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1. 发明授权

US4229554A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4229554A
公开(公告)日：1980-10-21
申请号：US746723
申请日：1976-12-02
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53 , C08F283/02 , C08G63/76 , C08G69/44
CPC分类号： C08G63/6824 , D06M11/47 , D06M11/70 , D06M15/507 , D06M15/53
摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound containing a metal from group Vb of the periodic table. Generally about 1:4 to about 4:1 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.
摘要翻译：提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时对这种聚合物纤维的可燃性没有贡献。阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，所述聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b）至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。通过使阻燃抗静电聚合物组合物包含含有周期表第Vb族中的金属的化合物的有效阻燃剂比例，可以获得改进的阻燃性能。通常使用约1:4至约4:1的卤素至锑化合物。这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

2. 发明授权

US4217394A Metal molds coated with oxidative stable polyoxyalkylene release agents 失效
标题翻译：金属模具涂有氧化稳定的聚氧化烯脱模剂
公开(公告)号：US4217394A
公开(公告)日：1980-08-12
申请号：US973100
申请日：1978-12-26
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： B29C33/62 , C10M107/34 , B32B15/04
CPC分类号： C10M107/34 , B29C33/62 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/106 , C10M2209/107 , C10M2209/109 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , Y10T428/31678
摘要： There are disclosed mold-release compositions suitable for lubricating metal molds which are used in molding natural and synthetic rubber and other polymers. The mold release agents of the invention are oxidation-stable homopolymer and copolymer, i.e., block or heteric polyoxyalkylene lubricant compounds. The lubricants of the invention can be used alone or in mixtures with prior art polyoxyalkylene lubricant compounds. The polyoxyalkylene mold release lubricants of the invention have the formula: ##STR1## R is individually selected from alkyl groups of 1 to about 21 carbon atoms, preferably about 7 to about 21 carbon atoms, and most preferably about 12 to about 18 carbon atoms. In lubricants I and III, R.sub.1 and R.sub.2 are the residue of the same or different and in lubricant II different alkylene units, all individually selected from the group consisting of the residue of ethylene oxide, propylene oxide, butylene oxide and an aromatic glycidyl ether, R.sub.3 is the residue of a difunctional phenol, R.sub.4 is hydrogen, an acyl or alkyl group and where alkyl, derived from an aliphatic monofunctional alcohol having 1 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 4 to about 12 carbon atoms or where acyl derived from an aliphatic monocarboxylic acid of 2 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 6 to about 12 carbon atoms, R.sub.5 is the residue of an aromatic glycidyl ether, preferably a phenyl glycidyl ether and n or m+n have a value to produce a molecular weight of about 300 to about 6000, preferably about 600 to about 5000 and most preferably about 1000 to about 4000.
摘要翻译：公开了适用于润滑金属模具的脱模组合物，其用于模制天然和合成橡胶和其它聚合物。本发明的脱模剂是氧化稳定的均聚物和共聚物，即嵌段或杂多聚氧化烯润滑剂化合物。本发明的润滑剂可以单独使用或与现有技术的聚氧化烯润滑剂化合物混合使用。本发明的聚氧化烯脱模润滑剂具有下式： I. II。和 III。 R独立地选自1至约21个碳原子，优选约7至约21个碳原子的烷基，最优选约12至约18个碳原子。在润滑剂I和III中，R1和R2是相同或不同的残基，润滑剂II不同的亚烷基单元，全部分别选自环氧乙烷，环氧丙烷，环氧丁烷和芳族缩水甘油醚的残基， R3是二官能苯酚的残基，R4是氢，酰基或烷基，其中烷基衍生自具有1至约21个碳原子，优选约4至约18个碳原子，最优选约4至约18个碳原子的脂肪族单官能醇约12个碳原子，或其中衍生自2至约21个碳原子，优选约4至约18个碳原子，最优选约6至约12个碳原子的脂肪族单羧酸的酰基，R 5为芳族缩水甘油醚的残基，优选苯基缩水甘油醚，n或m + n具有产生约300至约6000，优选约600至约5000，最优选约1000至约4000的分子量的值。

