 , C10G2400/20 , Y02P20/132 , Y02P30/40 , Y02P30/42 , C07C11/02 , C07C31/04
摘要： A process for the production of a mono-olefin from a feedstock comprising a paraffinic hydrocarbon which process comprises the steps of: (a) feeding the feedstock and a molecular oxygen-containing gas to an autothermal cracker wherein they are reacted by oxidative dehydrogenation to form a product comprising one, or more, mono-olefin(s) and synthesis gas, (b) separating the product from step (a) into a synthesis gas-containing stream and one, or more, olefins and recovering the one, or more, olefin(s), (c) contacting synthesis gas-containing stream separated in step (b) with either, (i) a catalyst for the conversion of synthesis gas to methanol under conditions whereby synthesis gas is converted to methanol; or (ii) a catalyst for the water gas shift reaction under conditions whereby carbon monoxide in the synthesis gas is converted by reaction with water to hydrogen and carbon dioxide and thereafter recovering hydrogen; or (iii) a catalyst for the conversion of synthesis gas to hydrocarbons under conditions whereby synthesis gas is converted to a hydrocarbon product, and thereafter recovering at least a part of the hydrocarbon product.
摘要翻译：一种从包含链烷烃的原料生产单烯烃的方法，该方法包括以下步骤：（a）将原料和含分子氧的气体进料到自热裂化器中，其中它们通过氧化脱氢反应形成包含一种或多种单烯烃和合成气的产品，（b）将步骤（a）中的产物分离成含合成气的料流和一种或多种烯烃，并回收一种或多种（c）将步骤（b）中分离的含有合成气的物流与（i）在合成气转化为甲醇的条件下将合成气转化为甲醇的催化剂接触;（c）或者（ii）用于水煤气变换反应的催化剂，其中合成气中的一氧化碳通过与水反应而转化成氢气和二氧化碳，然后回收氢气; 或（iii）在将合成气转化为烃产物的条件下将合成气转化为烃的催化剂，然后回收至少一部分烃产物。

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