3. 发明授权

US4110227A Oxidation stable polyoxyalkylene fiber lubricants 失效
标题翻译：氧化稳定的聚氧乙烯纤维润滑剂
公开(公告)号：US4110227A
公开(公告)日：1978-08-29
申请号：US834721
申请日：1977-09-19
申请人： David Dudley Newkirk , Robert Bernard Login , Basil Thir
发明人： David Dudley Newkirk , Robert Bernard Login , Basil Thir
IPC分类号： C07C69/02 , D06M13/10 , D06M15/53
CPC分类号： D06M7/00 , D06M2200/40 , Y10T428/2969
摘要： Lubricants for synthetic fibers such as polyester and nylon are disclosed which are improved oxidation stable polyoxyalkylene lubricant compounds. Such lubricant compounds can be used alone as textile fiber lubricants or in combination with other polyoxyalkylene compounds useful as fiber lubricants but which are subject to oxidative degradation under conditions of heating at temperatures at least above 200.degree. C. An improved textile fiber is produced by the use of such fiber lubricants in conventional processes for producing continuous filament, false twist, textured yarn as well as other type yarns.The improved oxidation stable homopolymer and copolymer, i.e., block or heteric polyoxyalkylene lubricant compounds have the formulas: ##STR1## and can be used alone or in mixtures or in a mixture of an effective proportion thereof of at least 25% by weight based on the total weight of the mixture with one or more of any prior art polyoxyalkylene fiber lubricant compounds but preferably with one or more polyoxyalkylene compounds selected from the group consisting of prior art compounds having the formulas: ##STR2## R is individually selected from alkyl groups of 1 to about 21 carbon atoms preferably about 7 to about 21 carbon atoms and most preferably about 12 to about 18 carbon atoms.In lubricants I, III, V and VI, R.sub.1 and R.sub.2 are the residue of the same or different alkylene units and in lubricant II, R.sub.1 and R.sub.2 are different alkylene units, all individually selected from the group consisting of the residue of ethylene oxide, propylene oxide, butylene oxide and an aromatic glycidyl ether, R.sub.3 is the residue of a difunctional phenol, R.sub.4 is hydrogen, an acyl or alkyl group and where alkyl, derived from an aliphatic monofunctional alcohol having 1 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 4 to about 12 carbon atoms or where acyl derived from an aliphatic monocarboxylic acid of 2 to about 21 carbon atoms, preferably about 4 to about 18 carbon atoms and most preferably about 6 to about 12 carbon atoms, R.sub.5 is the residue of an aromatic glycidyl ether, preferably a phenyl glycidyl ether and n or m + n have a value to produce a molecular weight of about 300 to about 2000, preferably about 600 to about 2000 and most preferably about 800 to about 1800.

4. 发明授权

US4568480A Microemulsions 失效
标题翻译：微乳
公开(公告)号：US4568480A
公开(公告)日：1986-02-04
申请号：US552643
申请日：1983-11-17
申请人： Basil Thir , Edward M. Dexheimer
发明人： Basil Thir , Edward M. Dexheimer
IPC分类号： A01N25/04 , A23L29/10 , A61K8/06 , A61K8/39 , A61K9/107 , A61Q19/00 , B01F17/00 , C11D17/00 , A01N61/02 , B01J13/00 , C07C41/00
CPC分类号： A61K8/068 , A01N25/04 , A23L29/10 , A61K8/39 , A61K9/1075 , A61Q19/00 , B01F17/0085 , C11D17/0021 , Y10S514/939 , Y10S516/01
摘要： A microemulsion of water and an alkoxylated phenol derivative which may also contain an oil and an additional surfactant.
摘要翻译：水和烷氧基化酚衍生物的微乳液，其也可以含有油和另外的表面活性剂。

5. 发明授权

US4426301A Polyoxyalkylenes containing alkaline catalyst residues chelated with benzoic acid derivatives 失效
标题翻译：含有碱性催化剂残余物的聚氧化烯与苯甲酸衍生物螯合
公开(公告)号：US4426301A
公开(公告)日：1984-01-17
申请号：US311668
申请日：1981-10-15
申请人： Edward M. Dexheimer , Michael J. Anchor , Basil Thir , Stephen E. Eisenstein
发明人： Edward M. Dexheimer , Michael J. Anchor , Basil Thir , Stephen E. Eisenstein
IPC分类号： C08G18/28 , C08G65/30 , D06M13/188 , D06M15/53 , D06M15/44 , D06M13/18
CPC分类号： D06M13/188 , C08G18/28 , C08G65/30 , D06M7/00 , D06M2200/40 , Y10T428/2967 , Y10T428/2969
摘要： The oxidation promoting harmful effects of the presence of an alkaline catalyst in a polyoxyalkylene can be eliminated and the product made more resistant to oxidation especially at elevated temperatures by the incorporation therein of soluble salts of certain benzoic acid derivatives. The soluble salts can be formed by reaction with the alkali or alkaline earth metal ion derived from the alkaline catalyst utilized in the polymerization of the polyoxyalkylene.
摘要翻译：可以消除氧化促进的碱性催化剂在聚氧化烯中的存在的有害影响，并且通过加入某些苯甲酸衍生物的可溶性盐，产物更耐氧化，特别是在高温下。可溶性盐可以通过与在聚氧化烯聚合中使用的碱性催化剂衍生的碱金属或碱土金属离子反应形成。

6. 发明授权

US4360144A Printed circuit board soldering 失效
标题翻译：印刷电路板焊接
公开(公告)号：US4360144A
公开(公告)日：1982-11-23
申请号：US226970
申请日：1981-01-21
申请人： William A. Cuddy , Basil Thir , Stephen E. Eisenstein
发明人： William A. Cuddy , Basil Thir , Stephen E. Eisenstein
IPC分类号： B23K35/36 , H05K3/34 , B05D5/12 , B23K31/02
CPC分类号： B23K35/3613 , H05K3/3489 , Y10T29/49144
摘要： The present invention relates to a method of wave soldering an assembly composed of a plurality of electrical conductors disposed on a surface of a sheet of insulating material. In accordance with this method, the surface of the sheet and the conductors are contacted with a stationary wave of molten solder having a polyether admixed therewith and floating on the surface thereof. The polyether is a heteric or block copolymer of a dihydroxyphenol and at least one lower alkylene oxide. It is preferred that the alkylene oxide contain 2 to 4 carbon atoms. The alkylene oxide may be all ethylene oxide or may be a mixture with other lower alkylene oxides such as propylene oxides and butylene oxides. In any event, the copolymer should contain at least about 20 percent by weight of oxyethylene groups, balance oxypropylene groups and/or oxybutylene groups. A conventional polymeric oxidation inhibitor may also be included.
摘要翻译：本发明涉及一种波峰焊接由多个设置在绝缘材料片的表面上的电导体组成的组件的方法。根据该方法，片材的表面和导体与具有聚醚的熔融焊料的固定波接触并漂浮在其表面上。聚醚是二羟基苯酚和至少一种低级环氧烷烃的杂环或嵌段共聚物。环氧烷优选含有2至4个碳原子。烯化氧可以全部是环氧乙烷，也可以是与其它低级环氧烷如环氧丙烷和环氧丁烷的混合物。在任何情况下，共聚物应包含至少约20重量％的氧化乙烯基团，余量的氧化丙烯基团和/或氧基丁烯基团。还可以包括常规的聚合物氧化抑制剂。

7. 发明授权

US4303767A Flame retardant antistatic additives and antistatic fibers 失效
标题翻译：阻燃抗静电添加剂和抗静电纤维
公开(公告)号：US4303767A
公开(公告)日：1981-12-01
申请号：US094033
申请日：1979-11-13
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： C08G63/682 , D06M11/47 , D06M11/68 , D06M15/507 , D06M15/53 , C08L67/00
CPC分类号： D06M11/47 , C08G63/6824 , D06M11/68 , D06M15/507 , D06M15/53
摘要： Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.Improved flame-retardant properties can be obtained by including with the flame-retardant, antistatic polymer composition an effective flame retardant proportion of a compound from group Vb of the periodic table. Generally about 1:4 to about 4:2 parts halogen to antimony compound is used. Such compounds are oxides of metals such as phosphorus, arsenic, antimony, or bismuth with the preferred compound being antimony trioxide.
摘要翻译：提供了阻燃抗静电聚合物添加剂，其在将合成聚合物纤维即聚酰胺纤维加入这些组合物时抑制静电荷的累积，并且同时不影响这种聚合物纤维的可燃性。阻燃抗静电聚合物组合物可与纤维如聚酰胺，聚酯，聚脲，聚氨酯，聚磺酰胺，聚烯烃和聚丙烯酸纤维组合使用。抗静电效果是通过将纤维涂布或分散在纤维中或在纤维上分散至约12重量％的聚合物组合物获得的，聚合物组合物是以下物质的反应产物：（a）聚氧化烯化合物或其聚酯和（b）至少一种选自（1）二醇，（2）聚酯和（3）脂族或芳族二酸或（3）的衍生物的反应物，其中至少一种所述反应物被卤化。通过使阻燃抗静电聚合物组合物包含有效的阻燃比例的元素周期表中的Vb族化合物，可以获得改进的阻燃性能。通常使用约1：4至约4：2份卤素至锑化合物。这些化合物是金属的氧化物，例如磷，砷，锑或铋，优选的化合物是三氧化锑。

8. 发明授权

US4179544A Fiber finish compositions 失效
标题翻译：纤维成品组合物
公开(公告)号：US4179544A
公开(公告)日：1979-12-18
申请号：US857382
申请日：1977-12-05
申请人： David D. Newkirk , Basil Thir , Robert B. Login
发明人： David D. Newkirk , Basil Thir , Robert B. Login
IPC分类号： C10M169/04 , D06M15/693 , D02G3/00
CPC分类号： D06M15/693 , C10M169/04 , C10M2207/023 , C10M2207/024 , C10M2209/101 , C10M2209/1033 , C10M2209/1045 , C10M2209/1055 , C10M2209/1065 , C10M2209/107 , C10M2209/1075 , C10M2209/1085 , C10M2209/1095 , C10M2221/043 , C10M2227/00 , C10N2220/02 , C10N2240/62 , Y10T428/2933 , Y10T428/2964 , Y10T428/2969
摘要： A fiber finish composition, consisting of a mixture of a major amount of lubricant and a minor amount of a stabilizer of said fiber finish and a process for employment thereof.
摘要翻译：一种纤维整理剂组合物，其由主要量的润滑剂和少量的所述纤维整理剂的稳定剂的混合物组成，以及其使用方法。

9. 发明授权

US4689082A Polymer composition 失效
标题翻译：聚合物组成
公开(公告)号：US4689082A
公开(公告)日：1987-08-25
申请号：US792204
申请日：1985-10-28
申请人： Edward M. Dexheimer , Basil Thir
发明人： Edward M. Dexheimer , Basil Thir
IPC分类号： B29C33/62 , C08K5/06 , C08L71/02 , C04B35/68 , C11D17/00
CPC分类号： C08L71/02 , B29C33/62 , C08K5/06
摘要： The instant invention relates to a rubber lubricant composition characterized by complete wetting of the elastomer surface both before and after vulcanization which gives a matte finish on cooling down that remains soft and does not flake off and which washes off easily after molding whereby there is little of no ooze after several months storage. This comprises (1) polyoxypropylene-polyoxyethylene block copolymer having a molecular weight of the hydrophobe of about 1000 to 12,000 and containing 40 to 80 percent oxyethylene groups and (2) an alkyl phenol ethoxylate.
摘要翻译：本发明涉及一种橡胶润滑剂组合物，其特征在于在硫化之前和之后完全润湿弹性体表面，其在冷却时提供无光泽的冷却，其保持柔软并且不会脱落，并且在成型后容易洗掉，因此几乎没有储存几个月后不渗出。这包括（1）疏水物的分子量为约1000至12,000并含有40至80％氧乙烯基的聚氧丙烯 - 聚氧乙烯嵌段共聚物和（2）烷基酚乙氧基化物。

10. 发明授权

US4371476A Mold release agents containing oxidation stable polyoxyalkylenes 失效
标题翻译：含有氧化稳定的聚氧化烯的脱模剂
公开(公告)号：US4371476A
公开(公告)日：1983-02-01
申请号：US211952
申请日：1980-12-01
申请人： David D. Newkirk , Robert B. Login , Basil Thir
发明人： David D. Newkirk , Robert B. Login , Basil Thir
IPC分类号： B29C33/62 , C08L21/00
CPC分类号： B29C33/62 , C10M3/00 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/106 , C10M2209/107 , C10M2209/109 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： Compositions having internal mold-release properties comprise a molding polymer and an oxidation stable polyoxyalkylene lubricant compound used alone or in combination with other polyoxyalkylene compounds.
摘要翻译：具有内部脱模性的组合物包括单独使用或与其它聚氧化烯化合物组合使用的模塑聚合物和氧化稳定的聚氧化烯润滑剂。

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